Direct Determination Of γ′ / γ′+γ / γ Phase Boundaries In Ni-Al-Cr System Based On Enthalpy Of Formation Results Obtained By Calorimetric Solution Method
The work is a continuation of the research carried out on a high-temperature calorimeter solution type on alloys from Ni-Al-Cr system. Thanks to the construction innovation introduced by authors the device allows the determination of the formation enthalpy of alloys at ambient and elevated temperatu...
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Language: | English |
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Polish Academy of Sciences
2015-09-01
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Series: | Archives of Metallurgy and Materials |
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Online Access: | http://www.degruyter.com/view/j/amm.2015.60.issue-3/amm-2015-0288/amm-2015-0288.xml?format=INT |
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author | Maciąg T. Rzyman K. Węcki B. |
author_facet | Maciąg T. Rzyman K. Węcki B. |
author_sort | Maciąg T. |
collection | DOAJ |
description | The work is a continuation of the research carried out on a high-temperature calorimeter solution type on alloys from Ni-Al-Cr system. Thanks to the construction innovation introduced by authors the device allows the determination of the formation enthalpy of alloys at ambient and elevated temperatures. Experiments described in this article were carried out at three temperatures: 873K, 996K and 1150K on the alloys of the chemical compositions from the Ni75Al25 ÷ Ni87Cr13 section of the Ni-Al-Cr system. On the basis of changes in the enthalpy of formation with increasing chromium content of the alloys, points corresponding to places of phase boundaries γ′ / γ′+γ / γ in Ni-Al-Cr system were determined. A similar relationship was observed in previous studies of alloys from Ni75Al25÷Ni75Cr25 section. For precise determination of these characteristic points a statistical model was applied |
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issn | 2300-1909 |
language | English |
last_indexed | 2024-04-12T07:39:07Z |
publishDate | 2015-09-01 |
publisher | Polish Academy of Sciences |
record_format | Article |
series | Archives of Metallurgy and Materials |
spelling | doaj.art-a7bda96a1428417490ee00b6de6b84a82022-12-22T03:41:51ZengPolish Academy of SciencesArchives of Metallurgy and Materials2300-19092015-09-016031657166210.1515/amm-2015-0288amm-2015-0288Direct Determination Of γ′ / γ′+γ / γ Phase Boundaries In Ni-Al-Cr System Based On Enthalpy Of Formation Results Obtained By Calorimetric Solution MethodMaciąg T.0Rzyman K.1Węcki B.2 SILESIAN UNIVERSITY OF TECHNOLOGY, FACULTY OF MATERIALS ENGINEERING AND METALLURGY, INSTITUTE OF METALS TECHNOLOGY, KRASIŃSKIEGO 8, 40-019 KATOWICE (POLAND) SILESIAN UNIVERSITY OF TECHNOLOGY, FACULTY OF MATERIALS ENGINEERING AND METALLURGY, INSTITUTE OF METALS TECHNOLOGY, KRASIŃSKIEGO 8, 40-019 KATOWICE (POLAND) SILESIAN UNIVERSITY OF TECHNOLOGY, FACULTY OF MATERIALS ENGINEERING AND METALLURGY, INSTITUTE OF METALS TECHNOLOGY, KRASIŃSKIEGO 8, 40-019 KATOWICE (POLAND)The work is a continuation of the research carried out on a high-temperature calorimeter solution type on alloys from Ni-Al-Cr system. Thanks to the construction innovation introduced by authors the device allows the determination of the formation enthalpy of alloys at ambient and elevated temperatures. Experiments described in this article were carried out at three temperatures: 873K, 996K and 1150K on the alloys of the chemical compositions from the Ni75Al25 ÷ Ni87Cr13 section of the Ni-Al-Cr system. On the basis of changes in the enthalpy of formation with increasing chromium content of the alloys, points corresponding to places of phase boundaries γ′ / γ′+γ / γ in Ni-Al-Cr system were determined. A similar relationship was observed in previous studies of alloys from Ni75Al25÷Ni75Cr25 section. For precise determination of these characteristic points a statistical model was appliedhttp://www.degruyter.com/view/j/amm.2015.60.issue-3/amm-2015-0288/amm-2015-0288.xml?format=INTsolution calorimetryenthalpy of formationintermetallic phasephase boundary |
spellingShingle | Maciąg T. Rzyman K. Węcki B. Direct Determination Of γ′ / γ′+γ / γ Phase Boundaries In Ni-Al-Cr System Based On Enthalpy Of Formation Results Obtained By Calorimetric Solution Method Archives of Metallurgy and Materials solution calorimetry enthalpy of formation intermetallic phase phase boundary |
title | Direct Determination Of γ′ / γ′+γ / γ Phase Boundaries In Ni-Al-Cr System Based On Enthalpy Of Formation Results Obtained By Calorimetric Solution Method |
title_full | Direct Determination Of γ′ / γ′+γ / γ Phase Boundaries In Ni-Al-Cr System Based On Enthalpy Of Formation Results Obtained By Calorimetric Solution Method |
title_fullStr | Direct Determination Of γ′ / γ′+γ / γ Phase Boundaries In Ni-Al-Cr System Based On Enthalpy Of Formation Results Obtained By Calorimetric Solution Method |
title_full_unstemmed | Direct Determination Of γ′ / γ′+γ / γ Phase Boundaries In Ni-Al-Cr System Based On Enthalpy Of Formation Results Obtained By Calorimetric Solution Method |
title_short | Direct Determination Of γ′ / γ′+γ / γ Phase Boundaries In Ni-Al-Cr System Based On Enthalpy Of Formation Results Obtained By Calorimetric Solution Method |
title_sort | direct determination of γ γ γ γ phase boundaries in ni al cr system based on enthalpy of formation results obtained by calorimetric solution method |
topic | solution calorimetry enthalpy of formation intermetallic phase phase boundary |
url | http://www.degruyter.com/view/j/amm.2015.60.issue-3/amm-2015-0288/amm-2015-0288.xml?format=INT |
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