STUDY ON THE PREPARATION AND CHARACTERIZATION OF ALUMINUM-PILLARED CLAYS USING MONTMORILLONITE K10
Aluminum-pillared interlayered clays (Al-PILCs) were synthesized under various experimental conditions starting from commercial montmorillonite K10 (K10-Mt). The pillaring process involves several steps that are easy realized in laboratory. The effect of montmorillonite/NaCl solution mass ratio for...
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| Format: | Article |
| Language: | English |
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2023-06-01
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| Series: | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
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| Online Access: | https://pubs.ub.ro/?pg=revues&rev=cscc6&num=202302&vol=2&aid=5539 |
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| author | ANA-MARIA GEORGESCU NICOLETA PLATON VASILICA-ALISA ARUS COSMIN JINESCU FRANÇOISE NARDOU ILEANA-DENISA NISTOR |
| author_facet | ANA-MARIA GEORGESCU NICOLETA PLATON VASILICA-ALISA ARUS COSMIN JINESCU FRANÇOISE NARDOU ILEANA-DENISA NISTOR |
| author_sort | ANA-MARIA GEORGESCU |
| collection | DOAJ |
| description | Aluminum-pillared interlayered clays (Al-PILCs) were synthesized under various experimental conditions starting from commercial montmorillonite K10 (K10-Mt). The pillaring process involves several steps that are easy realized in laboratory. The effect of montmorillonite/NaCl solution mass ratio for cationic exchange, OH/Al molar ratio and the aging time of pillaring solution on physico-chemical properties and thermal stability of Al-PILCs were examined in this paper. The synthesized nanomaterials were characterized by textural analysis: specific surface area (using Brunauer-Emmett-Teller (BET) and Langmuir methods), micropore volume and micropore area by t-plot method. X-ray diffraction (XRD) analysis was used to determine the basal distance and mineralogy of the materials. The modified clays were characterized by thermal analysis using thermogravimetric (TGA) and differential thermal (DTA) analysis. The specific surface area values, the basal spacing and the thermal stability of the Al-PILCs were affected by the synthesis parameters. The modified products are intended to be used for the adsorption of organic pollutants from wastewater. |
| first_indexed | 2024-03-12T23:15:39Z |
| format | Article |
| id | doaj.art-a929084ae6a04bb38eeb544da68167bf |
| institution | Directory Open Access Journal |
| issn | 1582-540X |
| language | English |
| last_indexed | 2024-03-12T23:15:39Z |
| publishDate | 2023-06-01 |
| publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
| record_format | Article |
| series | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
| spelling | doaj.art-a929084ae6a04bb38eeb544da68167bf2023-07-17T10:06:24ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry1582-540X2023-06-01242145153STUDY ON THE PREPARATION AND CHARACTERIZATION OF ALUMINUM-PILLARED CLAYS USING MONTMORILLONITE K10ANA-MARIA GEORGESCU 0NICOLETA PLATON1VASILICA-ALISA ARUS 2 COSMIN JINESCU3 FRANÇOISE NARDOU 4ILEANA-DENISA NISTOR5”Vasile Alecsandri” University of Bacău, Faculty of Engineering, Department of Chemical and Food Engineering, 157 Calea Mărăşeşti Street, 600115 Bacău, Romania”Vasile Alecsandri” University of Bacău, Faculty of Engineering, Department of Chemical and Food Engineering, 157 Calea Mărăşeşti Street, 600115 Bacău, Romania”Vasile Alecsandri” University of Bacău, Faculty of Engineering, Department of Chemical and Food Engineering, 157 Calea Mărăşeşti Street, 600115 Bacău, RomaniaPolitehnica University of Bucharest, Department of Industrial Process Equipment, 313 Splaiul Independentei, 060042, Bucharest, RomaniaUniversity of Limoges / CEC, SPCTS, UMR 7315 CNRS, 12 Rue Atlantis, 87068 Limoges Cedex, France”Vasile Alecsandri” University of Bacău, Faculty of Engineering, Department of Chemical and Food Engineering, 157 Calea Mărăşeşti Street, 600115 Bacău, RomaniaAluminum-pillared interlayered clays (Al-PILCs) were synthesized under various experimental conditions starting from commercial montmorillonite K10 (K10-Mt). The pillaring process involves several steps that are easy realized in laboratory. The effect of montmorillonite/NaCl solution mass ratio for cationic exchange, OH/Al molar ratio and the aging time of pillaring solution on physico-chemical properties and thermal stability of Al-PILCs were examined in this paper. The synthesized nanomaterials were characterized by textural analysis: specific surface area (using Brunauer-Emmett-Teller (BET) and Langmuir methods), micropore volume and micropore area by t-plot method. X-ray diffraction (XRD) analysis was used to determine the basal distance and mineralogy of the materials. The modified clays were characterized by thermal analysis using thermogravimetric (TGA) and differential thermal (DTA) analysis. The specific surface area values, the basal spacing and the thermal stability of the Al-PILCs were affected by the synthesis parameters. The modified products are intended to be used for the adsorption of organic pollutants from wastewater.https://pubs.ub.ro/?pg=revues&rev=cscc6&num=202302&vol=2&aid=5539basal spacingmontmorillonite k10pillaringspecific surface areathermal analysis |
| spellingShingle | ANA-MARIA GEORGESCU NICOLETA PLATON VASILICA-ALISA ARUS COSMIN JINESCU FRANÇOISE NARDOU ILEANA-DENISA NISTOR STUDY ON THE PREPARATION AND CHARACTERIZATION OF ALUMINUM-PILLARED CLAYS USING MONTMORILLONITE K10 Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry basal spacing montmorillonite k10 pillaring specific surface area thermal analysis |
| title | STUDY ON THE PREPARATION AND CHARACTERIZATION OF ALUMINUM-PILLARED CLAYS USING MONTMORILLONITE K10 |
| title_full | STUDY ON THE PREPARATION AND CHARACTERIZATION OF ALUMINUM-PILLARED CLAYS USING MONTMORILLONITE K10 |
| title_fullStr | STUDY ON THE PREPARATION AND CHARACTERIZATION OF ALUMINUM-PILLARED CLAYS USING MONTMORILLONITE K10 |
| title_full_unstemmed | STUDY ON THE PREPARATION AND CHARACTERIZATION OF ALUMINUM-PILLARED CLAYS USING MONTMORILLONITE K10 |
| title_short | STUDY ON THE PREPARATION AND CHARACTERIZATION OF ALUMINUM-PILLARED CLAYS USING MONTMORILLONITE K10 |
| title_sort | study on the preparation and characterization of aluminum pillared clays using montmorillonite k10 |
| topic | basal spacing montmorillonite k10 pillaring specific surface area thermal analysis |
| url | https://pubs.ub.ro/?pg=revues&rev=cscc6&num=202302&vol=2&aid=5539 |
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