Recovery and purification of uranium from slags produced in UF6 production reactor

In this paper, for recovery and purification of uranium from the slag, three simple operations, including heat treatment at low temperature, leaching operations at the ambient temperature, and uranium sedimentation in conventional methods, as well as the combined sedimentation method at the ambient...

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Main Authors: K Fatemi, M.T Nejhadkord, M Habibi Zare
Format: Article
Language:fas
Published: Nuclear Science and Technology Research Institute 2020-02-01
Series:مجله علوم و فنون هسته‌ای
Subjects:
Online Access:https://jonsat.nstri.ir/article_1065_53f3c7889278d0cb9e97cea3b21423b1.pdf
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author K Fatemi
M.T Nejhadkord
M Habibi Zare
author_facet K Fatemi
M.T Nejhadkord
M Habibi Zare
author_sort K Fatemi
collection DOAJ
description In this paper, for recovery and purification of uranium from the slag, three simple operations, including heat treatment at low temperature, leaching operations at the ambient temperature, and uranium sedimentation in conventional methods, as well as the combined sedimentation method at the ambient temperature were proposed. The overall role for each of these operations has been studied on the purity of the manufactured products. During the heat treatment, the combination of the insoluble U4+ in the slag structure was oxidized to soluble uranium compounds. Then, with the leaching process and using a dilute nitric acid solution, ammonium bicarbonate solution and methanol, the separation of uranium from the saturated solid phase was performed. The leached uranium in the presence of the fluorine ions in the form of AUC(ammonium uranyl carbonate), ADU(ammonium diuranate) was precipitated with high purity and high efficiency, and a very pure U3O8 containing fluorine concentrations of less than the permitted limit in the nuclear fuel pellet was used. The results of the analysis of the U3O8 shows that the elements that affect the uranium enrichment process and the fuel performance is decreased under the permitted limit.
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spelling doaj.art-a958d04a0e714e03b79009e603c5fa0f2023-05-02T10:15:41ZfasNuclear Science and Technology Research Instituteمجله علوم و فنون هسته‌ای1735-18712676-58612020-02-01404112010.24200/nst.2020.10651065Recovery and purification of uranium from slags produced in UF6 production reactorK Fatemi0M.T Nejhadkord1M Habibi Zare2شرکت سوخت رآکتورهای هسته‌ای، سازمان انرژی اتمی ایران، صندوق پستی: 1957-81465، اصفهان ـ ایرانشرکت سوخت رآکتورهای هسته‌ای، سازمان انرژی اتمی ایران، صندوق پستی: 1957-81465، اصفهان ـ ایرانشرکت سوخت رآکتورهای هسته‌ای، سازمان انرژی اتمی ایران، صندوق پستی: 1957-81465، اصفهان ـ ایرانIn this paper, for recovery and purification of uranium from the slag, three simple operations, including heat treatment at low temperature, leaching operations at the ambient temperature, and uranium sedimentation in conventional methods, as well as the combined sedimentation method at the ambient temperature were proposed. The overall role for each of these operations has been studied on the purity of the manufactured products. During the heat treatment, the combination of the insoluble U4+ in the slag structure was oxidized to soluble uranium compounds. Then, with the leaching process and using a dilute nitric acid solution, ammonium bicarbonate solution and methanol, the separation of uranium from the saturated solid phase was performed. The leached uranium in the presence of the fluorine ions in the form of AUC(ammonium uranyl carbonate), ADU(ammonium diuranate) was precipitated with high purity and high efficiency, and a very pure U3O8 containing fluorine concentrations of less than the permitted limit in the nuclear fuel pellet was used. The results of the analysis of the U3O8 shows that the elements that affect the uranium enrichment process and the fuel performance is decreased under the permitted limit.https://jonsat.nstri.ir/article_1065_53f3c7889278d0cb9e97cea3b21423b1.pdfrecoverypurificationuraniumuf6 production reactor
spellingShingle K Fatemi
M.T Nejhadkord
M Habibi Zare
Recovery and purification of uranium from slags produced in UF6 production reactor
مجله علوم و فنون هسته‌ای
recovery
purification
uranium
uf6 production reactor
title Recovery and purification of uranium from slags produced in UF6 production reactor
title_full Recovery and purification of uranium from slags produced in UF6 production reactor
title_fullStr Recovery and purification of uranium from slags produced in UF6 production reactor
title_full_unstemmed Recovery and purification of uranium from slags produced in UF6 production reactor
title_short Recovery and purification of uranium from slags produced in UF6 production reactor
title_sort recovery and purification of uranium from slags produced in uf6 production reactor
topic recovery
purification
uranium
uf6 production reactor
url https://jonsat.nstri.ir/article_1065_53f3c7889278d0cb9e97cea3b21423b1.pdf
work_keys_str_mv AT kfatemi recoveryandpurificationofuraniumfromslagsproducedinuf6productionreactor
AT mtnejhadkord recoveryandpurificationofuraniumfromslagsproducedinuf6productionreactor
AT mhabibizare recoveryandpurificationofuraniumfromslagsproducedinuf6productionreactor