catena-Poly[[bis(1H-benzimidazole-κN3)palladium(II)]-μ-benzene-1,4-dicarboxylato-κ2O1:O4]
In the title compound, [Pd(C8H4O4)(C7H6N2)2]n, the Pd atom is tetracoordinated by two carboxylate O atoms from two benzene-1,4-dicarboxylate (bdc) dianions and two N atoms from two benzimidazole ligands, resulting in a slightly distorted tetrahedral PdO2N2 geometry. The bdc ligand acts as a bridge,...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536807065051 |
| _version_ | 1798030948949819392 |
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| author | Qingguo Meng Lintong Wang Yanzhen Liu Yan Pang |
| author_facet | Qingguo Meng Lintong Wang Yanzhen Liu Yan Pang |
| author_sort | Qingguo Meng |
| collection | DOAJ |
| description | In the title compound, [Pd(C8H4O4)(C7H6N2)2]n, the Pd atom is tetracoordinated by two carboxylate O atoms from two benzene-1,4-dicarboxylate (bdc) dianions and two N atoms from two benzimidazole ligands, resulting in a slightly distorted tetrahedral PdO2N2 geometry. The bdc ligand acts as a bridge, linking the Pd atoms into a chain. Inter-chain N—H...O hydrogen bonds help to stabilize the crystal structure. |
| first_indexed | 2024-04-11T19:48:20Z |
| format | Article |
| id | doaj.art-a8d3fb6b313f4eadb3ec4f19fbd6f0a3 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T19:48:20Z |
| publishDate | 2008-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-a8d3fb6b313f4eadb3ec4f19fbd6f0a32022-12-22T04:06:22ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641m133m13310.1107/S1600536807065051catena-Poly[[bis(1H-benzimidazole-κN3)palladium(II)]-μ-benzene-1,4-dicarboxylato-κ2O1:O4]Qingguo MengLintong WangYanzhen LiuYan PangIn the title compound, [Pd(C8H4O4)(C7H6N2)2]n, the Pd atom is tetracoordinated by two carboxylate O atoms from two benzene-1,4-dicarboxylate (bdc) dianions and two N atoms from two benzimidazole ligands, resulting in a slightly distorted tetrahedral PdO2N2 geometry. The bdc ligand acts as a bridge, linking the Pd atoms into a chain. Inter-chain N—H...O hydrogen bonds help to stabilize the crystal structure.http://scripts.iucr.org/cgi-bin/paper?S1600536807065051 |
| spellingShingle | Qingguo Meng Lintong Wang Yanzhen Liu Yan Pang catena-Poly[[bis(1H-benzimidazole-κN3)palladium(II)]-μ-benzene-1,4-dicarboxylato-κ2O1:O4] Acta Crystallographica Section E |
| title | catena-Poly[[bis(1H-benzimidazole-κN3)palladium(II)]-μ-benzene-1,4-dicarboxylato-κ2O1:O4] |
| title_full | catena-Poly[[bis(1H-benzimidazole-κN3)palladium(II)]-μ-benzene-1,4-dicarboxylato-κ2O1:O4] |
| title_fullStr | catena-Poly[[bis(1H-benzimidazole-κN3)palladium(II)]-μ-benzene-1,4-dicarboxylato-κ2O1:O4] |
| title_full_unstemmed | catena-Poly[[bis(1H-benzimidazole-κN3)palladium(II)]-μ-benzene-1,4-dicarboxylato-κ2O1:O4] |
| title_short | catena-Poly[[bis(1H-benzimidazole-κN3)palladium(II)]-μ-benzene-1,4-dicarboxylato-κ2O1:O4] |
| title_sort | catena poly bis 1h benzimidazole 954 n3 palladium ii 956 benzene 1 4 dicarboxylato 954 2o1 o4 |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536807065051 |
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