Polyvinylidene Fluoride (PVDF)/Modified Clay Hybrid Membrane for Humic Acid and Methylene Blue Filtration
This research studied the impact of silanized clay modification on performance and antifouling Poly(vinylidene fluoride) (PVDF) membrane toward humic acid and methylene blue filtration. Clay modification was carried out by using 3-aminopropyltriethoxysilane (APS) to produce modified clay (Clay-APS)....
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| Format: | Article |
| Language: | English |
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Department of Chemistry, Universitas Gadjah Mada
2023-04-01
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| Series: | Indonesian Journal of Chemistry |
| Subjects: | |
| Online Access: | https://jurnal.ugm.ac.id/ijc/article/view/78979 |
| _version_ | 1827965560703418368 |
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| author | Edi Pramono Gadis Prihatin Wahyu Sejati Sayekti Wahyuningsih Candra Purnawan |
| author_facet | Edi Pramono Gadis Prihatin Wahyu Sejati Sayekti Wahyuningsih Candra Purnawan |
| author_sort | Edi Pramono |
| collection | DOAJ |
| description | This research studied the impact of silanized clay modification on performance and antifouling Poly(vinylidene fluoride) (PVDF) membrane toward humic acid and methylene blue filtration. Clay modification was carried out by using 3-aminopropyltriethoxysilane (APS) to produce modified clay (Clay-APS). Hybrid membranes were prepared by phase inversion for humic acid and methylene blue filtration. Hybrid membranes were characterized by measuring surface hydrophilicity, water flux, rejection, and antifouling properties. Clay and Clay-APS modification increased hybrid membrane surface hydrophilicity, as indicated by increasing the β fraction and decreasing the water contact angle. The PVDF/Clay and PVDF/Clay-APS hybrid membranes showed high permeability and selectivity with the highest water flux values of 24.2 L m−2 h−1. The rejections for humic acid and methylene blue were 98.8 and 99.3%, respectively. The highest antifouling property was obtained from the PVDF/Clay-APS hybrid membrane, with a flux recovery ratio was 96.0%. The PVDF/Clay hybrid membrane performance and antifouling properties showed that the membranes have the potential for water treatment. |
| first_indexed | 2024-04-09T17:35:12Z |
| format | Article |
| id | doaj.art-a96c9f93d24247de9f1743d26cb5f357 |
| institution | Directory Open Access Journal |
| issn | 1411-9420 2460-1578 |
| language | English |
| last_indexed | 2024-04-09T17:35:12Z |
| publishDate | 2023-04-01 |
| publisher | Department of Chemistry, Universitas Gadjah Mada |
| record_format | Article |
| series | Indonesian Journal of Chemistry |
| spelling | doaj.art-a96c9f93d24247de9f1743d26cb5f3572023-04-18T01:55:50ZengDepartment of Chemistry, Universitas Gadjah MadaIndonesian Journal of Chemistry1411-94202460-15782023-04-0123242543710.22146/ijc.7897933598Polyvinylidene Fluoride (PVDF)/Modified Clay Hybrid Membrane for Humic Acid and Methylene Blue FiltrationEdi Pramono0Gadis Prihatin Wahyu Sejati1Sayekti Wahyuningsih2Candra Purnawan3Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sebelas Maret, Jl. Ir. Sutami 36A, Kentingan, Surakarta 57126, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sebelas Maret, Jl. Ir. Sutami 36A, Kentingan, Surakarta 57126, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sebelas Maret, Jl. Ir. Sutami 36A, Kentingan, Surakarta 57126, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sebelas Maret, Jl. Ir. Sutami 36A, Kentingan, Surakarta 57126, IndonesiaThis research studied the impact of silanized clay modification on performance and antifouling Poly(vinylidene fluoride) (PVDF) membrane toward humic acid and methylene blue filtration. Clay modification was carried out by using 3-aminopropyltriethoxysilane (APS) to produce modified clay (Clay-APS). Hybrid membranes were prepared by phase inversion for humic acid and methylene blue filtration. Hybrid membranes were characterized by measuring surface hydrophilicity, water flux, rejection, and antifouling properties. Clay and Clay-APS modification increased hybrid membrane surface hydrophilicity, as indicated by increasing the β fraction and decreasing the water contact angle. The PVDF/Clay and PVDF/Clay-APS hybrid membranes showed high permeability and selectivity with the highest water flux values of 24.2 L m−2 h−1. The rejections for humic acid and methylene blue were 98.8 and 99.3%, respectively. The highest antifouling property was obtained from the PVDF/Clay-APS hybrid membrane, with a flux recovery ratio was 96.0%. The PVDF/Clay hybrid membrane performance and antifouling properties showed that the membranes have the potential for water treatment.https://jurnal.ugm.ac.id/ijc/article/view/78979clay modificationdye filtrationhybrid membranepolyvinylidene fluoride |
| spellingShingle | Edi Pramono Gadis Prihatin Wahyu Sejati Sayekti Wahyuningsih Candra Purnawan Polyvinylidene Fluoride (PVDF)/Modified Clay Hybrid Membrane for Humic Acid and Methylene Blue Filtration Indonesian Journal of Chemistry clay modification dye filtration hybrid membrane polyvinylidene fluoride |
| title | Polyvinylidene Fluoride (PVDF)/Modified Clay Hybrid Membrane for Humic Acid and Methylene Blue Filtration |
| title_full | Polyvinylidene Fluoride (PVDF)/Modified Clay Hybrid Membrane for Humic Acid and Methylene Blue Filtration |
| title_fullStr | Polyvinylidene Fluoride (PVDF)/Modified Clay Hybrid Membrane for Humic Acid and Methylene Blue Filtration |
| title_full_unstemmed | Polyvinylidene Fluoride (PVDF)/Modified Clay Hybrid Membrane for Humic Acid and Methylene Blue Filtration |
| title_short | Polyvinylidene Fluoride (PVDF)/Modified Clay Hybrid Membrane for Humic Acid and Methylene Blue Filtration |
| title_sort | polyvinylidene fluoride pvdf modified clay hybrid membrane for humic acid and methylene blue filtration |
| topic | clay modification dye filtration hybrid membrane polyvinylidene fluoride |
| url | https://jurnal.ugm.ac.id/ijc/article/view/78979 |
| work_keys_str_mv | AT edipramono polyvinylidenefluoridepvdfmodifiedclayhybridmembraneforhumicacidandmethylenebluefiltration AT gadisprihatinwahyusejati polyvinylidenefluoridepvdfmodifiedclayhybridmembraneforhumicacidandmethylenebluefiltration AT sayektiwahyuningsih polyvinylidenefluoridepvdfmodifiedclayhybridmembraneforhumicacidandmethylenebluefiltration AT candrapurnawan polyvinylidenefluoridepvdfmodifiedclayhybridmembraneforhumicacidandmethylenebluefiltration |