Glucose-Treated Manganese Hexacyanoferrate for Sodium-Ion Secondary Battery
Manganese hexacyanoferrate (Mn-PBA) is a promising cathode material forsodium-ion secondary battery (SIB) with high average voltage (=3.4 V) against Na. Here,we find that the thermal decomposition of glucose modifies the surface state of Mn-PBA,without affecting the bulk crystal structure. The gluco...
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| Format: | Article |
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MDPI AG
2015-09-01
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| Series: | Energies |
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| Online Access: | http://www.mdpi.com/1996-1073/8/9/9486 |
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| author | Yutaka Moritomo Kensuke Goto Takayuki Shibata |
| author_facet | Yutaka Moritomo Kensuke Goto Takayuki Shibata |
| author_sort | Yutaka Moritomo |
| collection | DOAJ |
| description | Manganese hexacyanoferrate (Mn-PBA) is a promising cathode material forsodium-ion secondary battery (SIB) with high average voltage (=3.4 V) against Na. Here,we find that the thermal decomposition of glucose modifies the surface state of Mn-PBA,without affecting the bulk crystal structure. The glucose treatment significantly improves therate properties of Mn-PBA in SIB. The critical discharge rate increases from 1 C (as-grown)to 15 C (glucose-treated). Our observation suggests that thermal treatment is quite effectivefor insulating coordination polymers. |
| first_indexed | 2024-04-11T13:10:38Z |
| format | Article |
| id | doaj.art-a8a970c4fa6d42eda1fd077b5866ae5f |
| institution | Directory Open Access Journal |
| issn | 1996-1073 |
| language | English |
| last_indexed | 2024-04-11T13:10:38Z |
| publishDate | 2015-09-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Energies |
| spelling | doaj.art-a8a970c4fa6d42eda1fd077b5866ae5f2022-12-22T04:22:36ZengMDPI AGEnergies1996-10732015-09-01899486949410.3390/en8099486en8099486Glucose-Treated Manganese Hexacyanoferrate for Sodium-Ion Secondary BatteryYutaka Moritomo0Kensuke Goto1Takayuki Shibata2Graduate School of Pure and Applied Science, University of Tsukuba, Tsukuba 305-8577, JapanGraduate School of Pure and Applied Science, University of Tsukuba, Tsukuba 305-8577, JapanGraduate School of Pure and Applied Science, University of Tsukuba, Tsukuba 305-8577, JapanManganese hexacyanoferrate (Mn-PBA) is a promising cathode material forsodium-ion secondary battery (SIB) with high average voltage (=3.4 V) against Na. Here,we find that the thermal decomposition of glucose modifies the surface state of Mn-PBA,without affecting the bulk crystal structure. The glucose treatment significantly improves therate properties of Mn-PBA in SIB. The critical discharge rate increases from 1 C (as-grown)to 15 C (glucose-treated). Our observation suggests that thermal treatment is quite effectivefor insulating coordination polymers.http://www.mdpi.com/1996-1073/8/9/9486sodium-ion secondary batteryprussian blue analoguesglucose treatmentsurface modification |
| spellingShingle | Yutaka Moritomo Kensuke Goto Takayuki Shibata Glucose-Treated Manganese Hexacyanoferrate for Sodium-Ion Secondary Battery Energies sodium-ion secondary battery prussian blue analogues glucose treatment surface modification |
| title | Glucose-Treated Manganese Hexacyanoferrate for Sodium-Ion Secondary Battery |
| title_full | Glucose-Treated Manganese Hexacyanoferrate for Sodium-Ion Secondary Battery |
| title_fullStr | Glucose-Treated Manganese Hexacyanoferrate for Sodium-Ion Secondary Battery |
| title_full_unstemmed | Glucose-Treated Manganese Hexacyanoferrate for Sodium-Ion Secondary Battery |
| title_short | Glucose-Treated Manganese Hexacyanoferrate for Sodium-Ion Secondary Battery |
| title_sort | glucose treated manganese hexacyanoferrate for sodium ion secondary battery |
| topic | sodium-ion secondary battery prussian blue analogues glucose treatment surface modification |
| url | http://www.mdpi.com/1996-1073/8/9/9486 |
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