{N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II)
The molecule of the title compound, [Mn(NCS)2(C16H18N4)], has crystallographic twofold rotation symmetry, with the MnII atom lying on the rotation axis. The MnII atom is six-coordinated by four N atoms of the Schiff base ligand and by two N atoms of two thiocyanate ligands, forming a distorted octah...
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Format: | Article |
Language: | English |
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International Union of Crystallography
2010-07-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810021550 |
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author | Fu-Ming Wang |
author_facet | Fu-Ming Wang |
author_sort | Fu-Ming Wang |
collection | DOAJ |
description | The molecule of the title compound, [Mn(NCS)2(C16H18N4)], has crystallographic twofold rotation symmetry, with the MnII atom lying on the rotation axis. The MnII atom is six-coordinated by four N atoms of the Schiff base ligand and by two N atoms of two thiocyanate ligands, forming a distorted octahedral geometry. |
first_indexed | 2024-12-20T06:01:49Z |
format | Article |
id | doaj.art-a7d5bdf4d2cc42cfbad2bd0ef2930f56 |
institution | Directory Open Access Journal |
issn | 1600-5368 |
language | English |
last_indexed | 2024-12-20T06:01:49Z |
publishDate | 2010-07-01 |
publisher | International Union of Crystallography |
record_format | Article |
series | Acta Crystallographica Section E |
spelling | doaj.art-a7d5bdf4d2cc42cfbad2bd0ef2930f562022-12-21T19:50:54ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-07-01667m776m77610.1107/S1600536810021550{N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II)Fu-Ming WangThe molecule of the title compound, [Mn(NCS)2(C16H18N4)], has crystallographic twofold rotation symmetry, with the MnII atom lying on the rotation axis. The MnII atom is six-coordinated by four N atoms of the Schiff base ligand and by two N atoms of two thiocyanate ligands, forming a distorted octahedral geometry.http://scripts.iucr.org/cgi-bin/paper?S1600536810021550 |
spellingShingle | Fu-Ming Wang {N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II) Acta Crystallographica Section E |
title | {N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II) |
title_full | {N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II) |
title_fullStr | {N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II) |
title_full_unstemmed | {N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II) |
title_short | {N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II) |
title_sort | n n amp 8242 bis 1 2 pyridyl ethylidene ethane 1 2 diamine amp 954 4n n amp 8242 n amp 8242 amp 8242 n amp 8242 amp 8242 amp 8242 bis thiocyanato amp 954 n manganese ii |
url | http://scripts.iucr.org/cgi-bin/paper?S1600536810021550 |
work_keys_str_mv | AT fumingwang nnamp8242bis12pyridylethylideneethane12diamineamp9544nnamp8242namp8242amp8242namp8242amp8242amp8242bisthiocyanatoamp954nmanganeseii |