{N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II)

The molecule of the title compound, [Mn(NCS)2(C16H18N4)], has crystallographic twofold rotation symmetry, with the MnII atom lying on the rotation axis. The MnII atom is six-coordinated by four N atoms of the Schiff base ligand and by two N atoms of two thiocyanate ligands, forming a distorted octah...

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Main Author: Fu-Ming Wang
Format: Article
Language:English
Published: International Union of Crystallography 2010-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810021550
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author Fu-Ming Wang
author_facet Fu-Ming Wang
author_sort Fu-Ming Wang
collection DOAJ
description The molecule of the title compound, [Mn(NCS)2(C16H18N4)], has crystallographic twofold rotation symmetry, with the MnII atom lying on the rotation axis. The MnII atom is six-coordinated by four N atoms of the Schiff base ligand and by two N atoms of two thiocyanate ligands, forming a distorted octahedral geometry.
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spelling doaj.art-a7d5bdf4d2cc42cfbad2bd0ef2930f562022-12-21T19:50:54ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-07-01667m776m77610.1107/S1600536810021550{N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II)Fu-Ming WangThe molecule of the title compound, [Mn(NCS)2(C16H18N4)], has crystallographic twofold rotation symmetry, with the MnII atom lying on the rotation axis. The MnII atom is six-coordinated by four N atoms of the Schiff base ligand and by two N atoms of two thiocyanate ligands, forming a distorted octahedral geometry.http://scripts.iucr.org/cgi-bin/paper?S1600536810021550
spellingShingle Fu-Ming Wang
{N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II)
Acta Crystallographica Section E
title {N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II)
title_full {N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II)
title_fullStr {N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II)
title_full_unstemmed {N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II)
title_short {N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II)
title_sort n n amp 8242 bis 1 2 pyridyl ethylidene ethane 1 2 diamine amp 954 4n n amp 8242 n amp 8242 amp 8242 n amp 8242 amp 8242 amp 8242 bis thiocyanato amp 954 n manganese ii
url http://scripts.iucr.org/cgi-bin/paper?S1600536810021550
work_keys_str_mv AT fumingwang nnamp8242bis12pyridylethylideneethane12diamineamp9544nnamp8242namp8242amp8242namp8242amp8242amp8242bisthiocyanatoamp954nmanganeseii