Detección de almidón en leche en polvo basado en espectroscopia Raman y mínimos cuadrados parciales

This research aimed to establish a mathematical model, using Raman spectral information and the partial least squares regression algorithm (PLS), to predict the percentage of adulteration of powdered milk by starch. The regression model obtained can be used to identify samples that show starch in...

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Main Author: José Antonio Blas-Matienzo
Format: Article
Language:Spanish
Published: Universidad Nacional de Trujillo 2019-12-01
Series:Agroindustrial Science
Subjects:
Online Access:http://revistas.unitru.edu.pe/index.php/agroindscience/article/view/2702
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author José Antonio Blas-Matienzo
author_facet José Antonio Blas-Matienzo
author_sort José Antonio Blas-Matienzo
collection DOAJ
description This research aimed to establish a mathematical model, using Raman spectral information and the partial least squares regression algorithm (PLS), to predict the percentage of adulteration of powdered milk by starch. The regression model obtained can be used to identify samples that show starch in powdered milk in concentrations ranging from 5% to 40% (w/w). The cross-validation method was used with the strategy of leaving a sample out. The interval that was optimal is the wave number range of 2170-2272 cm-1 . The linear regression model obtained has a multiple correlation coefficient of 99.99%, minimum sum of squares of the predicted residual error (PRESS) of 237.4 and the value of the F statistic, 19210.29 allows us to establish that if there is a relationship Linear significance between Raman intensities and the values of starch concentrations in the mixture. The value of the critical level p = 0.006 indicates that there is a significant linear relationship, and therefore, that the hyperplane defined by the regression equation offers a good fit.
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spelling doaj.art-a94c49e95a62463a836d1e6e13ed652d2022-12-21T20:05:08ZspaUniversidad Nacional de TrujilloAgroindustrial Science2226-29892226-29892019-12-019212713210.17268/agroind.sci.2019.02.04Detección de almidón en leche en polvo basado en espectroscopia Raman y mínimos cuadrados parcialesJosé Antonio Blas-Matienzo0Facultad de Ingeniería en Industrias Alimentarias, Universidad Nacional Agraria de la Selva. This research aimed to establish a mathematical model, using Raman spectral information and the partial least squares regression algorithm (PLS), to predict the percentage of adulteration of powdered milk by starch. The regression model obtained can be used to identify samples that show starch in powdered milk in concentrations ranging from 5% to 40% (w/w). The cross-validation method was used with the strategy of leaving a sample out. The interval that was optimal is the wave number range of 2170-2272 cm-1 . The linear regression model obtained has a multiple correlation coefficient of 99.99%, minimum sum of squares of the predicted residual error (PRESS) of 237.4 and the value of the F statistic, 19210.29 allows us to establish that if there is a relationship Linear significance between Raman intensities and the values of starch concentrations in the mixture. The value of the critical level p = 0.006 indicates that there is a significant linear relationship, and therefore, that the hyperplane defined by the regression equation offers a good fit.http://revistas.unitru.edu.pe/index.php/agroindscience/article/view/2702partial least squaresmilk powderstarchraman spectroscopyinterval pls.
spellingShingle José Antonio Blas-Matienzo
Detección de almidón en leche en polvo basado en espectroscopia Raman y mínimos cuadrados parciales
Agroindustrial Science
partial least squares
milk powder
starch
raman spectroscopy
interval pls.
title Detección de almidón en leche en polvo basado en espectroscopia Raman y mínimos cuadrados parciales
title_full Detección de almidón en leche en polvo basado en espectroscopia Raman y mínimos cuadrados parciales
title_fullStr Detección de almidón en leche en polvo basado en espectroscopia Raman y mínimos cuadrados parciales
title_full_unstemmed Detección de almidón en leche en polvo basado en espectroscopia Raman y mínimos cuadrados parciales
title_short Detección de almidón en leche en polvo basado en espectroscopia Raman y mínimos cuadrados parciales
title_sort deteccion de almidon en leche en polvo basado en espectroscopia raman y minimos cuadrados parciales
topic partial least squares
milk powder
starch
raman spectroscopy
interval pls.
url http://revistas.unitru.edu.pe/index.php/agroindscience/article/view/2702
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