Fourier Transform Infrared (FTIR) Spectroscopy with Chemometric Techniques for the Classification of Ballpoint Pen Inks

FTIR spectroscopic techniques have been shown to possess good abilities to analyse ballpoint pen inks. These in-situ techniques involve directing light onto ballpoint ink samples to generate an FTIR spectrum, providing “molecular fingerprints” of the ink samples thus allowing comparison by direct vi...

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Main Authors: Muhammad Naeim Mohamad Asri, Wan Nur Syuhaila Mat Desa, Dzulkiflee Ismail
Format: Article
Language:Arabic
Published: Naif University Publishing House 2015-12-01
Series:Arab Journal of Forensic Sciences & Forensic Medicine
Subjects:
Online Access:https://journals.nauss.edu.sa/index.php/AJFSFM/article/view/113
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author Muhammad Naeim Mohamad Asri
Wan Nur Syuhaila Mat Desa
Dzulkiflee Ismail
author_facet Muhammad Naeim Mohamad Asri
Wan Nur Syuhaila Mat Desa
Dzulkiflee Ismail
author_sort Muhammad Naeim Mohamad Asri
collection DOAJ
description FTIR spectroscopic techniques have been shown to possess good abilities to analyse ballpoint pen inks. These in-situ techniques involve directing light onto ballpoint ink samples to generate an FTIR spectrum, providing “molecular fingerprints” of the ink samples thus allowing comparison by direct visual comparison. In this study, ink from blue (n=15) and red (n=15) ballpoint pens of five different brands: Kilometrico®, G-Soft®, Stabilo®, Pilot® and Faber Castell® was analysed using the FTIR technique with the objective of establishing a distinctive differentiation according to the brand. The resulting spectra were first compared and grouped manually. Due to the similarities in terms of colour and shade of the inks, distinctive differentiation could not be achieved by means of direct visual comparison. However, when the same spectral data was analysed by Principal Component Analysis (PCA) software, distinctive grouping of the ballpoint pen inks was achieved. Our results demonstrate that PCA can be used objectively to investigate ballpoint pen inks of similar colour and more importantly of different brands.
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spelling doaj.art-a8e34e3b42404caba686850dc9a154d42024-03-12T12:28:14ZaraNaif University Publishing HouseArab Journal of Forensic Sciences & Forensic Medicine1658-67861658-67942015-12-011210.12816/001769923Fourier Transform Infrared (FTIR) Spectroscopy with Chemometric Techniques for the Classification of Ballpoint Pen InksMuhammad Naeim Mohamad Asri0Wan Nur Syuhaila Mat Desa1Dzulkiflee Ismail2Forensic Science Program, School of Health Sciences, Universiti Sains MalaysiaForensic Science Program, School of Health Sciences, Universiti Sains MalaysiaForensic Science Program, School of Health Sciences, Universiti Sains MalaysiaFTIR spectroscopic techniques have been shown to possess good abilities to analyse ballpoint pen inks. These in-situ techniques involve directing light onto ballpoint ink samples to generate an FTIR spectrum, providing “molecular fingerprints” of the ink samples thus allowing comparison by direct visual comparison. In this study, ink from blue (n=15) and red (n=15) ballpoint pens of five different brands: Kilometrico®, G-Soft®, Stabilo®, Pilot® and Faber Castell® was analysed using the FTIR technique with the objective of establishing a distinctive differentiation according to the brand. The resulting spectra were first compared and grouped manually. Due to the similarities in terms of colour and shade of the inks, distinctive differentiation could not be achieved by means of direct visual comparison. However, when the same spectral data was analysed by Principal Component Analysis (PCA) software, distinctive grouping of the ballpoint pen inks was achieved. Our results demonstrate that PCA can be used objectively to investigate ballpoint pen inks of similar colour and more importantly of different brands.https://journals.nauss.edu.sa/index.php/AJFSFM/article/view/113forensic scienceprincipal component analysis (pca)ftir spectroscopyballpoint pen inksdirect visual comparison
spellingShingle Muhammad Naeim Mohamad Asri
Wan Nur Syuhaila Mat Desa
Dzulkiflee Ismail
Fourier Transform Infrared (FTIR) Spectroscopy with Chemometric Techniques for the Classification of Ballpoint Pen Inks
Arab Journal of Forensic Sciences & Forensic Medicine
forensic science
principal component analysis (pca)
ftir spectroscopy
ballpoint pen inks
direct visual comparison
title Fourier Transform Infrared (FTIR) Spectroscopy with Chemometric Techniques for the Classification of Ballpoint Pen Inks
title_full Fourier Transform Infrared (FTIR) Spectroscopy with Chemometric Techniques for the Classification of Ballpoint Pen Inks
title_fullStr Fourier Transform Infrared (FTIR) Spectroscopy with Chemometric Techniques for the Classification of Ballpoint Pen Inks
title_full_unstemmed Fourier Transform Infrared (FTIR) Spectroscopy with Chemometric Techniques for the Classification of Ballpoint Pen Inks
title_short Fourier Transform Infrared (FTIR) Spectroscopy with Chemometric Techniques for the Classification of Ballpoint Pen Inks
title_sort fourier transform infrared ftir spectroscopy with chemometric techniques for the classification of ballpoint pen inks
topic forensic science
principal component analysis (pca)
ftir spectroscopy
ballpoint pen inks
direct visual comparison
url https://journals.nauss.edu.sa/index.php/AJFSFM/article/view/113
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AT wannursyuhailamatdesa fouriertransforminfraredftirspectroscopywithchemometrictechniquesfortheclassificationofballpointpeninks
AT dzulkifleeismail fouriertransforminfraredftirspectroscopywithchemometrictechniquesfortheclassificationofballpointpeninks