Investigation of Vegetable Oils and Their Derivatives for the Synthesis of Extreme Pressure Additives

The harmful effects of wear can be reduced through proper lubrication of the frictional parts. When exposed to excessive loads, the lubricant film is displaced from the surfaces, and even the adhesive lubricant layer may rupture. Additives known as Extreme Pressure (EP) are frequently incorporated i...

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Main Authors: Gábor Zoltán Nagy, Roland Nagy
Format: Article
Language:English
Published: MDPI AG 2023-10-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/16/19/6570
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author Gábor Zoltán Nagy
Roland Nagy
author_facet Gábor Zoltán Nagy
Roland Nagy
author_sort Gábor Zoltán Nagy
collection DOAJ
description The harmful effects of wear can be reduced through proper lubrication of the frictional parts. When exposed to excessive loads, the lubricant film is displaced from the surfaces, and even the adhesive lubricant layer may rupture. Additives known as Extreme Pressure (EP) are frequently incorporated into lubricants to minimise wear and avert seizures under high temperature and pressure. Mechanistically, these additives generate a film on the surface through chemisorption. These additives are extensively applied in various lubricants, with the largest quantities being employed in metalworking fluids and lubricating greases. Sulfurized vegetable oils and their derivates can be used as EP additives for lubricants. To conduct the investigations, sulfurized additives were synthesized using different vegetable-based oils and fatty acid esters, and alpha-olefins. In this study, the Four-ball test results were compared to gain a more accurate comprehension of how various raw-material-based additives influence wear and friction. The goal was to select raw materials that could be used with favorable results for the production of EP additives. The objective was to achieve a minimum Four-ball weld load parameter of 2000 N. The experiments revealed that the functional impacts of the synthesized samples are dependent on the type of raw materials employed. Based on the experimental data and the stated criteria, the examined raw materials were found to be suitable for the synthesis of EP additives.
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spelling doaj.art-a95dff3a490643ca8cce083a43c4e42d2023-11-19T14:41:42ZengMDPI AGMaterials1996-19442023-10-011619657010.3390/ma16196570Investigation of Vegetable Oils and Their Derivatives for the Synthesis of Extreme Pressure AdditivesGábor Zoltán Nagy0Roland Nagy1Department of MOL Hydrocarbon and Coal Processing, Faculty of Engineering, University of Pannonia, 8200 Veszprém, HungaryDepartment of MOL Hydrocarbon and Coal Processing, Faculty of Engineering, University of Pannonia, 8200 Veszprém, HungaryThe harmful effects of wear can be reduced through proper lubrication of the frictional parts. When exposed to excessive loads, the lubricant film is displaced from the surfaces, and even the adhesive lubricant layer may rupture. Additives known as Extreme Pressure (EP) are frequently incorporated into lubricants to minimise wear and avert seizures under high temperature and pressure. Mechanistically, these additives generate a film on the surface through chemisorption. These additives are extensively applied in various lubricants, with the largest quantities being employed in metalworking fluids and lubricating greases. Sulfurized vegetable oils and their derivates can be used as EP additives for lubricants. To conduct the investigations, sulfurized additives were synthesized using different vegetable-based oils and fatty acid esters, and alpha-olefins. In this study, the Four-ball test results were compared to gain a more accurate comprehension of how various raw-material-based additives influence wear and friction. The goal was to select raw materials that could be used with favorable results for the production of EP additives. The objective was to achieve a minimum Four-ball weld load parameter of 2000 N. The experiments revealed that the functional impacts of the synthesized samples are dependent on the type of raw materials employed. Based on the experimental data and the stated criteria, the examined raw materials were found to be suitable for the synthesis of EP additives.https://www.mdpi.com/1996-1944/16/19/6570EP additivesvegetable oilvegetable oil derivatessynthesis
spellingShingle Gábor Zoltán Nagy
Roland Nagy
Investigation of Vegetable Oils and Their Derivatives for the Synthesis of Extreme Pressure Additives
Materials
EP additives
vegetable oil
vegetable oil derivates
synthesis
title Investigation of Vegetable Oils and Their Derivatives for the Synthesis of Extreme Pressure Additives
title_full Investigation of Vegetable Oils and Their Derivatives for the Synthesis of Extreme Pressure Additives
title_fullStr Investigation of Vegetable Oils and Their Derivatives for the Synthesis of Extreme Pressure Additives
title_full_unstemmed Investigation of Vegetable Oils and Their Derivatives for the Synthesis of Extreme Pressure Additives
title_short Investigation of Vegetable Oils and Their Derivatives for the Synthesis of Extreme Pressure Additives
title_sort investigation of vegetable oils and their derivatives for the synthesis of extreme pressure additives
topic EP additives
vegetable oil
vegetable oil derivates
synthesis
url https://www.mdpi.com/1996-1944/16/19/6570
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