Diacetato[N,N′-bis(2-pyridylmethylidene)cyclohexane-1,2-diamine]manganese(II) hexahydrate
The asymmetric unit of the title compound, [Mn(C2H3O2)2(C18H20N4)]·6H2O, consists of a neutral MnII complex with six solvent water molecules. In the complex, the Mn2+ ion is eight-coordinated in a distorted square-antiprismatic environment by four N atoms from the tetradentate ligand N,N&am...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-03-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053680800353X |
| _version_ | 1828143632957308928 |
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| author | Kwang Ha In-Chul Hwang |
| author_facet | Kwang Ha In-Chul Hwang |
| author_sort | Kwang Ha |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, [Mn(C2H3O2)2(C18H20N4)]·6H2O, consists of a neutral MnII complex with six solvent water molecules. In the complex, the Mn2+ ion is eight-coordinated in a distorted square-antiprismatic environment by four N atoms from the tetradentate ligand N,N′-bis(2-pyridylmethylidene)cyclohexane-1,2-diamine (bpic) and four O atoms from two acetate ligands. The compound displays intermolecular O—H...O hydrogen-bond interactions to form various kinds of ring structures and cyclic water clusters. |
| first_indexed | 2024-04-11T20:01:33Z |
| format | Article |
| id | doaj.art-a8957431efcd452d83da8932b9ed0438 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T20:01:33Z |
| publishDate | 2008-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-a8957431efcd452d83da8932b9ed04382022-12-22T04:05:35ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-03-01643m453m45310.1107/S160053680800353XDiacetato[N,N′-bis(2-pyridylmethylidene)cyclohexane-1,2-diamine]manganese(II) hexahydrateKwang HaIn-Chul HwangThe asymmetric unit of the title compound, [Mn(C2H3O2)2(C18H20N4)]·6H2O, consists of a neutral MnII complex with six solvent water molecules. In the complex, the Mn2+ ion is eight-coordinated in a distorted square-antiprismatic environment by four N atoms from the tetradentate ligand N,N′-bis(2-pyridylmethylidene)cyclohexane-1,2-diamine (bpic) and four O atoms from two acetate ligands. The compound displays intermolecular O—H...O hydrogen-bond interactions to form various kinds of ring structures and cyclic water clusters.http://scripts.iucr.org/cgi-bin/paper?S160053680800353X |
| spellingShingle | Kwang Ha In-Chul Hwang Diacetato[N,N′-bis(2-pyridylmethylidene)cyclohexane-1,2-diamine]manganese(II) hexahydrate Acta Crystallographica Section E |
| title | Diacetato[N,N′-bis(2-pyridylmethylidene)cyclohexane-1,2-diamine]manganese(II) hexahydrate |
| title_full | Diacetato[N,N′-bis(2-pyridylmethylidene)cyclohexane-1,2-diamine]manganese(II) hexahydrate |
| title_fullStr | Diacetato[N,N′-bis(2-pyridylmethylidene)cyclohexane-1,2-diamine]manganese(II) hexahydrate |
| title_full_unstemmed | Diacetato[N,N′-bis(2-pyridylmethylidene)cyclohexane-1,2-diamine]manganese(II) hexahydrate |
| title_short | Diacetato[N,N′-bis(2-pyridylmethylidene)cyclohexane-1,2-diamine]manganese(II) hexahydrate |
| title_sort | diacetato n n 8242 bis 2 pyridylmethylidene cyclohexane 1 2 diamine manganese ii hexahydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053680800353X |
| work_keys_str_mv | AT kwangha diacetatonn8242bis2pyridylmethylidenecyclohexane12diaminemanganeseiihexahydrate AT inchulhwang diacetatonn8242bis2pyridylmethylidenecyclohexane12diaminemanganeseiihexahydrate |