Universal tradeoff relation between speed, uncertainty, and dissipation in nonequilibrium stationary states

We derive universal thermodynamic inequalities that bound from below the moments of first-passage times of stochastic currents in nonequilibrium stationary states of Markov jump processes in the limit where the thresholds that define the first-passage problem are large. These inequa...

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Main Author: Izaak Neri
Format: Article
Language:English
Published: SciPost 2022-04-01
Series:SciPost Physics
Online Access:https://scipost.org/SciPostPhys.12.4.139
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author Izaak Neri
author_facet Izaak Neri
author_sort Izaak Neri
collection DOAJ
description We derive universal thermodynamic inequalities that bound from below the moments of first-passage times of stochastic currents in nonequilibrium stationary states of Markov jump processes in the limit where the thresholds that define the first-passage problem are large. These inequalities describe a tradeoff between speed, uncertainty, and dissipation in nonequilibrium processes, which are quantified, respectively, with the moments of the first-passage times of stochastic currents, the splitting probability, and the mean entropy production rate. Near equilibrium, the inequalities imply that mean-first passage times are lower bounded by the Van't Hoff-Arrhenius law, whereas far from thermal equilibrium the bounds describe a universal speed limit for rate processes. When the current is the stochastic entropy production, then the bounds are equalities, a remarkable property that follows from the fact that the exponentiated negative entropy production is a martingale.
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spelling doaj.art-a932c2a8238e42e592a547635df29c832022-12-22T00:08:28ZengSciPostSciPost Physics2542-46532022-04-0112413910.21468/SciPostPhys.12.4.139Universal tradeoff relation between speed, uncertainty, and dissipation in nonequilibrium stationary statesIzaak NeriWe derive universal thermodynamic inequalities that bound from below the moments of first-passage times of stochastic currents in nonequilibrium stationary states of Markov jump processes in the limit where the thresholds that define the first-passage problem are large. These inequalities describe a tradeoff between speed, uncertainty, and dissipation in nonequilibrium processes, which are quantified, respectively, with the moments of the first-passage times of stochastic currents, the splitting probability, and the mean entropy production rate. Near equilibrium, the inequalities imply that mean-first passage times are lower bounded by the Van't Hoff-Arrhenius law, whereas far from thermal equilibrium the bounds describe a universal speed limit for rate processes. When the current is the stochastic entropy production, then the bounds are equalities, a remarkable property that follows from the fact that the exponentiated negative entropy production is a martingale.https://scipost.org/SciPostPhys.12.4.139
spellingShingle Izaak Neri
Universal tradeoff relation between speed, uncertainty, and dissipation in nonequilibrium stationary states
SciPost Physics
title Universal tradeoff relation between speed, uncertainty, and dissipation in nonequilibrium stationary states
title_full Universal tradeoff relation between speed, uncertainty, and dissipation in nonequilibrium stationary states
title_fullStr Universal tradeoff relation between speed, uncertainty, and dissipation in nonequilibrium stationary states
title_full_unstemmed Universal tradeoff relation between speed, uncertainty, and dissipation in nonequilibrium stationary states
title_short Universal tradeoff relation between speed, uncertainty, and dissipation in nonequilibrium stationary states
title_sort universal tradeoff relation between speed uncertainty and dissipation in nonequilibrium stationary states
url https://scipost.org/SciPostPhys.12.4.139
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