| Summary: | This paper presents the development of composite silicate mass compositions based on man-made waste for the production of autoclave hardening products, as well as the results of physico-chemical studies of hydration products of silicate materials. The possibility, expediency and efficiency of using multi-tonnage technogenic waste of Kazakhstan in the industry of composite building materials is shown. Based on the results of the conducted research, the composition of a composite silicate mass based on burnt carbonate-barium tailings (8–12%), electrothermophosphoric slags (82–90%) or sand and dust from cement kiln electrofilters (2–5%) for the production of autoclave hardening products was developed. It was found that the cementing substance in composite silicate materials is represented by CSH(B) calcium silicate hydrates, tobermorite and serpentine. The simultaneous presence of fibrous and crystalline calcium and magnesium silicate hydrates in hydration products leads to the creation of composite products with a maximum strength of 41–49 MPa.
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