The Effect of Hydrogen on Pore Formation in Aluminum Alloy Castings: Myth Versus Reality

The solubility of hydrogen in liquid and solid aluminum is reviewed. Based on classical nucleation theory, it is shown that pores cannot nucleate either homogeneously or heterogeneously in liquid aluminum. Results of in situ studies on pore formation show that pores appear at low hydrogen supersatur...

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Main Author: Murat Tiryakioğlu
Format: Article
Language:English
Published: MDPI AG 2020-03-01
Series:Metals
Subjects:
Online Access:https://www.mdpi.com/2075-4701/10/3/368
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author Murat Tiryakioğlu
author_facet Murat Tiryakioğlu
author_sort Murat Tiryakioğlu
collection DOAJ
description The solubility of hydrogen in liquid and solid aluminum is reviewed. Based on classical nucleation theory, it is shown that pores cannot nucleate either homogeneously or heterogeneously in liquid aluminum. Results of in situ studies on pore formation show that pores appear at low hydrogen supersaturation levels, bypassing nucleation completely. The results are explained based on the bifilm theory introduced by Prof. John Campbell, as this theory is currently the most appropriate, and most likely, the only mechanism for pores to form. Examples for the effect of hydrogen on pore formation are given by using extreme data from the literature. It is concluded that a fundamental change in how hydrogen is viewed is needed in aluminum casting industry.
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spelling doaj.art-a88f9c8450c24fba97c415ce884d76b82022-12-21T18:15:05ZengMDPI AGMetals2075-47012020-03-0110336810.3390/met10030368met10030368The Effect of Hydrogen on Pore Formation in Aluminum Alloy Castings: Myth Versus RealityMurat Tiryakioğlu0Jacksonville University; Jacksonville, FL 32211, USAThe solubility of hydrogen in liquid and solid aluminum is reviewed. Based on classical nucleation theory, it is shown that pores cannot nucleate either homogeneously or heterogeneously in liquid aluminum. Results of in situ studies on pore formation show that pores appear at low hydrogen supersaturation levels, bypassing nucleation completely. The results are explained based on the bifilm theory introduced by Prof. John Campbell, as this theory is currently the most appropriate, and most likely, the only mechanism for pores to form. Examples for the effect of hydrogen on pore formation are given by using extreme data from the literature. It is concluded that a fundamental change in how hydrogen is viewed is needed in aluminum casting industry.https://www.mdpi.com/2075-4701/10/3/368supersaturationfracture pressurenucleationbifilm theoryjohn campbell
spellingShingle Murat Tiryakioğlu
The Effect of Hydrogen on Pore Formation in Aluminum Alloy Castings: Myth Versus Reality
Metals
supersaturation
fracture pressure
nucleation
bifilm theory
john campbell
title The Effect of Hydrogen on Pore Formation in Aluminum Alloy Castings: Myth Versus Reality
title_full The Effect of Hydrogen on Pore Formation in Aluminum Alloy Castings: Myth Versus Reality
title_fullStr The Effect of Hydrogen on Pore Formation in Aluminum Alloy Castings: Myth Versus Reality
title_full_unstemmed The Effect of Hydrogen on Pore Formation in Aluminum Alloy Castings: Myth Versus Reality
title_short The Effect of Hydrogen on Pore Formation in Aluminum Alloy Castings: Myth Versus Reality
title_sort effect of hydrogen on pore formation in aluminum alloy castings myth versus reality
topic supersaturation
fracture pressure
nucleation
bifilm theory
john campbell
url https://www.mdpi.com/2075-4701/10/3/368
work_keys_str_mv AT murattiryakioglu theeffectofhydrogenonporeformationinaluminumalloycastingsmythversusreality
AT murattiryakioglu effectofhydrogenonporeformationinaluminumalloycastingsmythversusreality