catena-Poly[[[diaquacopper(II)]-bis[μ-1,5-bis(1H-imidazol-1-yl)pentane-κ2N3:N3′]] naphthalene-1,5-disulfonate]
In the title complex, {[Cu(C11H16N4)2(H2O)2](C10H6O6S2)}n, the CuII atom, lying on an inversion center, is six-coordinated by two water molecules and four N atoms from four 1,5-bis(1H-imidazol-1-yl)pentane (biim-5) ligands in a distorted octahedral geometry. Adjacent CuII atoms are linked by two bii...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812045679 |
| _version_ | 1818322095760736256 |
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| author | Lai-Ping Zhang Shu-Tang Wen Xiao-Ning Fu |
| author_facet | Lai-Ping Zhang Shu-Tang Wen Xiao-Ning Fu |
| author_sort | Lai-Ping Zhang |
| collection | DOAJ |
| description | In the title complex, {[Cu(C11H16N4)2(H2O)2](C10H6O6S2)}n, the CuII atom, lying on an inversion center, is six-coordinated by two water molecules and four N atoms from four 1,5-bis(1H-imidazol-1-yl)pentane (biim-5) ligands in a distorted octahedral geometry. Adjacent CuII atoms are linked by two biim-5 ligands, forming a chain along [111]. Two atoms of the pentane group are disordered over two sets of sites, with an occupancy ratio of 0.554 (18):0.446 (18). Intermolecular O—H...O hydrogen bonds link the chains and the centrosymmetric naphthalene-1,5-disulfonate anions into a layer structure parallel to (0-11). |
| first_indexed | 2024-12-13T10:51:21Z |
| format | Article |
| id | doaj.art-a96193d868c144ca843a7d3d6cabe1e9 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:51:21Z |
| publishDate | 2012-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-a96193d868c144ca843a7d3d6cabe1e92022-12-21T23:49:50ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-12-016812m1505m150510.1107/S1600536812045679catena-Poly[[[diaquacopper(II)]-bis[μ-1,5-bis(1H-imidazol-1-yl)pentane-κ2N3:N3′]] naphthalene-1,5-disulfonate]Lai-Ping ZhangShu-Tang WenXiao-Ning FuIn the title complex, {[Cu(C11H16N4)2(H2O)2](C10H6O6S2)}n, the CuII atom, lying on an inversion center, is six-coordinated by two water molecules and four N atoms from four 1,5-bis(1H-imidazol-1-yl)pentane (biim-5) ligands in a distorted octahedral geometry. Adjacent CuII atoms are linked by two biim-5 ligands, forming a chain along [111]. Two atoms of the pentane group are disordered over two sets of sites, with an occupancy ratio of 0.554 (18):0.446 (18). Intermolecular O—H...O hydrogen bonds link the chains and the centrosymmetric naphthalene-1,5-disulfonate anions into a layer structure parallel to (0-11).http://scripts.iucr.org/cgi-bin/paper?S1600536812045679 |
| spellingShingle | Lai-Ping Zhang Shu-Tang Wen Xiao-Ning Fu catena-Poly[[[diaquacopper(II)]-bis[μ-1,5-bis(1H-imidazol-1-yl)pentane-κ2N3:N3′]] naphthalene-1,5-disulfonate] Acta Crystallographica Section E |
| title | catena-Poly[[[diaquacopper(II)]-bis[μ-1,5-bis(1H-imidazol-1-yl)pentane-κ2N3:N3′]] naphthalene-1,5-disulfonate] |
| title_full | catena-Poly[[[diaquacopper(II)]-bis[μ-1,5-bis(1H-imidazol-1-yl)pentane-κ2N3:N3′]] naphthalene-1,5-disulfonate] |
| title_fullStr | catena-Poly[[[diaquacopper(II)]-bis[μ-1,5-bis(1H-imidazol-1-yl)pentane-κ2N3:N3′]] naphthalene-1,5-disulfonate] |
| title_full_unstemmed | catena-Poly[[[diaquacopper(II)]-bis[μ-1,5-bis(1H-imidazol-1-yl)pentane-κ2N3:N3′]] naphthalene-1,5-disulfonate] |
| title_short | catena-Poly[[[diaquacopper(II)]-bis[μ-1,5-bis(1H-imidazol-1-yl)pentane-κ2N3:N3′]] naphthalene-1,5-disulfonate] |
| title_sort | catena poly diaquacopper ii bis amp 956 1 5 bis 1h imidazol 1 yl pentane amp 954 2n3 n3 amp 8242 naphthalene 1 5 disulfonate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812045679 |
| work_keys_str_mv | AT laipingzhang catenapolydiaquacopperiibisamp95615bis1himidazol1ylpentaneamp9542n3n3amp8242naphthalene15disulfonate AT shutangwen catenapolydiaquacopperiibisamp95615bis1himidazol1ylpentaneamp9542n3n3amp8242naphthalene15disulfonate AT xiaoningfu catenapolydiaquacopperiibisamp95615bis1himidazol1ylpentaneamp9542n3n3amp8242naphthalene15disulfonate |