Crystal structure of [3-(4,5-dihydro-1,3-thiazolin-2-yl-κN)-1,3-thiazolidine-2-thione-κS2](1,3-thiazolidine-2-thione-κS2)copper(I) nitrate
The mononuclear complex salt, [Cu(C3H5NS2)(C6H8N2S3)]NO3, contains a [C9H13CuN3S5]+ cation and an NO3− anion. All of the non-H atoms of the cation lie on a mirror plane, as do the N and one O atom of the nitrate anion, such that the planes of the cation and anion are mutually orthogonal. The cationi...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014-08-01
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| Series: | Acta Crystallographica Section E |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681401544X |
| _version_ | 1818083192976965632 |
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| author | Saowanit Saithong Pirawan Klongkleaw Chaveng Pakawatchai Jedsada Mokakul |
| author_facet | Saowanit Saithong Pirawan Klongkleaw Chaveng Pakawatchai Jedsada Mokakul |
| author_sort | Saowanit Saithong |
| collection | DOAJ |
| description | The mononuclear complex salt, [Cu(C3H5NS2)(C6H8N2S3)]NO3, contains a [C9H13CuN3S5]+ cation and an NO3− anion. All of the non-H atoms of the cation lie on a mirror plane, as do the N and one O atom of the nitrate anion, such that the planes of the cation and anion are mutually orthogonal. The cationic complex adopts a slightly distorted trigonal–planar geometry about the CuI cation. In the crystal, layers parallel to (010) are generated by N—H...O hydrogen bonds, supported by short S...O [3.196 (4) and 3.038 (3) Å] and S...S contacts [3.4392 (13) Å]. Adjacent layers are linked by C—H...O hydrogen bonds and weak π–π stacking interactions [centroid–centroid distance = 4.0045 (10) Å] between the thiazoline rings, forming a three-dimensional network. This stacking also imposes a close contact, of approximately 3.678 Å, between the CuI cations and the centroids of the six-membered chelate rings of molecules in adjacent layers. |
| first_indexed | 2024-12-10T19:34:06Z |
| format | Article |
| id | doaj.art-a749741d3ae04827bbde10fb4d8d3b8d |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T19:34:06Z |
| publishDate | 2014-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-a749741d3ae04827bbde10fb4d8d3b8d2022-12-22T01:36:10ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-08-01708919310.1107/S160053681401544Xsj5420Crystal structure of [3-(4,5-dihydro-1,3-thiazolin-2-yl-κN)-1,3-thiazolidine-2-thione-κS2](1,3-thiazolidine-2-thione-κS2)copper(I) nitrateSaowanit Saithong0Pirawan Klongkleaw1Chaveng Pakawatchai2Jedsada Mokakul3Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, ThailandDepartment of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, ThailandDepartment of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, ThailandDepartment of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, ThailandThe mononuclear complex salt, [Cu(C3H5NS2)(C6H8N2S3)]NO3, contains a [C9H13CuN3S5]+ cation and an NO3− anion. All of the non-H atoms of the cation lie on a mirror plane, as do the N and one O atom of the nitrate anion, such that the planes of the cation and anion are mutually orthogonal. The cationic complex adopts a slightly distorted trigonal–planar geometry about the CuI cation. In the crystal, layers parallel to (010) are generated by N—H...O hydrogen bonds, supported by short S...O [3.196 (4) and 3.038 (3) Å] and S...S contacts [3.4392 (13) Å]. Adjacent layers are linked by C—H...O hydrogen bonds and weak π–π stacking interactions [centroid–centroid distance = 4.0045 (10) Å] between the thiazoline rings, forming a three-dimensional network. This stacking also imposes a close contact, of approximately 3.678 Å, between the CuI cations and the centroids of the six-membered chelate rings of molecules in adjacent layers.http://scripts.iucr.org/cgi-bin/paper?S160053681401544Xcopper(II) complex1,3-thiazolidine-2-thione3-(2-thiazolin-2-yl)thiazolidine-2-thionecrystal structure |
| spellingShingle | Saowanit Saithong Pirawan Klongkleaw Chaveng Pakawatchai Jedsada Mokakul Crystal structure of [3-(4,5-dihydro-1,3-thiazolin-2-yl-κN)-1,3-thiazolidine-2-thione-κS2](1,3-thiazolidine-2-thione-κS2)copper(I) nitrate Acta Crystallographica Section E copper(II) complex 1,3-thiazolidine-2-thione 3-(2-thiazolin-2-yl)thiazolidine-2-thione crystal structure |
| title | Crystal structure of [3-(4,5-dihydro-1,3-thiazolin-2-yl-κN)-1,3-thiazolidine-2-thione-κS2](1,3-thiazolidine-2-thione-κS2)copper(I) nitrate |
| title_full | Crystal structure of [3-(4,5-dihydro-1,3-thiazolin-2-yl-κN)-1,3-thiazolidine-2-thione-κS2](1,3-thiazolidine-2-thione-κS2)copper(I) nitrate |
| title_fullStr | Crystal structure of [3-(4,5-dihydro-1,3-thiazolin-2-yl-κN)-1,3-thiazolidine-2-thione-κS2](1,3-thiazolidine-2-thione-κS2)copper(I) nitrate |
| title_full_unstemmed | Crystal structure of [3-(4,5-dihydro-1,3-thiazolin-2-yl-κN)-1,3-thiazolidine-2-thione-κS2](1,3-thiazolidine-2-thione-κS2)copper(I) nitrate |
| title_short | Crystal structure of [3-(4,5-dihydro-1,3-thiazolin-2-yl-κN)-1,3-thiazolidine-2-thione-κS2](1,3-thiazolidine-2-thione-κS2)copper(I) nitrate |
| title_sort | crystal structure of 3 4 5 dihydro 1 3 thiazolin 2 yl κn 1 3 thiazolidine 2 thione κs2 1 3 thiazolidine 2 thione κs2 copper i nitrate |
| topic | copper(II) complex 1,3-thiazolidine-2-thione 3-(2-thiazolin-2-yl)thiazolidine-2-thione crystal structure |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053681401544X |
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