Synthesis, Crystal Structure and Separation Performance of p-tert-butyl(tetradecyloxy)calix[6]arene
This work describes the investigation of separation performance of the p-tert-butyl(tetradecyloxy)calix[6]arene (C6A-C10-OH) as stationary phase for gas chromatography (GC) separations. Its structure was characterized by IR, 1H NMR, 13C NMR, MS and single-crystal X-ray diffraction analysis. The C6A-...
| Main Authors: | , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Slovenian Chemical Society
2022-03-01
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| Series: | Acta Chimica Slovenica |
| Subjects: | |
| Online Access: | https://journals.matheo.si/index.php/ACSi/article/view/7218 |
| _version_ | 1818156039448559616 |
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| author | Wei Zhang Zhi-qiang Cai Xiao-min Shuai Wei Li Qiu-chen Huang Ruo-nan Chen Qi-qi Zang Fei-fei Li Tao Sun |
| author_facet | Wei Zhang Zhi-qiang Cai Xiao-min Shuai Wei Li Qiu-chen Huang Ruo-nan Chen Qi-qi Zang Fei-fei Li Tao Sun |
| author_sort | Wei Zhang |
| collection | DOAJ |
| description | This work describes the investigation of separation performance of the p-tert-butyl(tetradecyloxy)calix[6]arene (C6A-C10-OH) as stationary phase for gas chromatography (GC) separations. Its structure was characterized by IR, 1H NMR, 13C NMR, MS and single-crystal X-ray diffraction analysis. The C6A-C10-OH column shows good separation capacity for aliphatic, aromatic and cis-/trans- isomers. Especially, it exhibits multiple molecular recognition interactions for the analytes with a wide range of polarity, including dispersion, π-π, H-bonding and dipole-dipole interactions. The present work provides experimental and theoretical basis for the designing of the new calixarene stationary phases in GC analyses. |
| first_indexed | 2024-12-11T14:51:58Z |
| format | Article |
| id | doaj.art-a75904192a854b748e59c9b2b49d1965 |
| institution | Directory Open Access Journal |
| issn | 1318-0207 1580-3155 |
| language | English |
| last_indexed | 2024-12-11T14:51:58Z |
| publishDate | 2022-03-01 |
| publisher | Slovenian Chemical Society |
| record_format | Article |
| series | Acta Chimica Slovenica |
| spelling | doaj.art-a75904192a854b748e59c9b2b49d19652022-12-22T01:01:26ZengSlovenian Chemical SocietyActa Chimica Slovenica1318-02071580-31552022-03-0169122723410.17344/acsi.2021.72181047Synthesis, Crystal Structure and Separation Performance of p-tert-butyl(tetradecyloxy)calix[6]areneWei ZhangZhi-qiang CaiXiao-min ShuaiWei LiQiu-chen HuangRuo-nan ChenQi-qi ZangFei-fei LiTao SunThis work describes the investigation of separation performance of the p-tert-butyl(tetradecyloxy)calix[6]arene (C6A-C10-OH) as stationary phase for gas chromatography (GC) separations. Its structure was characterized by IR, 1H NMR, 13C NMR, MS and single-crystal X-ray diffraction analysis. The C6A-C10-OH column shows good separation capacity for aliphatic, aromatic and cis-/trans- isomers. Especially, it exhibits multiple molecular recognition interactions for the analytes with a wide range of polarity, including dispersion, π-π, H-bonding and dipole-dipole interactions. The present work provides experimental and theoretical basis for the designing of the new calixarene stationary phases in GC analyses.https://journals.matheo.si/index.php/ACSi/article/view/7218calixarenecrystal structureseparation performance |
| spellingShingle | Wei Zhang Zhi-qiang Cai Xiao-min Shuai Wei Li Qiu-chen Huang Ruo-nan Chen Qi-qi Zang Fei-fei Li Tao Sun Synthesis, Crystal Structure and Separation Performance of p-tert-butyl(tetradecyloxy)calix[6]arene Acta Chimica Slovenica calixarene crystal structure separation performance |
| title | Synthesis, Crystal Structure and Separation Performance of p-tert-butyl(tetradecyloxy)calix[6]arene |
| title_full | Synthesis, Crystal Structure and Separation Performance of p-tert-butyl(tetradecyloxy)calix[6]arene |
| title_fullStr | Synthesis, Crystal Structure and Separation Performance of p-tert-butyl(tetradecyloxy)calix[6]arene |
| title_full_unstemmed | Synthesis, Crystal Structure and Separation Performance of p-tert-butyl(tetradecyloxy)calix[6]arene |
| title_short | Synthesis, Crystal Structure and Separation Performance of p-tert-butyl(tetradecyloxy)calix[6]arene |
| title_sort | synthesis crystal structure and separation performance of p tert butyl tetradecyloxy calix 6 arene |
| topic | calixarene crystal structure separation performance |
| url | https://journals.matheo.si/index.php/ACSi/article/view/7218 |
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