6-[(2,4-Dimethylanilino)methylidene]-2-hydroxycyclohexa-2,4-dienone
In the title compound, C15H15NO2, the dihedral angle between the aromatic rings is 5.86 (6)°, and an intramolecular N—H...O hydrogen bond generates an S(6) motif, which helps to stabilize the enamine–keto tautomer. An intramolecular O—H...O hydrogen b...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2013-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813012233 |
| _version_ | 1819001855148032000 |
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| author | Shaukat Shujah Saqib Ali Zia-ur-Rehman M. Nawaz Tahir Auke Meetsma |
| author_facet | Shaukat Shujah Saqib Ali Zia-ur-Rehman M. Nawaz Tahir Auke Meetsma |
| author_sort | Shaukat Shujah |
| collection | DOAJ |
| description | In the title compound, C15H15NO2, the dihedral angle between the aromatic rings is 5.86 (6)°, and an intramolecular N—H...O hydrogen bond generates an S(6) motif, which helps to stabilize the enamine–keto tautomer. An intramolecular O—H...O hydrogen bond also occurs. In the crystal, inversion dimers linked by pairs of O—H...O hydrogen bonds generate R22(10) loops. A C—H...O interaction links the dimers into [010] chains and aromatic π–π stacking [centroid–centroid separation = 3.6131 (9) Å] also occurs. |
| first_indexed | 2024-12-20T22:55:50Z |
| format | Article |
| id | doaj.art-a745e00ef81646f9bd194aa848cb2fac |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T22:55:50Z |
| publishDate | 2013-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-a745e00ef81646f9bd194aa848cb2fac2022-12-21T19:24:08ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-06-01696o871o87110.1107/S16005368130122336-[(2,4-Dimethylanilino)methylidene]-2-hydroxycyclohexa-2,4-dienoneShaukat ShujahSaqib AliZia-ur-RehmanM. Nawaz TahirAuke MeetsmaIn the title compound, C15H15NO2, the dihedral angle between the aromatic rings is 5.86 (6)°, and an intramolecular N—H...O hydrogen bond generates an S(6) motif, which helps to stabilize the enamine–keto tautomer. An intramolecular O—H...O hydrogen bond also occurs. In the crystal, inversion dimers linked by pairs of O—H...O hydrogen bonds generate R22(10) loops. A C—H...O interaction links the dimers into [010] chains and aromatic π–π stacking [centroid–centroid separation = 3.6131 (9) Å] also occurs.http://scripts.iucr.org/cgi-bin/paper?S1600536813012233 |
| spellingShingle | Shaukat Shujah Saqib Ali Zia-ur-Rehman M. Nawaz Tahir Auke Meetsma 6-[(2,4-Dimethylanilino)methylidene]-2-hydroxycyclohexa-2,4-dienone Acta Crystallographica Section E |
| title | 6-[(2,4-Dimethylanilino)methylidene]-2-hydroxycyclohexa-2,4-dienone |
| title_full | 6-[(2,4-Dimethylanilino)methylidene]-2-hydroxycyclohexa-2,4-dienone |
| title_fullStr | 6-[(2,4-Dimethylanilino)methylidene]-2-hydroxycyclohexa-2,4-dienone |
| title_full_unstemmed | 6-[(2,4-Dimethylanilino)methylidene]-2-hydroxycyclohexa-2,4-dienone |
| title_short | 6-[(2,4-Dimethylanilino)methylidene]-2-hydroxycyclohexa-2,4-dienone |
| title_sort | 6 2 4 dimethylanilino methylidene 2 hydroxycyclohexa 2 4 dienone |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813012233 |
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