Combined Effect of Pressure and Temperature on Rheological Properties of Water-in-crude Oil Emulsions

The rheological behavior of emulsions has been extensively investigated through experiments made at atmospheric pressure. This study presents a new experimental characterization of these fluids with measurements performed under pressure and in a large range of temperature. The results show that visc...

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Main Authors: Chaudemanche C., Henaut I., Argillier J-F.
Format: Article
Language:English
Published: De Gruyter 2009-12-01
Series:Applied Rheology
Subjects:
Online Access:https://doi.org/10.3933/applrheol-19-62210
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author Chaudemanche C.
Henaut I.
Argillier J-F.
author_facet Chaudemanche C.
Henaut I.
Argillier J-F.
author_sort Chaudemanche C.
collection DOAJ
description The rheological behavior of emulsions has been extensively investigated through experiments made at atmospheric pressure. This study presents a new experimental characterization of these fluids with measurements performed under pressure and in a large range of temperature. The results show that viscosities obey Barus model that predicts an exponential increase with pressure. The extent of the increase is governed by a unique piezoviscous coefficient. This coefficient exhibits a non monotonous variation with temperature. It has been shown that its thermal dependence and its value can be related to the viscoelastic properties of the fluid. The coefficient is an increasing function of temperature for a solid-like behaviour and a decreasing function of temperature for a liquid-like behaviour. This approach has been applied to heavy crude oils. It has been demonstrated that water droplets and oil composition modify the elastic character of heavy crude oils and as a consequence they modify their piezoviscosity.
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spelling doaj.art-a7c5ce1ab3f14b50b257fad5e6e052a22022-12-21T21:33:58ZengDe GruyterApplied Rheology1617-81062009-12-0119662210-162210-810.3933/applrheol-19-62210Combined Effect of Pressure and Temperature on Rheological Properties of Water-in-crude Oil EmulsionsChaudemanche C.0Henaut I.1Argillier J-F.2Institut Français du Pétrole (IFP), 1 et 4 avenue de Bois-Préau, 92852Rueil – Malmaison Cedex, FranceInstitut Français du Pétrole (IFP), 1 et 4 avenue de Bois-Préau, 92852Rueil – Malmaison Cedex, FranceInstitut Français du Pétrole (IFP), 1 et 4 avenue de Bois-Préau, 92852Rueil – Malmaison Cedex, FranceThe rheological behavior of emulsions has been extensively investigated through experiments made at atmospheric pressure. This study presents a new experimental characterization of these fluids with measurements performed under pressure and in a large range of temperature. The results show that viscosities obey Barus model that predicts an exponential increase with pressure. The extent of the increase is governed by a unique piezoviscous coefficient. This coefficient exhibits a non monotonous variation with temperature. It has been shown that its thermal dependence and its value can be related to the viscoelastic properties of the fluid. The coefficient is an increasing function of temperature for a solid-like behaviour and a decreasing function of temperature for a liquid-like behaviour. This approach has been applied to heavy crude oils. It has been demonstrated that water droplets and oil composition modify the elastic character of heavy crude oils and as a consequence they modify their piezoviscosity.https://doi.org/10.3933/applrheol-19-62210emulsionspiezodependenceviscoelastic propertiesheavy oils
spellingShingle Chaudemanche C.
Henaut I.
Argillier J-F.
Combined Effect of Pressure and Temperature on Rheological Properties of Water-in-crude Oil Emulsions
Applied Rheology
emulsions
piezodependence
viscoelastic properties
heavy oils
title Combined Effect of Pressure and Temperature on Rheological Properties of Water-in-crude Oil Emulsions
title_full Combined Effect of Pressure and Temperature on Rheological Properties of Water-in-crude Oil Emulsions
title_fullStr Combined Effect of Pressure and Temperature on Rheological Properties of Water-in-crude Oil Emulsions
title_full_unstemmed Combined Effect of Pressure and Temperature on Rheological Properties of Water-in-crude Oil Emulsions
title_short Combined Effect of Pressure and Temperature on Rheological Properties of Water-in-crude Oil Emulsions
title_sort combined effect of pressure and temperature on rheological properties of water in crude oil emulsions
topic emulsions
piezodependence
viscoelastic properties
heavy oils
url https://doi.org/10.3933/applrheol-19-62210
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