Synthesis and homopolymerization kinetics of 7-(methacroyloxy)-2-oxo-heptylphosphonic acid and its copolymerization with methyl methacrylate

Synthesis and homopolymerization kinetics of 7-(methacroyloxy)-2-oxo-heptylphosphonic acid and its copolymerization with methyl methacrylate

The synthesis of polymerizable 7-(methacroyloxy)-2-oxo-heptylphosphonic acid M1 destined for self-etch adhesives is described. M1 is characterized by 1H, 13C and 31P-NMR spectroscopy. Its homopolymerization and copolymerization reactivity in the solvents methanol and dioxane between 45 and 70°C in t...

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Bibliographic Details
Main Authors: Štefan Chmela, Agnesa Fiedlerová, Tibor Liptaj, Yohann Catel, Norbert Moszner
Format: Article
Language:English
Published: Taylor & Francis Group 2019-01-01
Series:Designed Monomers and Polymers
Subjects:
adhesives
dental polymers
radical polymerizations
copolymerization parameters
Online Access:http://dx.doi.org/10.1080/15685551.2019.1582216

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