Anisotropy in RFe2 Intermetallics: An NMR Study
The anisotropy of the Ho3+, Tb3+ and Tm3+ rare-earth ions in RFe2 compounds is investigated using the field dependence of the NMR spectra of 169Tm, 159Tb and 165Ho in polycrystalline TmFe2, TbFe2, HoFe2 and related pseudo-binary compounds. The very large hyperfine interaction in these ions dominates...
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| Format: | Article |
| Language: | English |
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Sultan Qaboos University
2009-06-01
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| Series: | Sultan Qaboos University Journal for Science |
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| Online Access: | https://journals.squ.edu.om/index.php/squjs/article/view/361 |
| Summary: | The anisotropy of the Ho3+, Tb3+ and Tm3+ rare-earth ions in RFe2 compounds is investigated using the field dependence of the NMR spectra of 169Tm, 159Tb and 165Ho in polycrystalline TmFe2, TbFe2, HoFe2 and related pseudo-binary compounds. The very large hyperfine interaction in these ions dominates the NMR spectrum; the NMR frequencies in the 2 to 7 GHz range provide therefore a measure of the localized moment and its orientation in the crystal field. We compare the NMR measurements to single ion computations that include magnetostriction.
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| ISSN: | 1027-524X 2414-536X |