Oxidative carbonylation of dimethylethinyl carbinol in oscillation mode.
In the system KI–PdI<sub>2</sub>–CO–O<sub>2</su>–CH<sub>3</sub>OH the oscillation mode of carbonylation reaction of a new substrate – dimethylethinylcarbinol – was found out. The limits of the initial concentrations...
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| Format: | Article |
| Language: | Russian |
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MIREA - Russian Technological University
2008-06-01
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| Series: | Тонкие химические технологии |
| Online Access: | https://www.finechem-mirea.ru/jour/article/view/1505 |
| _version_ | 1797882274657599488 |
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| author | S. N. Gorodsky A. V. Kurdiukov |
| author_facet | S. N. Gorodsky A. V. Kurdiukov |
| author_sort | S. N. Gorodsky |
| collection | DOAJ |
| description | In the system KI–PdI<sub>2</sub>–CO–O<sub>2</su>–CH<sub>3</sub>OH the oscillation mode of carbonylation reaction of a new substrate – dimethylethinylcarbinol – was found out. The limits of the initial concentrations of the catalytic system components and the composition of a gas mixture in which steady oscillations of platinum electrode potential (EPt) and pH are realized was preliminary outlined. |
| first_indexed | 2024-04-10T03:32:09Z |
| format | Article |
| id | doaj.art-a82677a85ebd43f2a3e0dd6a39e54612 |
| institution | Directory Open Access Journal |
| issn | 2410-6593 2686-7575 |
| language | Russian |
| last_indexed | 2024-04-10T03:32:09Z |
| publishDate | 2008-06-01 |
| publisher | MIREA - Russian Technological University |
| record_format | Article |
| series | Тонкие химические технологии |
| spelling | doaj.art-a82677a85ebd43f2a3e0dd6a39e546122023-03-13T07:25:29ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752008-06-013386891500Oxidative carbonylation of dimethylethinyl carbinol in oscillation mode.S. N. Gorodsky0A. V. KurdiukovМИТХТ им. М.В. Ломоносова, 119571, Москва, пр-т Вернадского, д. 86In the system KI–PdI<sub>2</sub>–CO–O<sub>2</su>–CH<sub>3</sub>OH the oscillation mode of carbonylation reaction of a new substrate – dimethylethinylcarbinol – was found out. The limits of the initial concentrations of the catalytic system components and the composition of a gas mixture in which steady oscillations of platinum electrode potential (EPt) and pH are realized was preliminary outlined.https://www.finechem-mirea.ru/jour/article/view/1505 |
| spellingShingle | S. N. Gorodsky A. V. Kurdiukov Oxidative carbonylation of dimethylethinyl carbinol in oscillation mode. Тонкие химические технологии |
| title | Oxidative carbonylation of dimethylethinyl carbinol in oscillation mode. |
| title_full | Oxidative carbonylation of dimethylethinyl carbinol in oscillation mode. |
| title_fullStr | Oxidative carbonylation of dimethylethinyl carbinol in oscillation mode. |
| title_full_unstemmed | Oxidative carbonylation of dimethylethinyl carbinol in oscillation mode. |
| title_short | Oxidative carbonylation of dimethylethinyl carbinol in oscillation mode. |
| title_sort | oxidative carbonylation of dimethylethinyl carbinol in oscillation mode |
| url | https://www.finechem-mirea.ru/jour/article/view/1505 |
| work_keys_str_mv | AT sngorodsky oxidativecarbonylationofdimethylethinylcarbinolinoscillationmode AT avkurdiukov oxidativecarbonylationofdimethylethinylcarbinolinoscillationmode |