Fabrication of ZnWO<sub>4</sub>-SnO<sub>2</sub> Core–Shell Nanorods for Enhanced Solar Light-Driven Photoelectrochemical Performance

This article describes the effective synthesis of colloidal SnO<sub>2</sub> quantum dots and ZnWO<sub>4</sub> nanorods using wet chemical synthesis and hydrothermal synthesis, respectively. The resulting ZnWO<sub>4</sub>-SnO<sub>2</sub> core–shell nano...

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Main Authors: Bathula Babu, Shaik Gouse Peera, Kisoo Yoo
Format: Article
Language:English
Published: MDPI AG 2023-05-01
Series:Inorganics
Subjects:
Online Access:https://www.mdpi.com/2304-6740/11/5/213
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author Bathula Babu
Shaik Gouse Peera
Kisoo Yoo
author_facet Bathula Babu
Shaik Gouse Peera
Kisoo Yoo
author_sort Bathula Babu
collection DOAJ
description This article describes the effective synthesis of colloidal SnO<sub>2</sub> quantum dots and ZnWO<sub>4</sub> nanorods using wet chemical synthesis and hydrothermal synthesis, respectively. The resulting ZnWO<sub>4</sub>-SnO<sub>2</sub> core–shell nanorod heterostructure is then made, and its structural, optical, and morphological properties are assessed using XRD, SEM, TEM, and DRS. The heterojunction’s structural confinement increases the exposure of its reactive sites, and its electronic confinement promotes its redox activity. The heterostructure subsequently exhibits a smaller bandgap and better light-harvesting capabilities, resulting in increased photoelectrochemical performance. The heterostructure of core–shell nanorods shows promise for usage in a range of optoelectronic devices and effective solar energy conversion.
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spelling doaj.art-a90316cf1ae84570a64f57e7a6668c182023-11-18T01:49:13ZengMDPI AGInorganics2304-67402023-05-0111521310.3390/inorganics11050213Fabrication of ZnWO<sub>4</sub>-SnO<sub>2</sub> Core–Shell Nanorods for Enhanced Solar Light-Driven Photoelectrochemical PerformanceBathula Babu0Shaik Gouse Peera1Kisoo Yoo2School of Mechanical Engineering, Yeungnam University, Gyeongsan 38541, Republic of KoreaDepartment of Environmental Science, Keimyung University, Daegu 42601, Republic of KoreaSchool of Mechanical Engineering, Yeungnam University, Gyeongsan 38541, Republic of KoreaThis article describes the effective synthesis of colloidal SnO<sub>2</sub> quantum dots and ZnWO<sub>4</sub> nanorods using wet chemical synthesis and hydrothermal synthesis, respectively. The resulting ZnWO<sub>4</sub>-SnO<sub>2</sub> core–shell nanorod heterostructure is then made, and its structural, optical, and morphological properties are assessed using XRD, SEM, TEM, and DRS. The heterojunction’s structural confinement increases the exposure of its reactive sites, and its electronic confinement promotes its redox activity. The heterostructure subsequently exhibits a smaller bandgap and better light-harvesting capabilities, resulting in increased photoelectrochemical performance. The heterostructure of core–shell nanorods shows promise for usage in a range of optoelectronic devices and effective solar energy conversion.https://www.mdpi.com/2304-6740/11/5/213ZnWO<sub>4</sub>nanorodsSnO<sub>2</sub>quantum dotscore–shellphotoelectrochemical
spellingShingle Bathula Babu
Shaik Gouse Peera
Kisoo Yoo
Fabrication of ZnWO<sub>4</sub>-SnO<sub>2</sub> Core–Shell Nanorods for Enhanced Solar Light-Driven Photoelectrochemical Performance
Inorganics
ZnWO<sub>4</sub>
nanorods
SnO<sub>2</sub>
quantum dots
core–shell
photoelectrochemical
title Fabrication of ZnWO<sub>4</sub>-SnO<sub>2</sub> Core–Shell Nanorods for Enhanced Solar Light-Driven Photoelectrochemical Performance
title_full Fabrication of ZnWO<sub>4</sub>-SnO<sub>2</sub> Core–Shell Nanorods for Enhanced Solar Light-Driven Photoelectrochemical Performance
title_fullStr Fabrication of ZnWO<sub>4</sub>-SnO<sub>2</sub> Core–Shell Nanorods for Enhanced Solar Light-Driven Photoelectrochemical Performance
title_full_unstemmed Fabrication of ZnWO<sub>4</sub>-SnO<sub>2</sub> Core–Shell Nanorods for Enhanced Solar Light-Driven Photoelectrochemical Performance
title_short Fabrication of ZnWO<sub>4</sub>-SnO<sub>2</sub> Core–Shell Nanorods for Enhanced Solar Light-Driven Photoelectrochemical Performance
title_sort fabrication of znwo sub 4 sub sno sub 2 sub core shell nanorods for enhanced solar light driven photoelectrochemical performance
topic ZnWO<sub>4</sub>
nanorods
SnO<sub>2</sub>
quantum dots
core–shell
photoelectrochemical
url https://www.mdpi.com/2304-6740/11/5/213
work_keys_str_mv AT bathulababu fabricationofznwosub4subsnosub2subcoreshellnanorodsforenhancedsolarlightdrivenphotoelectrochemicalperformance
AT shaikgousepeera fabricationofznwosub4subsnosub2subcoreshellnanorodsforenhancedsolarlightdrivenphotoelectrochemicalperformance
AT kisooyoo fabricationofznwosub4subsnosub2subcoreshellnanorodsforenhancedsolarlightdrivenphotoelectrochemicalperformance