Atom Transfer Radical Addition via Dual Photoredox/Manganese Catalytic System
Atom transfer radical addition of bromonitromethane and 1,2-dibromotetrafluoroethane to alkenes is described. The reaction is performed under blue light irradiation using two catalysts: 4CzIPN and manganese (II) bromide. The cyanoarene photocatalyst serves for the redox activation of starting organi...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2023-07-01
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| Series: | Catalysts |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2073-4344/13/7/1126 |
| _version_ | 1797589914078937088 |
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| author | Vladislav S. Kostromitin Vitalij V. Levin Alexander D. Dilman |
| author_facet | Vladislav S. Kostromitin Vitalij V. Levin Alexander D. Dilman |
| author_sort | Vladislav S. Kostromitin |
| collection | DOAJ |
| description | Atom transfer radical addition of bromonitromethane and 1,2-dibromotetrafluoroethane to alkenes is described. The reaction is performed under blue light irradiation using two catalysts: 4CzIPN and manganese (II) bromide. The cyanoarene photocatalyst serves for the redox activation of starting organic bromide, while the manganese salt facilitates the trapping of the alkyl radical with the formation of the carbon–bromine bond. |
| first_indexed | 2024-03-11T01:12:52Z |
| format | Article |
| id | doaj.art-a80a69a40e2c4a54a65168fd0f135d7a |
| institution | Directory Open Access Journal |
| issn | 2073-4344 |
| language | English |
| last_indexed | 2024-03-11T01:12:52Z |
| publishDate | 2023-07-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Catalysts |
| spelling | doaj.art-a80a69a40e2c4a54a65168fd0f135d7a2023-11-18T18:45:08ZengMDPI AGCatalysts2073-43442023-07-01137112610.3390/catal13071126Atom Transfer Radical Addition via Dual Photoredox/Manganese Catalytic SystemVladislav S. Kostromitin0Vitalij V. Levin1Alexander D. Dilman2N. D. Zelinsky Institute of Organic Chemistry, Leninsky Prosp. 47, 119991 Moscow, RussiaN. D. Zelinsky Institute of Organic Chemistry, Leninsky Prosp. 47, 119991 Moscow, RussiaN. D. Zelinsky Institute of Organic Chemistry, Leninsky Prosp. 47, 119991 Moscow, RussiaAtom transfer radical addition of bromonitromethane and 1,2-dibromotetrafluoroethane to alkenes is described. The reaction is performed under blue light irradiation using two catalysts: 4CzIPN and manganese (II) bromide. The cyanoarene photocatalyst serves for the redox activation of starting organic bromide, while the manganese salt facilitates the trapping of the alkyl radical with the formation of the carbon–bromine bond.https://www.mdpi.com/2073-4344/13/7/1126atom transferradical reactionsorganofluorinephotocatalysis |
| spellingShingle | Vladislav S. Kostromitin Vitalij V. Levin Alexander D. Dilman Atom Transfer Radical Addition via Dual Photoredox/Manganese Catalytic System Catalysts atom transfer radical reactions organofluorine photocatalysis |
| title | Atom Transfer Radical Addition via Dual Photoredox/Manganese Catalytic System |
| title_full | Atom Transfer Radical Addition via Dual Photoredox/Manganese Catalytic System |
| title_fullStr | Atom Transfer Radical Addition via Dual Photoredox/Manganese Catalytic System |
| title_full_unstemmed | Atom Transfer Radical Addition via Dual Photoredox/Manganese Catalytic System |
| title_short | Atom Transfer Radical Addition via Dual Photoredox/Manganese Catalytic System |
| title_sort | atom transfer radical addition via dual photoredox manganese catalytic system |
| topic | atom transfer radical reactions organofluorine photocatalysis |
| url | https://www.mdpi.com/2073-4344/13/7/1126 |
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