UTILIZATION OF Penaus monodon SHRIMP SHELL WASTE AS ADSORBENT OF CADMIUM(II) IN WATER MEDIUM
Utilization of shrimp shell has been optimum so that in this research preparation of adsorbent chitosan from shell of shrimp (Penaus monodon) as raw materials for cadmium(II) adsorption was carried out. The chitin was made by the deproteination, demineralization; chitosan was prepared by chitin de...
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Format: | Article |
Language: | English |
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Department of Chemistry, Universitas Gadjah Mada
2010-06-01
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Series: | Indonesian Journal of Chemistry |
Online Access: | https://jurnal.ugm.ac.id/ijc/article/view/21819 |
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author | Sari Edi Cahyaningrum Amaria Amaria |
author_facet | Sari Edi Cahyaningrum Amaria Amaria |
author_sort | Sari Edi Cahyaningrum |
collection | DOAJ |
description | Utilization of shrimp shell has been optimum so that in this research preparation of adsorbent chitosan from shell of shrimp (Penaus monodon) as raw materials for cadmium(II) adsorption was carried out. The chitin was made by the deproteination, demineralization; chitosan was prepared by chitin deacetylation. This work was started with Infra Red Spectroscopic identification of functional group. Percentage of deacetylation was determined also by Infra Red Spectroscopy. Contant of nitrogen was determined by Kjeldhal method. The isotherm adsorption Langmuir model was employed for the determination of the energy and the capacity in adsorption. Result showed that chitosan could be isolated from shrimp shell waste with % deacetylation degree of 79.80 and % nitrogen 7.11. Cadmium(II) was chemically adsorbed on chitosan involving energi adsorption of 32.27 kJ/mole. Adsorption capacity of cadmium(II) was 6.35 x 10-5 mole/g. The constant adsorption rate k, was 0.91 x 10-3 s-1 and equilibrium adsorption desorption are K = 10.28 x 103. The ability adsorption of chitosan in real waste has the efficiency of 90%.
Keywords: adsorption, cadmium(II), chitosan |
first_indexed | 2024-12-21T07:40:44Z |
format | Article |
id | doaj.art-a93747ef349846fb9ee41fd9be467cdf |
institution | Directory Open Access Journal |
issn | 1411-9420 2460-1578 |
language | English |
last_indexed | 2024-12-21T07:40:44Z |
publishDate | 2010-06-01 |
publisher | Department of Chemistry, Universitas Gadjah Mada |
record_format | Article |
series | Indonesian Journal of Chemistry |
spelling | doaj.art-a93747ef349846fb9ee41fd9be467cdf2022-12-21T19:11:19ZengDepartment of Chemistry, Universitas Gadjah MadaIndonesian Journal of Chemistry1411-94202460-15782010-06-015213013410.22146/ijc.2181914917UTILIZATION OF Penaus monodon SHRIMP SHELL WASTE AS ADSORBENT OF CADMIUM(II) IN WATER MEDIUMSari Edi Cahyaningrum0Amaria Amaria1Chemistry Department, Faculty of Mathematics and Natural Sciences State University of Surabaya, SurabayaChemistry Department, Faculty of Mathematics and Natural Sciences State University of Surabaya, SurabayaUtilization of shrimp shell has been optimum so that in this research preparation of adsorbent chitosan from shell of shrimp (Penaus monodon) as raw materials for cadmium(II) adsorption was carried out. The chitin was made by the deproteination, demineralization; chitosan was prepared by chitin deacetylation. This work was started with Infra Red Spectroscopic identification of functional group. Percentage of deacetylation was determined also by Infra Red Spectroscopy. Contant of nitrogen was determined by Kjeldhal method. The isotherm adsorption Langmuir model was employed for the determination of the energy and the capacity in adsorption. Result showed that chitosan could be isolated from shrimp shell waste with % deacetylation degree of 79.80 and % nitrogen 7.11. Cadmium(II) was chemically adsorbed on chitosan involving energi adsorption of 32.27 kJ/mole. Adsorption capacity of cadmium(II) was 6.35 x 10-5 mole/g. The constant adsorption rate k, was 0.91 x 10-3 s-1 and equilibrium adsorption desorption are K = 10.28 x 103. The ability adsorption of chitosan in real waste has the efficiency of 90%. Keywords: adsorption, cadmium(II), chitosanhttps://jurnal.ugm.ac.id/ijc/article/view/21819 |
spellingShingle | Sari Edi Cahyaningrum Amaria Amaria UTILIZATION OF Penaus monodon SHRIMP SHELL WASTE AS ADSORBENT OF CADMIUM(II) IN WATER MEDIUM Indonesian Journal of Chemistry |
title | UTILIZATION OF Penaus monodon SHRIMP SHELL WASTE AS ADSORBENT OF CADMIUM(II) IN WATER MEDIUM |
title_full | UTILIZATION OF Penaus monodon SHRIMP SHELL WASTE AS ADSORBENT OF CADMIUM(II) IN WATER MEDIUM |
title_fullStr | UTILIZATION OF Penaus monodon SHRIMP SHELL WASTE AS ADSORBENT OF CADMIUM(II) IN WATER MEDIUM |
title_full_unstemmed | UTILIZATION OF Penaus monodon SHRIMP SHELL WASTE AS ADSORBENT OF CADMIUM(II) IN WATER MEDIUM |
title_short | UTILIZATION OF Penaus monodon SHRIMP SHELL WASTE AS ADSORBENT OF CADMIUM(II) IN WATER MEDIUM |
title_sort | utilization of penaus monodon shrimp shell waste as adsorbent of cadmium ii in water medium |
url | https://jurnal.ugm.ac.id/ijc/article/view/21819 |
work_keys_str_mv | AT sariedicahyaningrum utilizationofpenausmonodonshrimpshellwasteasadsorbentofcadmiumiiinwatermedium AT amariaamaria utilizationofpenausmonodonshrimpshellwasteasadsorbentofcadmiumiiinwatermedium |