Di-μ-acetato-κ4O:O′-bis[(1,10-phenanthroline-κ2N,N′)(trifluoromethanesulfonato-κO)copper(II)]
The complete molecule of the title compound, [Cu2(C2H3O2)2(CF3O3S)2(C12H8N2)2], is completed by the application of a twofold rotation and comprises two CuII ions, each of which is pentacoordinated by two N atoms from a bidentate 1,10-phenanthroline (phen) ligand, two O atoms from acetate ligands and...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2013-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813027323 |
| _version_ | 1818914687957336064 |
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| author | Nanthawat Wannarit Chaveng Pakawatchai Sujittra Youngme |
| author_facet | Nanthawat Wannarit Chaveng Pakawatchai Sujittra Youngme |
| author_sort | Nanthawat Wannarit |
| collection | DOAJ |
| description | The complete molecule of the title compound, [Cu2(C2H3O2)2(CF3O3S)2(C12H8N2)2], is completed by the application of a twofold rotation and comprises two CuII ions, each of which is pentacoordinated by two N atoms from a bidentate 1,10-phenanthroline (phen) ligand, two O atoms from acetate ligands and an O atom from a trifluoromethanesulfonate anion, forming a (4 + 1) distorted square-pyramidal coordination geometry. The CuII ions are connected by two acetate bridges in a syn–syn configuration. The F atoms of the trifluoromethanesulfonate ligands are disordered, with site-occupation factors of 70 and 30. The molecular structure is stabilized by intramolecular face-to-face π–π interactions with centroid–centroid distances in the range 3.5654 (12)–3.8775(12) Å. The crystal structure is stabilized by C—H...O interactions, leading to a three-dimensional lattice structure. |
| first_indexed | 2024-12-19T23:50:21Z |
| format | Article |
| id | doaj.art-a910b330e6c7443da147763f8f988de6 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T23:50:21Z |
| publishDate | 2013-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-a910b330e6c7443da147763f8f988de62022-12-21T20:01:10ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-11-016911m591m59210.1107/S1600536813027323Di-μ-acetato-κ4O:O′-bis[(1,10-phenanthroline-κ2N,N′)(trifluoromethanesulfonato-κO)copper(II)]Nanthawat WannaritChaveng PakawatchaiSujittra YoungmeThe complete molecule of the title compound, [Cu2(C2H3O2)2(CF3O3S)2(C12H8N2)2], is completed by the application of a twofold rotation and comprises two CuII ions, each of which is pentacoordinated by two N atoms from a bidentate 1,10-phenanthroline (phen) ligand, two O atoms from acetate ligands and an O atom from a trifluoromethanesulfonate anion, forming a (4 + 1) distorted square-pyramidal coordination geometry. The CuII ions are connected by two acetate bridges in a syn–syn configuration. The F atoms of the trifluoromethanesulfonate ligands are disordered, with site-occupation factors of 70 and 30. The molecular structure is stabilized by intramolecular face-to-face π–π interactions with centroid–centroid distances in the range 3.5654 (12)–3.8775(12) Å. The crystal structure is stabilized by C—H...O interactions, leading to a three-dimensional lattice structure.http://scripts.iucr.org/cgi-bin/paper?S1600536813027323 |
| spellingShingle | Nanthawat Wannarit Chaveng Pakawatchai Sujittra Youngme Di-μ-acetato-κ4O:O′-bis[(1,10-phenanthroline-κ2N,N′)(trifluoromethanesulfonato-κO)copper(II)] Acta Crystallographica Section E |
| title | Di-μ-acetato-κ4O:O′-bis[(1,10-phenanthroline-κ2N,N′)(trifluoromethanesulfonato-κO)copper(II)] |
| title_full | Di-μ-acetato-κ4O:O′-bis[(1,10-phenanthroline-κ2N,N′)(trifluoromethanesulfonato-κO)copper(II)] |
| title_fullStr | Di-μ-acetato-κ4O:O′-bis[(1,10-phenanthroline-κ2N,N′)(trifluoromethanesulfonato-κO)copper(II)] |
| title_full_unstemmed | Di-μ-acetato-κ4O:O′-bis[(1,10-phenanthroline-κ2N,N′)(trifluoromethanesulfonato-κO)copper(II)] |
| title_short | Di-μ-acetato-κ4O:O′-bis[(1,10-phenanthroline-κ2N,N′)(trifluoromethanesulfonato-κO)copper(II)] |
| title_sort | di 956 acetato 954 4o o 8242 bis 1 10 phenanthroline 954 2n n 8242 trifluoromethanesulfonato 954 o copper ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813027323 |
| work_keys_str_mv | AT nanthawatwannarit di956acetato9544oo8242bis110phenanthroline9542nn8242trifluoromethanesulfonato954ocopperii AT chavengpakawatchai di956acetato9544oo8242bis110phenanthroline9542nn8242trifluoromethanesulfonato954ocopperii AT sujittrayoungme di956acetato9544oo8242bis110phenanthroline9542nn8242trifluoromethanesulfonato954ocopperii |