Polymer binders for the electrodes of lithium batteries. Part 3. Conductive polymers

The third part of the review is devoted to polymer binders with electronic conductivity used to make composite electrodes for lithium electrochemical systems. Polymer semiconductors (“synthetic metals”), related polymers with additionally introduced functional groups, related copolymers and mixtures...

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Main Authors: Istomina, Aigul Salavatovna, Bushkova, Ol'ga Viktorovna
Format: Article
Language:English
Published: Saratov State University 2021-03-01
Series:Электрохимическая энергетика
Subjects:
Online Access:https://energetica.sgu.ru/sites/default/files/electro202101-up-x1.pdf
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author Istomina, Aigul Salavatovna
Bushkova, Ol'ga Viktorovna
author_facet Istomina, Aigul Salavatovna
Bushkova, Ol'ga Viktorovna
author_sort Istomina, Aigul Salavatovna
collection DOAJ
description The third part of the review is devoted to polymer binders with electronic conductivity used to make composite electrodes for lithium electrochemical systems. Polymer semiconductors (“synthetic metals”), related polymers with additionally introduced functional groups, related copolymers and mixtures of polymers, as well as carbon chain polymers and copolymers with inсorporated polyaromatic fragments are considered. Such materials significantly improve electrical connectivity of the composite electrode and make it possible to eliminate or minimise the content of electrochemically inert conductive additives (carbon black, graphite powder), which positively influences on the specific capacity and cycling stability of the electrodes. Improving conditions of electronic transfer is especially important for the efficient use of active materials with extremely low intrinsic conductivity, such as Si, Li4Ti5O12, LiFePO4, etc. The final part of the review summarizes general principles of the targeted selection of a polymer binder.
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spelling doaj.art-a7b59262244c44fd8020aae8a8c736422022-12-21T17:22:30ZengSaratov State UniversityЭлектрохимическая энергетика1608-40391680-95052021-03-0121132010.18500/1608-4039-2021-21-1-3-20Polymer binders for the electrodes of lithium batteries. Part 3. Conductive polymersIstomina, Aigul Salavatovna0Bushkova, Ol'ga Viktorovna1Institute of Chemistry of a Solid body UB of RAS, 91, GSP, Pervomayskaya St., Yekaterinburg, 620990Institute of high-temperature Electrochemistry UB of RAS, 20, Akademicheskaya St., Yekaterinburg, 620990The third part of the review is devoted to polymer binders with electronic conductivity used to make composite electrodes for lithium electrochemical systems. Polymer semiconductors (“synthetic metals”), related polymers with additionally introduced functional groups, related copolymers and mixtures of polymers, as well as carbon chain polymers and copolymers with inсorporated polyaromatic fragments are considered. Such materials significantly improve electrical connectivity of the composite electrode and make it possible to eliminate or minimise the content of electrochemically inert conductive additives (carbon black, graphite powder), which positively influences on the specific capacity and cycling stability of the electrodes. Improving conditions of electronic transfer is especially important for the efficient use of active materials with extremely low intrinsic conductivity, such as Si, Li4Ti5O12, LiFePO4, etc. The final part of the review summarizes general principles of the targeted selection of a polymer binder.https://energetica.sgu.ru/sites/default/files/electro202101-up-x1.pdfpolymer bindersconductive polymerscomposite electrodeslithium-ion batteries
spellingShingle Istomina, Aigul Salavatovna
Bushkova, Ol'ga Viktorovna
Polymer binders for the electrodes of lithium batteries. Part 3. Conductive polymers
Электрохимическая энергетика
polymer binders
conductive polymers
composite electrodes
lithium-ion batteries
title Polymer binders for the electrodes of lithium batteries. Part 3. Conductive polymers
title_full Polymer binders for the electrodes of lithium batteries. Part 3. Conductive polymers
title_fullStr Polymer binders for the electrodes of lithium batteries. Part 3. Conductive polymers
title_full_unstemmed Polymer binders for the electrodes of lithium batteries. Part 3. Conductive polymers
title_short Polymer binders for the electrodes of lithium batteries. Part 3. Conductive polymers
title_sort polymer binders for the electrodes of lithium batteries part 3 conductive polymers
topic polymer binders
conductive polymers
composite electrodes
lithium-ion batteries
url https://energetica.sgu.ru/sites/default/files/electro202101-up-x1.pdf
work_keys_str_mv AT istominaaigulsalavatovna polymerbindersfortheelectrodesoflithiumbatteriespart3conductivepolymers
AT bushkovaolgaviktorovna polymerbindersfortheelectrodesoflithiumbatteriespart3conductivepolymers