Kinetika Adsorpsi Mikrokapsul Kitosan Taut Silang Kalium Persulfat terhadap Zat Warna Methyl Orange

Dyes, typically available in textile and paper industries, can cause an aesthetical issue in their wastewater stream even in its low concentration Some colors are considered toxic to the environment and even carcinogenic. In that sense, the adsorption using chitosan, might be an alternative method o...

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Main Authors: Endang Sulistyawati, Wibiana Wulan Nandari, Arifa Rahma Nurchasanah, Kurnia Kumala Dewi
Format: Article
Language:English
Published: Universitas Gadjah Mada 2020-06-01
Series:Jurnal Rekayasa Proses
Subjects:
Online Access:https://jurnal.ugm.ac.id/jrekpros/article/view/50634
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author Endang Sulistyawati
Wibiana Wulan Nandari
Arifa Rahma Nurchasanah
Kurnia Kumala Dewi
author_facet Endang Sulistyawati
Wibiana Wulan Nandari
Arifa Rahma Nurchasanah
Kurnia Kumala Dewi
author_sort Endang Sulistyawati
collection DOAJ
description Dyes, typically available in textile and paper industries, can cause an aesthetical issue in their wastewater stream even in its low concentration Some colors are considered toxic to the environment and even carcinogenic. In that sense, the adsorption using chitosan, might be an alternative method offering better environmental quality by its capability for eliminating the dyes from the waste stream. This research was aimed to study the adsorption kinetics of methyl orange dyes in the presence of chitosan microcapsules, employing the measurement of concentration concerning time over several measured temperatures of 40, 50, and 60 °C. Chitosan microcapsules originated from abundantly available organic materials, have been synthesized by the support of potassium persulfate as a cross-linker through ionic gelation and solvent evaporation method. The microcapsules were subjected to Fourier transform infrared (FTIR) spectroscopy and scanning electron microscopy (SEM) characterizations, while UV-Vis was utilized for observing dye concentration changes. The results showed that chitosan microcapsules had been successfully prepared with a deacetylation degree of 53.92 % and a grain diameter of 1246 μm. The adsorption adapted the chemisorption mechanism with endothermic behavior. Besides, its kinetics seemed to follow the Lagergren pseudo-second-order equation with the value of the kinetic constant suitable for the tested temperature, following the Arrhenius equation.   A B S T R A K Zat pewarna yang banyak ditemukan di industri tekstil dan kertas, cenderung menyebabkan masalah estetika dalam aliran air limbah meskipun dalam jumlah rendah. Beberapa zat pewarna bersifat racun bagi lingkungan dan bahkan ada yang tergolong zat karsinogen. Adsorpsi, terutama dengan memanfaatkan kitosan, dapat digunakan sebagai metode alternatif yang memberikan kualitas lingkungan yang lebih baik dalam menghilangkan zat warna dari aliran limbah. Penelitian ini bertujuan untuk mempelajari kinetika adsorpsi pewarna metil oranye menggunakan kitosan dalam bentuk mikrokapsul, dengan mengamati perubahan konsentrasi sebagai fungsi waktu pada beberapa suhu teruji yaitu 40, 50, dan 60 °C. Mikrokapsul kitosan berasal dari bahan organik yang tersedia berlimpah dan disintesis dengan bantuan kalium persulfat sebagai penaut silang dengan menggunakan metode gelasi ionik dan metode penguapan pelarut. Karakteristik mikrokapsul dianalisis menggunakan spektroskopi Fourier transform infrared (FT-IR) dan scanning electron microscopy (SEM), sedangkan UV-Vis digunakan untuk mengamati perubahan konsentrasi zat warna. Hasil penelitian menunjukkan, mikrokapsul kitosan yang berhasil disintesis mempunyai derajat deasetilasi 53,92% dan diameter butir sekitar 1246 μm. Adsorpsi mengikuti mekanisme kemisorpsi dengan perilaku endotermik. Persamaan kinetik mengikuti persamaan Lagergren orde dua-semu dengan nilai konstanta kinetik untuk suhu yang diuji mengikuti persamaan Arrhenius.
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spelling doaj.art-a80b7afe132b462da3d1619b41a4058a2022-12-21T21:27:50ZengUniversitas Gadjah MadaJurnal Rekayasa Proses1978-287X2549-14902020-06-0114110.22146/jrekpros.5063427093Kinetika Adsorpsi Mikrokapsul Kitosan Taut Silang Kalium Persulfat terhadap Zat Warna Methyl OrangeEndang Sulistyawati0Wibiana Wulan Nandari1Arifa Rahma Nurchasanah2Kurnia Kumala Dewi3Program Studi Teknik Kimia, FTI, UPN “Veteran” Yogyakarta, Jl. SWK 104 (Lingkar Utara), Condongcatur, Yogyakarta – 55283Program Studi Teknik Kimia, FTI, UPN “Veteran” Yogyakarta, Jl. SWK 104 (Lingkar Utara), Condongcatur, Yogyakarta – 55283Program Studi Teknik Kimia, FTI, UPN “Veteran” Yogyakarta, Jl. SWK 104 (Lingkar Utara), Condongcatur, Yogyakarta – 55283Program Studi Teknik Kimia, FTI, UPN “Veteran” Yogyakarta, Jl. SWK 104 (Lingkar Utara), Condongcatur, Yogyakarta – 55283Dyes, typically available in textile and paper industries, can cause an aesthetical issue in their wastewater stream even in its low concentration Some colors are considered toxic to the environment and even carcinogenic. In that sense, the adsorption using chitosan, might be an alternative method offering better environmental quality by its capability for eliminating the dyes from the waste stream. This research was aimed to study the adsorption kinetics of methyl orange dyes in the presence of chitosan microcapsules, employing the measurement of concentration concerning time over several measured temperatures of 40, 50, and 60 °C. Chitosan microcapsules originated from abundantly available organic materials, have been synthesized by the support of potassium persulfate as a cross-linker through ionic gelation and solvent evaporation method. The microcapsules were subjected to Fourier transform infrared (FTIR) spectroscopy and scanning electron microscopy (SEM) characterizations, while UV-Vis was utilized for observing dye concentration changes. The results showed that chitosan microcapsules had been successfully prepared with a deacetylation degree of 53.92 % and a grain diameter of 1246 μm. The adsorption adapted the chemisorption mechanism with endothermic behavior. Besides, its kinetics seemed to follow the Lagergren pseudo-second-order equation with the value of the kinetic constant suitable for the tested temperature, following the Arrhenius equation.   A B S T R A K Zat pewarna yang banyak ditemukan di industri tekstil dan kertas, cenderung menyebabkan masalah estetika dalam aliran air limbah meskipun dalam jumlah rendah. Beberapa zat pewarna bersifat racun bagi lingkungan dan bahkan ada yang tergolong zat karsinogen. Adsorpsi, terutama dengan memanfaatkan kitosan, dapat digunakan sebagai metode alternatif yang memberikan kualitas lingkungan yang lebih baik dalam menghilangkan zat warna dari aliran limbah. Penelitian ini bertujuan untuk mempelajari kinetika adsorpsi pewarna metil oranye menggunakan kitosan dalam bentuk mikrokapsul, dengan mengamati perubahan konsentrasi sebagai fungsi waktu pada beberapa suhu teruji yaitu 40, 50, dan 60 °C. Mikrokapsul kitosan berasal dari bahan organik yang tersedia berlimpah dan disintesis dengan bantuan kalium persulfat sebagai penaut silang dengan menggunakan metode gelasi ionik dan metode penguapan pelarut. Karakteristik mikrokapsul dianalisis menggunakan spektroskopi Fourier transform infrared (FT-IR) dan scanning electron microscopy (SEM), sedangkan UV-Vis digunakan untuk mengamati perubahan konsentrasi zat warna. Hasil penelitian menunjukkan, mikrokapsul kitosan yang berhasil disintesis mempunyai derajat deasetilasi 53,92% dan diameter butir sekitar 1246 μm. Adsorpsi mengikuti mekanisme kemisorpsi dengan perilaku endotermik. Persamaan kinetik mengikuti persamaan Lagergren orde dua-semu dengan nilai konstanta kinetik untuk suhu yang diuji mengikuti persamaan Arrhenius.https://jurnal.ugm.ac.id/jrekpros/article/view/50634khemisorpsikitosanlagergrenmikrokapsulorde dua semutaut silang
spellingShingle Endang Sulistyawati
Wibiana Wulan Nandari
Arifa Rahma Nurchasanah
Kurnia Kumala Dewi
Kinetika Adsorpsi Mikrokapsul Kitosan Taut Silang Kalium Persulfat terhadap Zat Warna Methyl Orange
Jurnal Rekayasa Proses
khemisorpsi
kitosan
lagergren
mikrokapsul
orde dua semu
taut silang
title Kinetika Adsorpsi Mikrokapsul Kitosan Taut Silang Kalium Persulfat terhadap Zat Warna Methyl Orange
title_full Kinetika Adsorpsi Mikrokapsul Kitosan Taut Silang Kalium Persulfat terhadap Zat Warna Methyl Orange
title_fullStr Kinetika Adsorpsi Mikrokapsul Kitosan Taut Silang Kalium Persulfat terhadap Zat Warna Methyl Orange
title_full_unstemmed Kinetika Adsorpsi Mikrokapsul Kitosan Taut Silang Kalium Persulfat terhadap Zat Warna Methyl Orange
title_short Kinetika Adsorpsi Mikrokapsul Kitosan Taut Silang Kalium Persulfat terhadap Zat Warna Methyl Orange
title_sort kinetika adsorpsi mikrokapsul kitosan taut silang kalium persulfat terhadap zat warna methyl orange
topic khemisorpsi
kitosan
lagergren
mikrokapsul
orde dua semu
taut silang
url https://jurnal.ugm.ac.id/jrekpros/article/view/50634
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AT arifarahmanurchasanah kinetikaadsorpsimikrokapsulkitosantautsilangkaliumpersulfatterhadapzatwarnamethylorange
AT kurniakumaladewi kinetikaadsorpsimikrokapsulkitosantautsilangkaliumpersulfatterhadapzatwarnamethylorange