4-(Dimethylamino)pyridinium trichlorido[4-(dimethylamino)pyridine-κN]cobaltate(II)
In the anion of the title compound, (C7H11N2)[CoCl3(C7H10N2)], the CoII ion is coordinated by one N atom from a 4-(dimethylamino)pyridine (DMAP) ligand and three Cl atoms, forming a CoNCl3 polyhedron with a distorted tetrahedral geometry. In the crystal, cations and anions are linked via weak N&...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2013-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813015602 |
| _version_ | 1831692175213068288 |
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| author | Fatiha Guenifa Nasreddine Hadjadj Ouahida Zeghouan Lamia Bendjeddou Hocine Merazig |
| author_facet | Fatiha Guenifa Nasreddine Hadjadj Ouahida Zeghouan Lamia Bendjeddou Hocine Merazig |
| author_sort | Fatiha Guenifa |
| collection | DOAJ |
| description | In the anion of the title compound, (C7H11N2)[CoCl3(C7H10N2)], the CoII ion is coordinated by one N atom from a 4-(dimethylamino)pyridine (DMAP) ligand and three Cl atoms, forming a CoNCl3 polyhedron with a distorted tetrahedral geometry. In the crystal, cations and anions are linked via weak N—H...Cl and C—H...Cl hydrogen bonds. Double layers of complex anions stack along the b- axis direction, which alternate with double layers of 4-(dimethylamino)-pyridinium cations. |
| first_indexed | 2024-12-20T11:46:40Z |
| format | Article |
| id | doaj.art-a8067158f17d4f1bbe934e624d12da68 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:46:40Z |
| publishDate | 2013-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-a8067158f17d4f1bbe934e624d12da682022-12-21T19:41:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-07-01697m379m38010.1107/S16005368130156024-(Dimethylamino)pyridinium trichlorido[4-(dimethylamino)pyridine-κN]cobaltate(II)Fatiha GuenifaNasreddine HadjadjOuahida ZeghouanLamia BendjeddouHocine MerazigIn the anion of the title compound, (C7H11N2)[CoCl3(C7H10N2)], the CoII ion is coordinated by one N atom from a 4-(dimethylamino)pyridine (DMAP) ligand and three Cl atoms, forming a CoNCl3 polyhedron with a distorted tetrahedral geometry. In the crystal, cations and anions are linked via weak N—H...Cl and C—H...Cl hydrogen bonds. Double layers of complex anions stack along the b- axis direction, which alternate with double layers of 4-(dimethylamino)-pyridinium cations.http://scripts.iucr.org/cgi-bin/paper?S1600536813015602 |
| spellingShingle | Fatiha Guenifa Nasreddine Hadjadj Ouahida Zeghouan Lamia Bendjeddou Hocine Merazig 4-(Dimethylamino)pyridinium trichlorido[4-(dimethylamino)pyridine-κN]cobaltate(II) Acta Crystallographica Section E |
| title | 4-(Dimethylamino)pyridinium trichlorido[4-(dimethylamino)pyridine-κN]cobaltate(II) |
| title_full | 4-(Dimethylamino)pyridinium trichlorido[4-(dimethylamino)pyridine-κN]cobaltate(II) |
| title_fullStr | 4-(Dimethylamino)pyridinium trichlorido[4-(dimethylamino)pyridine-κN]cobaltate(II) |
| title_full_unstemmed | 4-(Dimethylamino)pyridinium trichlorido[4-(dimethylamino)pyridine-κN]cobaltate(II) |
| title_short | 4-(Dimethylamino)pyridinium trichlorido[4-(dimethylamino)pyridine-κN]cobaltate(II) |
| title_sort | 4 dimethylamino pyridinium trichlorido 4 dimethylamino pyridine 954 n cobaltate ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813015602 |
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