Removal of Monovalent and Divalent Cations from Brine Water by Electrodialysis Using Modified Polyethersulfone Membranes
In electrodialysis, an ion exchange membrane removes unwanted ions from wastewater and toxic metal ions from effluents. Montmorillonite-based modified "polyethersulfone membranes" have been studied as a potential small-scale electrodialysis approach for removing ions from wastewater. The...
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| Format: | Article |
| Language: | English |
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Tikrit University
2024-01-01
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| Series: | Tikrit Journal of Engineering Sciences |
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| Online Access: | https://tj-es.com/ojs/index.php/tjes/article/view/1120 |
| _version_ | 1827368355194994688 |
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| author | Zainab A. Khalaf Sarah S. Mohammed Jawad |
| author_facet | Zainab A. Khalaf Sarah S. Mohammed Jawad |
| author_sort | Zainab A. Khalaf |
| collection | DOAJ |
| description |
In electrodialysis, an ion exchange membrane removes unwanted ions from wastewater and toxic metal ions from effluents. Montmorillonite-based modified "polyethersulfone membranes" have been studied as a potential small-scale electrodialysis approach for removing ions from wastewater. The study featured several steps, including solid polymerization, electrolyte balance, and removal of each component from the water. The study used three distinct “cation-exchange membranes (CEM)" types. The selected water body was diluted 100 times before being added to the electrodialysis cell in amounts of the center, cathodic, and anodic chambers, each containing 55, 30, and 40 mL. The initial pH for the real solutions of the water body was 7.16 at 25°C. Compared to "Sulfonated poly arylene ether sulfone (S-PESOS)" (23.23%) and Nafion® (35.34%), "hexamethylenediamine (HEXCl)" stands out as the only cross-linked material with significantly high-water content. When the membrane water content is too high, the membrane may lose its mechanical strength and cannot provide enough ionic conductivity. The semi-empirical model's parameters were estimated to simulate the elimination of Na+, K+, Ca2+, and Mg2+ by three membranes. HEXCl and S-PESOS were electrodialyzed and used to treat the serial dilution from the water with cationics. The removal rate gradually rose after the electrodialysis started.
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| first_indexed | 2024-03-08T09:30:13Z |
| format | Article |
| id | doaj.art-a897f755b5924f12927fde5c34a3a2d2 |
| institution | Directory Open Access Journal |
| issn | 1813-162X 2312-7589 |
| language | English |
| last_indexed | 2024-03-08T09:30:13Z |
| publishDate | 2024-01-01 |
| publisher | Tikrit University |
| record_format | Article |
| series | Tikrit Journal of Engineering Sciences |
| spelling | doaj.art-a897f755b5924f12927fde5c34a3a2d22024-01-31T05:35:54ZengTikrit UniversityTikrit Journal of Engineering Sciences1813-162X2312-75892024-01-0131110.25130/tjes.31.1.3Removal of Monovalent and Divalent Cations from Brine Water by Electrodialysis Using Modified Polyethersulfone Membranes Zainab A. Khalaf0Sarah S. Mohammed Jawad1Department of Electromechanical Engineering, College of Engineering, University of Samarra, Samarra, Iraq.Department of Chemistry, College of Education, University of Samarra, Samarra, Iraq. In electrodialysis, an ion exchange membrane removes unwanted ions from wastewater and toxic metal ions from effluents. Montmorillonite-based modified "polyethersulfone membranes" have been studied as a potential small-scale electrodialysis approach for removing ions from wastewater. The study featured several steps, including solid polymerization, electrolyte balance, and removal of each component from the water. The study used three distinct “cation-exchange membranes (CEM)" types. The selected water body was diluted 100 times before being added to the electrodialysis cell in amounts of the center, cathodic, and anodic chambers, each containing 55, 30, and 40 mL. The initial pH for the real solutions of the water body was 7.16 at 25°C. Compared to "Sulfonated poly arylene ether sulfone (S-PESOS)" (23.23%) and Nafion® (35.34%), "hexamethylenediamine (HEXCl)" stands out as the only cross-linked material with significantly high-water content. When the membrane water content is too high, the membrane may lose its mechanical strength and cannot provide enough ionic conductivity. The semi-empirical model's parameters were estimated to simulate the elimination of Na+, K+, Ca2+, and Mg2+ by three membranes. HEXCl and S-PESOS were electrodialyzed and used to treat the serial dilution from the water with cationics. The removal rate gradually rose after the electrodialysis started. https://tj-es.com/ojs/index.php/tjes/article/view/1120Toxic Metal IonsWastewaterPolymericIon ExchangeCation-Exchange Membranes |
| spellingShingle | Zainab A. Khalaf Sarah S. Mohammed Jawad Removal of Monovalent and Divalent Cations from Brine Water by Electrodialysis Using Modified Polyethersulfone Membranes Tikrit Journal of Engineering Sciences Toxic Metal Ions Wastewater Polymeric Ion Exchange Cation-Exchange Membranes |
| title | Removal of Monovalent and Divalent Cations from Brine Water by Electrodialysis Using Modified Polyethersulfone Membranes |
| title_full | Removal of Monovalent and Divalent Cations from Brine Water by Electrodialysis Using Modified Polyethersulfone Membranes |
| title_fullStr | Removal of Monovalent and Divalent Cations from Brine Water by Electrodialysis Using Modified Polyethersulfone Membranes |
| title_full_unstemmed | Removal of Monovalent and Divalent Cations from Brine Water by Electrodialysis Using Modified Polyethersulfone Membranes |
| title_short | Removal of Monovalent and Divalent Cations from Brine Water by Electrodialysis Using Modified Polyethersulfone Membranes |
| title_sort | removal of monovalent and divalent cations from brine water by electrodialysis using modified polyethersulfone membranes |
| topic | Toxic Metal Ions Wastewater Polymeric Ion Exchange Cation-Exchange Membranes |
| url | https://tj-es.com/ojs/index.php/tjes/article/view/1120 |
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