[1-(1-Adamantylamino)ethylidene]oxonium methanesulfonate
In the title salt, C12H20NO+·CH3SO3−, the [1-(1-adamantylamino)ethylidene]oxonium cations and methanesulfonate anions are linked into chains along the a axis via O—H...O and N—H...O hydrogen bonds. All non-H atoms of the acetamido group are esse...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809017632 |
| _version_ | 1819281337574490112 |
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| author | Robert Vícha Marek Nečas Zuzana Kozubková Milan Potáček |
| author_facet | Robert Vícha Marek Nečas Zuzana Kozubková Milan Potáček |
| author_sort | Robert Vícha |
| collection | DOAJ |
| description | In the title salt, C12H20NO+·CH3SO3−, the [1-(1-adamantylamino)ethylidene]oxonium cations and methanesulfonate anions are linked into chains along the a axis via O—H...O and N—H...O hydrogen bonds. All non-H atoms of the acetamido group are essentially planar, with a maximum deviation of 0.0085 (12) Å. In comparison with related structures, the carbonyl C=O bond is slightly elongated [1.249 (2) Å], whereas the amide C—N bond is shortened [1.292 (2) Å]. |
| first_indexed | 2024-12-24T00:58:05Z |
| format | Article |
| id | doaj.art-a74bb21d67ef4b1a8ae4b128fb4c1e0a |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:58:05Z |
| publishDate | 2009-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-a74bb21d67ef4b1a8ae4b128fb4c1e0a2022-12-21T17:23:26ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-06-01656o1307o130710.1107/S1600536809017632[1-(1-Adamantylamino)ethylidene]oxonium methanesulfonateRobert VíchaMarek NečasZuzana KozubkováMilan PotáčekIn the title salt, C12H20NO+·CH3SO3−, the [1-(1-adamantylamino)ethylidene]oxonium cations and methanesulfonate anions are linked into chains along the a axis via O—H...O and N—H...O hydrogen bonds. All non-H atoms of the acetamido group are essentially planar, with a maximum deviation of 0.0085 (12) Å. In comparison with related structures, the carbonyl C=O bond is slightly elongated [1.249 (2) Å], whereas the amide C—N bond is shortened [1.292 (2) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536809017632 |
| spellingShingle | Robert Vícha Marek Nečas Zuzana Kozubková Milan Potáček [1-(1-Adamantylamino)ethylidene]oxonium methanesulfonate Acta Crystallographica Section E |
| title | [1-(1-Adamantylamino)ethylidene]oxonium methanesulfonate |
| title_full | [1-(1-Adamantylamino)ethylidene]oxonium methanesulfonate |
| title_fullStr | [1-(1-Adamantylamino)ethylidene]oxonium methanesulfonate |
| title_full_unstemmed | [1-(1-Adamantylamino)ethylidene]oxonium methanesulfonate |
| title_short | [1-(1-Adamantylamino)ethylidene]oxonium methanesulfonate |
| title_sort | 1 1 adamantylamino ethylidene oxonium methanesulfonate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809017632 |
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