[1-(1-Adamantylamino)ethylidene]oxonium methanesulfonate
In the title salt, C12H20NO+·CH3SO3−, the [1-(1-adamantylamino)ethylidene]oxonium cations and methanesulfonate anions are linked into chains along the a axis via O—H...O and N—H...O hydrogen bonds. All non-H atoms of the acetamido group are esse...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809017632 |
| Summary: | In the title salt, C12H20NO+·CH3SO3−, the [1-(1-adamantylamino)ethylidene]oxonium cations and methanesulfonate anions are linked into chains along the a axis via O—H...O and N—H...O hydrogen bonds. All non-H atoms of the acetamido group are essentially planar, with a maximum deviation of 0.0085 (12) Å. In comparison with related structures, the carbonyl C=O bond is slightly elongated [1.249 (2) Å], whereas the amide C—N bond is shortened [1.292 (2) Å]. |
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| ISSN: | 1600-5368 |