Photodecomposition of Chloro – oho ( Bis (Ortho - Hydrxohy Penzaldehyde) Ortho - Phenylene Piiminatio) Vanadium (v) Complex Organic Solvents
A new Schiff base complex was prepeard and characterized: Chloro –Oxo (bis(Ohydroxy benzaldehyde) O-phenylene di imination ) Vanadium (V) with general formula (VOLCL). Complex was studied by using Three different organics Organic The photo chemistry of this solvent with different polarity ....
| Main Author: | |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
University of Baghdad
2017-04-01
|
| Series: | Ibn Al-Haitham Journal for Pure and Applied Sciences |
| Subjects: | |
| Online Access: | https://jih.uobaghdad.edu.iq/index.php/j/article/view/377 |
| _version_ | 1811308209754865664 |
|---|---|
| author | Ala E. Sultan |
| author_facet | Ala E. Sultan |
| author_sort | Ala E. Sultan |
| collection | DOAJ |
| description |
A new Schiff base complex was prepeard and characterized: Chloro –Oxo (bis(Ohydroxy benzaldehyde) O-phenylene di imination ) Vanadium (V) with general formula (VOLCL). Complex was studied by using Three different organics Organic The photo chemistry of this solvent with different polarity . These solvents were ( Acetone,pyridinest chloro form) . It was found that the chelate Vanadium (V) complex decomposed photochemically in these solvents during . In the tra oxidation –reduction reaction leading to free radical derived in the ligand of shiff base ℓ .Vanadium IV chelate complex . It was also found that the quantum yield of photo decomposition (фd) and Activity ratio did not depend on the nature of solvent . The study revealed that the photo decomposition of complex was first order reaction and it is simply delected during the hemolytic scission of the band (V-CL) to produce free redical which is (CL) and give vanadium IV complex (VOL).
|
| first_indexed | 2024-04-13T09:18:02Z |
| format | Article |
| id | doaj.art-a81d2f1e3a674417a0082654e8a3c7a3 |
| institution | Directory Open Access Journal |
| issn | 1609-4042 2521-3407 |
| language | English |
| last_indexed | 2024-04-13T09:18:02Z |
| publishDate | 2017-04-01 |
| publisher | University of Baghdad |
| record_format | Article |
| series | Ibn Al-Haitham Journal for Pure and Applied Sciences |
| spelling | doaj.art-a81d2f1e3a674417a0082654e8a3c7a32022-12-22T02:52:41ZengUniversity of BaghdadIbn Al-Haitham Journal for Pure and Applied Sciences1609-40422521-34072017-04-01271Photodecomposition of Chloro – oho ( Bis (Ortho - Hydrxohy Penzaldehyde) Ortho - Phenylene Piiminatio) Vanadium (v) Complex Organic SolventsAla E. Sultan A new Schiff base complex was prepeard and characterized: Chloro –Oxo (bis(Ohydroxy benzaldehyde) O-phenylene di imination ) Vanadium (V) with general formula (VOLCL). Complex was studied by using Three different organics Organic The photo chemistry of this solvent with different polarity . These solvents were ( Acetone,pyridinest chloro form) . It was found that the chelate Vanadium (V) complex decomposed photochemically in these solvents during . In the tra oxidation –reduction reaction leading to free radical derived in the ligand of shiff base ℓ .Vanadium IV chelate complex . It was also found that the quantum yield of photo decomposition (фd) and Activity ratio did not depend on the nature of solvent . The study revealed that the photo decomposition of complex was first order reaction and it is simply delected during the hemolytic scission of the band (V-CL) to produce free redical which is (CL) and give vanadium IV complex (VOL). https://jih.uobaghdad.edu.iq/index.php/j/article/view/377(photodecompohipion , O- hydrxohy penzaldehyde , O- phenylene diiminatio- Organic Solvents) |
| spellingShingle | Ala E. Sultan Photodecomposition of Chloro – oho ( Bis (Ortho - Hydrxohy Penzaldehyde) Ortho - Phenylene Piiminatio) Vanadium (v) Complex Organic Solvents Ibn Al-Haitham Journal for Pure and Applied Sciences (photodecompohipion , O- hydrxohy penzaldehyde , O- phenylene diiminatio- Organic Solvents) |
| title | Photodecomposition of Chloro – oho ( Bis (Ortho - Hydrxohy Penzaldehyde) Ortho - Phenylene Piiminatio) Vanadium (v) Complex Organic Solvents |
| title_full | Photodecomposition of Chloro – oho ( Bis (Ortho - Hydrxohy Penzaldehyde) Ortho - Phenylene Piiminatio) Vanadium (v) Complex Organic Solvents |
| title_fullStr | Photodecomposition of Chloro – oho ( Bis (Ortho - Hydrxohy Penzaldehyde) Ortho - Phenylene Piiminatio) Vanadium (v) Complex Organic Solvents |
| title_full_unstemmed | Photodecomposition of Chloro – oho ( Bis (Ortho - Hydrxohy Penzaldehyde) Ortho - Phenylene Piiminatio) Vanadium (v) Complex Organic Solvents |
| title_short | Photodecomposition of Chloro – oho ( Bis (Ortho - Hydrxohy Penzaldehyde) Ortho - Phenylene Piiminatio) Vanadium (v) Complex Organic Solvents |
| title_sort | photodecomposition of chloro a€ oho bis ortho hydrxohy penzaldehyde ortho phenylene piiminatio vanadium v complex organic solvents |
| topic | (photodecompohipion , O- hydrxohy penzaldehyde , O- phenylene diiminatio- Organic Solvents) |
| url | https://jih.uobaghdad.edu.iq/index.php/j/article/view/377 |
| work_keys_str_mv | AT alaesultan photodecompositionofchloroaohobisorthohydrxohypenzaldehydeorthophenylenepiiminatiovanadiumvcomplexorganicsolvents |