Microstructural evolution and mechanical properties of nano-ATZ ceramics by solid solution precipitation

Alumina toughened zirconia (ATZ) nanoceramics accompanied with high-strength, high-toughness and high-hardness were prepared by in-situ nanoprecipitation from using solid solution micro-powders. The submicron-sized Al2O3 (∼445 nm) and ZrO2 (∼361 nm) grains contained low-density precipitated nano-ZrO...

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Main Authors: Yongdong Yu, Xudong Liu, Yuchen Yuan, Wanjun Yu, Hang Yin, Zhao Yin, Yongting Zheng, Xiaodong He
Format: Article
Language:English
Published: Elsevier 2022-01-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2238785421015003
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author Yongdong Yu
Xudong Liu
Yuchen Yuan
Wanjun Yu
Hang Yin
Zhao Yin
Yongting Zheng
Xiaodong He
author_facet Yongdong Yu
Xudong Liu
Yuchen Yuan
Wanjun Yu
Hang Yin
Zhao Yin
Yongting Zheng
Xiaodong He
author_sort Yongdong Yu
collection DOAJ
description Alumina toughened zirconia (ATZ) nanoceramics accompanied with high-strength, high-toughness and high-hardness were prepared by in-situ nanoprecipitation from using solid solution micro-powders. The submicron-sized Al2O3 (∼445 nm) and ZrO2 (∼361 nm) grains contained low-density precipitated nano-ZrO2 (∼35 nm) and nano-Y4Al2O9 (YAM, ∼87 nm) particles, respectively, making high-performance nano-ATZ ceramics with ultrafine intracrystalline nanostructure yet achieved. There was a parallel or eutectic lattice orientation relationship between the submicrocrystals and its internal nanoparticles of their crystal planes, which is very conducive to the improvement of the mechanical properties of nano-ATZ ceramics. The fracture toughness and hardness of 30wt%Al2O3/70wt%ZrO2(3 mol%Y2O3) can reach up to 5.68 ± 0.17 MPa m1/2 (single-edge V-notched beam method, SEVNB) and 16.32 ± 0.45 GPa, respectively, which are improved by ∼25% and ∼20% compared with those of 3Y-TZP ceramics. Therefore, this method can be used to prepare nano-ATZ ceramics contained ultrafine nanoparticles and uniform distribution of Al2O3 phases.
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spelling doaj.art-a94b7f13a3484e4f9677515891d058152022-12-21T19:34:14ZengElsevierJournal of Materials Research and Technology2238-78542022-01-011612931304Microstructural evolution and mechanical properties of nano-ATZ ceramics by solid solution precipitationYongdong Yu0Xudong Liu1Yuchen Yuan2Wanjun Yu3Hang Yin4Zhao Yin5Yongting Zheng6Xiaodong He7National Key Laboratory of Science and Technology on Advanced Composites in Special Environments, Center for Composite Materials and Structures, Harbin Institute of Technology, Harbin, 150080, PR ChinaNational Key Laboratory of Science and Technology on Advanced Composites in Special Environments, Center for Composite Materials and Structures, Harbin Institute of Technology, Harbin, 150080, PR ChinaNational Key Laboratory of Science and Technology on Advanced Composites in Special Environments, Center for Composite Materials and Structures, Harbin Institute of Technology, Harbin, 150080, PR ChinaSchool of Environment and Materials Engineering, Yantai University, Yantai, 264003, PR ChinaNational Key Laboratory of Science and Technology on Advanced Composites in Special Environments, Center for Composite Materials and Structures, Harbin Institute of Technology, Harbin, 150080, PR ChinaNational Key Laboratory of Science and Technology on Advanced Composites in Special Environments, Center for Composite Materials and Structures, Harbin Institute of Technology, Harbin, 150080, PR ChinaNational Key Laboratory of Science and Technology on Advanced Composites in Special Environments, Center for Composite Materials and Structures, Harbin Institute of Technology, Harbin, 150080, PR China; Corresponding author.National Key Laboratory of Science and Technology on Advanced Composites in Special Environments, Center for Composite Materials and Structures, Harbin Institute of Technology, Harbin, 150080, PR ChinaAlumina toughened zirconia (ATZ) nanoceramics accompanied with high-strength, high-toughness and high-hardness were prepared by in-situ nanoprecipitation from using solid solution micro-powders. The submicron-sized Al2O3 (∼445 nm) and ZrO2 (∼361 nm) grains contained low-density precipitated nano-ZrO2 (∼35 nm) and nano-Y4Al2O9 (YAM, ∼87 nm) particles, respectively, making high-performance nano-ATZ ceramics with ultrafine intracrystalline nanostructure yet achieved. There was a parallel or eutectic lattice orientation relationship between the submicrocrystals and its internal nanoparticles of their crystal planes, which is very conducive to the improvement of the mechanical properties of nano-ATZ ceramics. The fracture toughness and hardness of 30wt%Al2O3/70wt%ZrO2(3 mol%Y2O3) can reach up to 5.68 ± 0.17 MPa m1/2 (single-edge V-notched beam method, SEVNB) and 16.32 ± 0.45 GPa, respectively, which are improved by ∼25% and ∼20% compared with those of 3Y-TZP ceramics. Therefore, this method can be used to prepare nano-ATZ ceramics contained ultrafine nanoparticles and uniform distribution of Al2O3 phases.http://www.sciencedirect.com/science/article/pii/S2238785421015003Combustion synthesisRapid solidificationMicrostructural evolutionNano-ATZSolid solutionsNanoprecipitation
spellingShingle Yongdong Yu
Xudong Liu
Yuchen Yuan
Wanjun Yu
Hang Yin
Zhao Yin
Yongting Zheng
Xiaodong He
Microstructural evolution and mechanical properties of nano-ATZ ceramics by solid solution precipitation
Journal of Materials Research and Technology
Combustion synthesis
Rapid solidification
Microstructural evolution
Nano-ATZ
Solid solutions
Nanoprecipitation
title Microstructural evolution and mechanical properties of nano-ATZ ceramics by solid solution precipitation
title_full Microstructural evolution and mechanical properties of nano-ATZ ceramics by solid solution precipitation
title_fullStr Microstructural evolution and mechanical properties of nano-ATZ ceramics by solid solution precipitation
title_full_unstemmed Microstructural evolution and mechanical properties of nano-ATZ ceramics by solid solution precipitation
title_short Microstructural evolution and mechanical properties of nano-ATZ ceramics by solid solution precipitation
title_sort microstructural evolution and mechanical properties of nano atz ceramics by solid solution precipitation
topic Combustion synthesis
Rapid solidification
Microstructural evolution
Nano-ATZ
Solid solutions
Nanoprecipitation
url http://www.sciencedirect.com/science/article/pii/S2238785421015003
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