DWARF-GREEN COCONUT FIBERS: A VERSATILE NATURAL RENEWABLE RAW BIORESOURCE. TREATMENT, MORPHOLOGY, AND PHYSICOCHEMICAL PROPERTIES

Dwarf-green coconut fibers were modified by alkali treatment and characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), as well as thermogravimetric (TGA), mechanical, and dielectric analyses. Changes in composition, structure,...

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Main Authors: Milena A. Esmeraldo, Antonio C. Gomes, Jose E. B. Freitas, Pierre B. A. Fechine, Antonio S. B. Sombra, Elisangela Corradini, Giuseppe Mele, Alfonso Maffezzoli, Selma E. Mazzetto
Format: Article
Language:English
Published: North Carolina State University 2010-11-01
Series:BioResources
Subjects:
Online Access:http://www.ncsu.edu/bioresources/BioRes_05/BioRes_05_4_2478_Esmeraldo_GFFSCMMM_Dwarf_Green_Coconut_Props_1018.pdf
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author Milena A. Esmeraldo
Antonio C. Gomes
Jose E. B. Freitas
Pierre B. A. Fechine
Antonio S. B. Sombra
Elisangela Corradini
Giuseppe Mele
Alfonso Maffezzoli
Selma E. Mazzetto
author_facet Milena A. Esmeraldo
Antonio C. Gomes
Jose E. B. Freitas
Pierre B. A. Fechine
Antonio S. B. Sombra
Elisangela Corradini
Giuseppe Mele
Alfonso Maffezzoli
Selma E. Mazzetto
author_sort Milena A. Esmeraldo
collection DOAJ
description Dwarf-green coconut fibers were modified by alkali treatment and characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), as well as thermogravimetric (TGA), mechanical, and dielectric analyses. Changes in composition, structure, and morphology of the coconut fibers were observed after sodium hydroxide treatments due to the removal of lignin, hemicellulose, and other impurities. The XRD data were in agreement with the morphological analysis, where the crystallinity fraction increased with the concentration of alkali solution and fell off above 10%. The infrared spectrometry showed the partial dissolution of hemicellulose, lignin, and pectin, which was clearly identified by the band at 1736 cm-1. Thermogravimetric analysis showed a double degradation process for the untreated dwarf-green coconut fibers, while a single one was observed after the pretreatment. The tensile properties showed an increased elongation at break, modulus, and strength, and the dielectric results showed a decrease of all parameters (permittivity, dielectric loss, and conductivity), reflecting the reduced dipole and ion mobility associated with the loss of amorphous components.
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spelling doaj.art-a96dc7b7f6984d0ba43ed1e19f99abae2022-12-21T22:57:20ZengNorth Carolina State UniversityBioResources1930-21262010-11-015424782501DWARF-GREEN COCONUT FIBERS: A VERSATILE NATURAL RENEWABLE RAW BIORESOURCE. TREATMENT, MORPHOLOGY, AND PHYSICOCHEMICAL PROPERTIESMilena A. EsmeraldoAntonio C. GomesJose E. B. FreitasPierre B. A. FechineAntonio S. B. SombraElisangela CorradiniGiuseppe MeleAlfonso MaffezzoliSelma E. MazzettoDwarf-green coconut fibers were modified by alkali treatment and characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), as well as thermogravimetric (TGA), mechanical, and dielectric analyses. Changes in composition, structure, and morphology of the coconut fibers were observed after sodium hydroxide treatments due to the removal of lignin, hemicellulose, and other impurities. The XRD data were in agreement with the morphological analysis, where the crystallinity fraction increased with the concentration of alkali solution and fell off above 10%. The infrared spectrometry showed the partial dissolution of hemicellulose, lignin, and pectin, which was clearly identified by the band at 1736 cm-1. Thermogravimetric analysis showed a double degradation process for the untreated dwarf-green coconut fibers, while a single one was observed after the pretreatment. The tensile properties showed an increased elongation at break, modulus, and strength, and the dielectric results showed a decrease of all parameters (permittivity, dielectric loss, and conductivity), reflecting the reduced dipole and ion mobility associated with the loss of amorphous components.www.ncsu.edu/bioresources/BioRes_05/BioRes_05_4_2478_Esmeraldo_GFFSCMMM_Dwarf_Green_Coconut_Props_1018.pdfDwarf-green coir fibersSurface pretreatmentMorphologyPhysicochemical and mechanical properties
spellingShingle Milena A. Esmeraldo
Antonio C. Gomes
Jose E. B. Freitas
Pierre B. A. Fechine
Antonio S. B. Sombra
Elisangela Corradini
Giuseppe Mele
Alfonso Maffezzoli
Selma E. Mazzetto
DWARF-GREEN COCONUT FIBERS: A VERSATILE NATURAL RENEWABLE RAW BIORESOURCE. TREATMENT, MORPHOLOGY, AND PHYSICOCHEMICAL PROPERTIES
BioResources
Dwarf-green coir fibers
Surface pretreatment
Morphology
Physicochemical and mechanical properties
title DWARF-GREEN COCONUT FIBERS: A VERSATILE NATURAL RENEWABLE RAW BIORESOURCE. TREATMENT, MORPHOLOGY, AND PHYSICOCHEMICAL PROPERTIES
title_full DWARF-GREEN COCONUT FIBERS: A VERSATILE NATURAL RENEWABLE RAW BIORESOURCE. TREATMENT, MORPHOLOGY, AND PHYSICOCHEMICAL PROPERTIES
title_fullStr DWARF-GREEN COCONUT FIBERS: A VERSATILE NATURAL RENEWABLE RAW BIORESOURCE. TREATMENT, MORPHOLOGY, AND PHYSICOCHEMICAL PROPERTIES
title_full_unstemmed DWARF-GREEN COCONUT FIBERS: A VERSATILE NATURAL RENEWABLE RAW BIORESOURCE. TREATMENT, MORPHOLOGY, AND PHYSICOCHEMICAL PROPERTIES
title_short DWARF-GREEN COCONUT FIBERS: A VERSATILE NATURAL RENEWABLE RAW BIORESOURCE. TREATMENT, MORPHOLOGY, AND PHYSICOCHEMICAL PROPERTIES
title_sort dwarf green coconut fibers a versatile natural renewable raw bioresource treatment morphology and physicochemical properties
topic Dwarf-green coir fibers
Surface pretreatment
Morphology
Physicochemical and mechanical properties
url http://www.ncsu.edu/bioresources/BioRes_05/BioRes_05_4_2478_Esmeraldo_GFFSCMMM_Dwarf_Green_Coconut_Props_1018.pdf
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