Bis(μ-iodo)-tetrakis(<i>O</i>-methyl <i>N</i>-phenylthiocarbamate)-tetraiodo-dibismuth

Bis(μ-iodo)-tetrakis(<i>O</i>-methyl <i>N</i>-phenylthiocarbamate)-tetraiodo-dibismuth

In order to investigate the coordination chemistry of <i>O</i>-alkyl <i>N</i>-aryl thiocarbamate ligands, BiI<sub>3</sub> was reacted with two equivalents of MeOC(=S)N(H)Ph in MeCN solution to afford the dinuclear title compound complexes [{I<sub>2</sub&g...

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Bibliographic Details
Main Authors: Wafa Arar, Abderrahim Khatyr, Michael Knorr, Carsten Strohmann, Annika Schmidt
Format: Article
Language:English
Published: MDPI AG 2022-06-01
Series:Molbank
Subjects:
bismuth triiodide
thiocarbamate
thione
crystal structure
hirshfeld analysis
Online Access:https://www.mdpi.com/1422-8599/2022/2/M1381
Description
Summary:In order to investigate the coordination chemistry of <i>O</i>-alkyl <i>N</i>-aryl thiocarbamate ligands, BiI<sub>3</sub> was reacted with two equivalents of MeOC(=S)N(H)Ph in MeCN solution to afford the dinuclear title compound complexes [{I<sub>2</sub>Bi(μ<sub>2</sub>-I)<sub>2</sub>BiI<sub>2</sub>}{κ<sup>1</sup>-MeOC(=S)N(H)Ph}<sub>4</sub>] <b>1</b>. Compound <b>1</b> was characterized by IR, UV and NMR spectroscopy, the formation of a dinuclear framework is ascertained by a single-crystal X-ray diffraction study performed at 100 K.
ISSN:1422-8599

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