Diacetato[N,N′-bis(2-pyridylmethylidene)cyclohexane-1,2-diamine]manganese(II) hexahydrate
The asymmetric unit of the title compound, [Mn(C2H3O2)2(C18H20N4)]·6H2O, consists of a neutral MnII complex with six solvent water molecules. In the complex, the Mn2+ ion is eight-coordinated in a distorted square-antiprismatic environment by four N atoms from the tetradentate ligand N,N&am...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-03-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053680800353X |
| Summary: | The asymmetric unit of the title compound, [Mn(C2H3O2)2(C18H20N4)]·6H2O, consists of a neutral MnII complex with six solvent water molecules. In the complex, the Mn2+ ion is eight-coordinated in a distorted square-antiprismatic environment by four N atoms from the tetradentate ligand N,N′-bis(2-pyridylmethylidene)cyclohexane-1,2-diamine (bpic) and four O atoms from two acetate ligands. The compound displays intermolecular O—H...O hydrogen-bond interactions to form various kinds of ring structures and cyclic water clusters. |
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| ISSN: | 1600-5368 |