ACETAMIDE COMPLEXES FOR CHLORIDES AND BROMIDES OF SOME LANTHANIDES: SYNTHESIS AND PROPERTIES
The aim of the this work is the synthesis and study (IR, single crystal XRD, DTG) of complex compounds of chlorides and bromides of lanthanum, neodymium, holmium, and erbium with acetamide [Ln(AA)4(H2O)4]Cl3·H2O (Ln = La, Nd, Ho, Er ) and [La(AA)4(H2O)4]Br3·H2O. Ligands (Ln) coordination occurs thro...
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| Format: | Article |
| Language: | Russian |
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MIREA - Russian Technological University
2016-08-01
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| Series: | Тонкие химические технологии |
| Subjects: | |
| Online Access: | https://www.finechem-mirea.ru/jour/article/view/38 |
| _version_ | 1797882058979147776 |
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| author | L. Yu. Alikberova D. V. Albov P. S. Kibalnikov M. I. Vergeles G. A. Fedorova E. V. Volchkova |
| author_facet | L. Yu. Alikberova D. V. Albov P. S. Kibalnikov M. I. Vergeles G. A. Fedorova E. V. Volchkova |
| author_sort | L. Yu. Alikberova |
| collection | DOAJ |
| description | The aim of the this work is the synthesis and study (IR, single crystal XRD, DTG) of complex compounds of chlorides and bromides of lanthanum, neodymium, holmium, and erbium with acetamide [Ln(AA)4(H2O)4]Cl3·H2O (Ln = La, Nd, Ho, Er ) and [La(AA)4(H2O)4]Br3·H2O. Ligands (Ln) coordination occurs through the oxygen atoms, and the coordination polyhedra of the Ln atoms are distorted tetragonal antiprisms or two-capped trigonal prisms (CN = 8). All the studied complexes are characterized by a developed system of hydrogen bonds with the bromide or chloride ions (and outer-sphere water molecules) in the cavities of the structure formed by the complex cations. The features of the complexes thermal decomposition are discussed. |
| first_indexed | 2024-04-10T03:28:53Z |
| format | Article |
| id | doaj.art-a7db547f9885402a8c0ca5df972f3337 |
| institution | Directory Open Access Journal |
| issn | 2410-6593 2686-7575 |
| language | Russian |
| last_indexed | 2024-04-10T03:28:53Z |
| publishDate | 2016-08-01 |
| publisher | MIREA - Russian Technological University |
| record_format | Article |
| series | Тонкие химические технологии |
| spelling | doaj.art-a7db547f9885402a8c0ca5df972f33372023-03-13T07:25:37ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752016-08-01114434910.32362/2410-6593-2016-11-4-43-4938ACETAMIDE COMPLEXES FOR CHLORIDES AND BROMIDES OF SOME LANTHANIDES: SYNTHESIS AND PROPERTIESL. Yu. Alikberova0D. V. Albov1P. S. Kibalnikov2M. I. Vergeles3G. A. Fedorova4E. V. Volchkova5Moscow Technological University (Institute of Fine Chemical Technologies)Lomonosov Moscow State UniversityMoscow Technological University (Institute of Fine Chemical Technologies)Moscow Technological University (Institute of Fine Chemical Technologies)Moscow Technological University (Institute of Fine Chemical Technologies)Moscow Technological University (Institute of Fine Chemical Technologies)The aim of the this work is the synthesis and study (IR, single crystal XRD, DTG) of complex compounds of chlorides and bromides of lanthanum, neodymium, holmium, and erbium with acetamide [Ln(AA)4(H2O)4]Cl3·H2O (Ln = La, Nd, Ho, Er ) and [La(AA)4(H2O)4]Br3·H2O. Ligands (Ln) coordination occurs through the oxygen atoms, and the coordination polyhedra of the Ln atoms are distorted tetragonal antiprisms or two-capped trigonal prisms (CN = 8). All the studied complexes are characterized by a developed system of hydrogen bonds with the bromide or chloride ions (and outer-sphere water molecules) in the cavities of the structure formed by the complex cations. The features of the complexes thermal decomposition are discussed.https://www.finechem-mirea.ru/jour/article/view/38tlanthanumneodymiumholmiumerbiumchloridebromideacetamidecomplexesstructure |
| spellingShingle | L. Yu. Alikberova D. V. Albov P. S. Kibalnikov M. I. Vergeles G. A. Fedorova E. V. Volchkova ACETAMIDE COMPLEXES FOR CHLORIDES AND BROMIDES OF SOME LANTHANIDES: SYNTHESIS AND PROPERTIES Тонкие химические технологии tlanthanum neodymium holmium erbium chloride bromide acetamide complexes structure |
| title | ACETAMIDE COMPLEXES FOR CHLORIDES AND BROMIDES OF SOME LANTHANIDES: SYNTHESIS AND PROPERTIES |
| title_full | ACETAMIDE COMPLEXES FOR CHLORIDES AND BROMIDES OF SOME LANTHANIDES: SYNTHESIS AND PROPERTIES |
| title_fullStr | ACETAMIDE COMPLEXES FOR CHLORIDES AND BROMIDES OF SOME LANTHANIDES: SYNTHESIS AND PROPERTIES |
| title_full_unstemmed | ACETAMIDE COMPLEXES FOR CHLORIDES AND BROMIDES OF SOME LANTHANIDES: SYNTHESIS AND PROPERTIES |
| title_short | ACETAMIDE COMPLEXES FOR CHLORIDES AND BROMIDES OF SOME LANTHANIDES: SYNTHESIS AND PROPERTIES |
| title_sort | acetamide complexes for chlorides and bromides of some lanthanides synthesis and properties |
| topic | tlanthanum neodymium holmium erbium chloride bromide acetamide complexes structure |
| url | https://www.finechem-mirea.ru/jour/article/view/38 |
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