μ-Nitrilotriacetato-tris(1,10-phenanthroline)dizinc(II) nitrate hexahydrate
The nitrilotriacetate trianion in the title compound, [Zn2(C6H6NO6)(C12H8N2)3]NO3·6H2O, is engaged in N,O,O′,O"-chelation to the phenanthroline-chelated ZnII unit, giving a distorted octahedral geometry for the metal atom. One of the three O atoms of the trianion that is enga...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808041433 |
| _version_ | 1829118739134545920 |
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| author | Lee Fang Chin Chew Hee Ng Seik Weng Ng |
| author_facet | Lee Fang Chin Chew Hee Ng Seik Weng Ng |
| author_sort | Lee Fang Chin |
| collection | DOAJ |
| description | The nitrilotriacetate trianion in the title compound, [Zn2(C6H6NO6)(C12H8N2)3]NO3·6H2O, is engaged in N,O,O′,O"-chelation to the phenanthroline-chelated ZnII unit, giving a distorted octahedral geometry for the metal atom. One of the three O atoms of the trianion that is engaged in chelation also binds to the bis(phenanthroline)-chelated ZnII unit, whose five-coordinate geometry is distorted owing to a long Zn...O interaction [2.401 (2) Å]. The dinuclear cations, nitrate anions and uncoordinated water molecules are linked into a three-dimensional network via O—H...O hydrogen bonds between water molecules and carboxylate O atoms. |
| first_indexed | 2024-12-13T10:43:14Z |
| format | Article |
| id | doaj.art-a7893f8f45864bbdbcb59f620dfc4b19 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:43:14Z |
| publishDate | 2009-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-a7893f8f45864bbdbcb59f620dfc4b192022-12-21T23:50:22ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-01-01651m40m4010.1107/S1600536808041433μ-Nitrilotriacetato-tris(1,10-phenanthroline)dizinc(II) nitrate hexahydrateLee Fang ChinChew Hee NgSeik Weng NgThe nitrilotriacetate trianion in the title compound, [Zn2(C6H6NO6)(C12H8N2)3]NO3·6H2O, is engaged in N,O,O′,O"-chelation to the phenanthroline-chelated ZnII unit, giving a distorted octahedral geometry for the metal atom. One of the three O atoms of the trianion that is engaged in chelation also binds to the bis(phenanthroline)-chelated ZnII unit, whose five-coordinate geometry is distorted owing to a long Zn...O interaction [2.401 (2) Å]. The dinuclear cations, nitrate anions and uncoordinated water molecules are linked into a three-dimensional network via O—H...O hydrogen bonds between water molecules and carboxylate O atoms.http://scripts.iucr.org/cgi-bin/paper?S1600536808041433 |
| spellingShingle | Lee Fang Chin Chew Hee Ng Seik Weng Ng μ-Nitrilotriacetato-tris(1,10-phenanthroline)dizinc(II) nitrate hexahydrate Acta Crystallographica Section E |
| title | μ-Nitrilotriacetato-tris(1,10-phenanthroline)dizinc(II) nitrate hexahydrate |
| title_full | μ-Nitrilotriacetato-tris(1,10-phenanthroline)dizinc(II) nitrate hexahydrate |
| title_fullStr | μ-Nitrilotriacetato-tris(1,10-phenanthroline)dizinc(II) nitrate hexahydrate |
| title_full_unstemmed | μ-Nitrilotriacetato-tris(1,10-phenanthroline)dizinc(II) nitrate hexahydrate |
| title_short | μ-Nitrilotriacetato-tris(1,10-phenanthroline)dizinc(II) nitrate hexahydrate |
| title_sort | 956 nitrilotriacetato tris 1 10 phenanthroline dizinc ii nitrate hexahydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808041433 |
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