Application of Bunchy TiO2 Hierarchical Microspheres as a Scattering Layer for Dye-Sensitized Solar Cells

A novel bunchy TiO2 hierarchical microspheres composite nanostructure with strings of anatase TiO2 hierarchical micro-spheres and rutile nanobelts framework (HSN) was synthesized via an one-pot hydrothermal process. This new structure presents great specific surface area, large pore size distributio...

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Main Authors: Yongjian Jiang, Fengyang Zhao
Format: Article
Language:English
Published: Frontiers Media S.A. 2021-06-01
Series:Frontiers in Energy Research
Subjects:
Online Access:https://www.frontiersin.org/articles/10.3389/fenrg.2021.682709/full
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author Yongjian Jiang
Fengyang Zhao
author_facet Yongjian Jiang
Fengyang Zhao
author_sort Yongjian Jiang
collection DOAJ
description A novel bunchy TiO2 hierarchical microspheres composite nanostructure with strings of anatase TiO2 hierarchical micro-spheres and rutile nanobelts framework (HSN) was synthesized via an one-pot hydrothermal process. This new structure presents great specific surface area, large pore size distribution, homogeneous three-dimensional (3D) structure, high crystallinity and excellent light scattering performance simultaneously. The bi-layer photoanode film was successfully prepared which TiO2 P25 as absorption layer and HSN as an efficient scattering layer on the top of TiO2 P25 film in dye sensitized solar cells (DSSC). The bi-layer DSSC taken on a great progress in the power conversion efficiency (PCE) achieved 8.08%. However, the PCE of single and double layer TiO2 film DSSCs just showed 6.72% and 3.67% respectively. Such improvement was mainly because of the efficient scattering centers (HSN) which can bring the enhanced dye loading, fast charge transfer and excellent light harvesting efficiency.
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spelling doaj.art-a937ad49660b4151a4efbd207211694d2022-12-21T19:07:20ZengFrontiers Media S.A.Frontiers in Energy Research2296-598X2021-06-01910.3389/fenrg.2021.682709682709Application of Bunchy TiO2 Hierarchical Microspheres as a Scattering Layer for Dye-Sensitized Solar CellsYongjian Jiang0Fengyang Zhao1College of Science, Liaoning Petrochemical University, Fushun, ChinaCollege of Chemistry and Material Science, Liaoning Petrochemical University, Fushun, ChinaA novel bunchy TiO2 hierarchical microspheres composite nanostructure with strings of anatase TiO2 hierarchical micro-spheres and rutile nanobelts framework (HSN) was synthesized via an one-pot hydrothermal process. This new structure presents great specific surface area, large pore size distribution, homogeneous three-dimensional (3D) structure, high crystallinity and excellent light scattering performance simultaneously. The bi-layer photoanode film was successfully prepared which TiO2 P25 as absorption layer and HSN as an efficient scattering layer on the top of TiO2 P25 film in dye sensitized solar cells (DSSC). The bi-layer DSSC taken on a great progress in the power conversion efficiency (PCE) achieved 8.08%. However, the PCE of single and double layer TiO2 film DSSCs just showed 6.72% and 3.67% respectively. Such improvement was mainly because of the efficient scattering centers (HSN) which can bring the enhanced dye loading, fast charge transfer and excellent light harvesting efficiency.https://www.frontiersin.org/articles/10.3389/fenrg.2021.682709/fulldye sensitized solar cellsbunchy TiO2 hierarchical microspheres (HSN)bi-layer DSSCsscattering layercharge transfer
spellingShingle Yongjian Jiang
Fengyang Zhao
Application of Bunchy TiO2 Hierarchical Microspheres as a Scattering Layer for Dye-Sensitized Solar Cells
Frontiers in Energy Research
dye sensitized solar cells
bunchy TiO2 hierarchical microspheres (HSN)
bi-layer DSSCs
scattering layer
charge transfer
title Application of Bunchy TiO2 Hierarchical Microspheres as a Scattering Layer for Dye-Sensitized Solar Cells
title_full Application of Bunchy TiO2 Hierarchical Microspheres as a Scattering Layer for Dye-Sensitized Solar Cells
title_fullStr Application of Bunchy TiO2 Hierarchical Microspheres as a Scattering Layer for Dye-Sensitized Solar Cells
title_full_unstemmed Application of Bunchy TiO2 Hierarchical Microspheres as a Scattering Layer for Dye-Sensitized Solar Cells
title_short Application of Bunchy TiO2 Hierarchical Microspheres as a Scattering Layer for Dye-Sensitized Solar Cells
title_sort application of bunchy tio2 hierarchical microspheres as a scattering layer for dye sensitized solar cells
topic dye sensitized solar cells
bunchy TiO2 hierarchical microspheres (HSN)
bi-layer DSSCs
scattering layer
charge transfer
url https://www.frontiersin.org/articles/10.3389/fenrg.2021.682709/full
work_keys_str_mv AT yongjianjiang applicationofbunchytio2hierarchicalmicrospheresasascatteringlayerfordyesensitizedsolarcells
AT fengyangzhao applicationofbunchytio2hierarchicalmicrospheresasascatteringlayerfordyesensitizedsolarcells