Synthesis and Crystal Structure of [Pb(gly)2]n; New lead(II) Coordination Polymer with Glycine Ligand
[Pb(gly)2]n (1) (gly is the abbreviation of Glycine) have been synthesized and characterized by elemental analyses, IR, 1H NMR and 13C NMR spectroscopy. The single crystal structure of 1 show the complex is 2D coordination polymer with octahedral environment that is formed into 3D supramolecule thro...
| Main Authors: | , , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Nanoscience and Nanotechnology Research Center, University of Kashan
2019-01-01
|
| Series: | Journal of Nanostructures |
| Subjects: | |
| Online Access: | http://jns.kashanu.ac.ir/article_87889_7161640b352f818e4fb989ae6875b7e9.pdf |
| _version_ | 1818554068600094720 |
|---|---|
| author | Zarnoosh Shokhchashm Azar Hakimifar Lida Hashemi Ali Morsali Michal Dusek Amir Reza Abbasi Mohammad Esmaeil Ebrahimzadeh Fateme Babaei Mojtaba Khanpour Matikolaei |
| author_facet | Zarnoosh Shokhchashm Azar Hakimifar Lida Hashemi Ali Morsali Michal Dusek Amir Reza Abbasi Mohammad Esmaeil Ebrahimzadeh Fateme Babaei Mojtaba Khanpour Matikolaei |
| author_sort | Zarnoosh Shokhchashm |
| collection | DOAJ |
| description | [Pb(gly)2]n (1) (gly is the abbreviation of Glycine) have been synthesized and characterized by elemental analyses, IR, 1H NMR and 13C NMR spectroscopy. The single crystal structure of 1 show the complex is 2D coordination polymer with octahedral environment that is formed into 3D supramolecule through hydrogen bond. Structural determination of compound 1 reveals the Pb(II) ion is four coordinated, bonded to a nitrogen, oxygen and two carbon atoms from the Glycine ligand.The crystal structure of compound 1 consists of a 3D supramolecular compound and shows the coordination number in the Pb(II) ions is six. PbO nanoparticles were synthesized by calcination of compound 1 at 500, 550 and 600 °C under air atmosphere. Calcination of the compound 1 at these temperatures yields mixture of orthorhombic and tetragonal PbO nanoparticles and nanorods. The PbO nanostructure was characterized by scanning electron microscopy (SEM) and X-ray powder diffraction (XRD). The thermal stability of compound 1 was studied by thermal gravimetric (TG) and differential thermal analyses (DTA). |
| first_indexed | 2024-12-12T09:34:19Z |
| format | Article |
| id | doaj.art-a972173a94924240853b5a9b3acf788d |
| institution | Directory Open Access Journal |
| issn | 2251-7871 2251-788X |
| language | English |
| last_indexed | 2024-12-12T09:34:19Z |
| publishDate | 2019-01-01 |
| publisher | Nanoscience and Nanotechnology Research Center, University of Kashan |
| record_format | Article |
| series | Journal of Nanostructures |
| spelling | doaj.art-a972173a94924240853b5a9b3acf788d2022-12-22T00:28:46ZengNanoscience and Nanotechnology Research Center, University of KashanJournal of Nanostructures2251-78712251-788X2019-01-019181310.22052/JNS.2019.01.0287889Synthesis and Crystal Structure of [Pb(gly)2]n; New lead(II) Coordination Polymer with Glycine LigandZarnoosh Shokhchashm0Azar Hakimifar1Lida Hashemi2Ali Morsali3Michal Dusek4Amir Reza Abbasi5Mohammad Esmaeil Ebrahimzadeh6Fateme Babaei7Mojtaba Khanpour Matikolaei8Department of Chemistry, Payame Noor University, Abhar, Zanjan, IranDepartment of Chemistry, Faculty of Sciences, Tarbiat Modares University, Tehran, IranDepartment of Chemistry, Faculty of Sciences, Tarbiat Modares University, Tehran, IranDepartment of Chemistry, Faculty of Sciences, Tarbiat Modares University, Tehran, IranInstitute of physics ASCR Cukrovarnicka 10 162 00 Prague Czech RepublicFaculty of Chemistry, Razi University, Kermanshah, IranMazandaran Gas Company, Mazandaran, IranMazandaran Gas Company, Mazandaran, IranMazandaran Gas Company, Mazandaran, Iran[Pb(gly)2]n (1) (gly is the abbreviation of Glycine) have been synthesized and characterized by elemental analyses, IR, 1H NMR and 13C NMR spectroscopy. The single crystal structure of 1 show the complex is 2D coordination polymer with octahedral environment that is formed into 3D supramolecule through hydrogen bond. Structural determination of compound 1 reveals the Pb(II) ion is four coordinated, bonded to a nitrogen, oxygen and two carbon atoms from the Glycine ligand.The crystal structure of compound 1 consists of a 3D supramolecular compound and shows the coordination number in the Pb(II) ions is six. PbO nanoparticles were synthesized by calcination of compound 1 at 500, 550 and 600 °C under air atmosphere. Calcination of the compound 1 at these temperatures yields mixture of orthorhombic and tetragonal PbO nanoparticles and nanorods. The PbO nanostructure was characterized by scanning electron microscopy (SEM) and X-ray powder diffraction (XRD). The thermal stability of compound 1 was studied by thermal gravimetric (TG) and differential thermal analyses (DTA).http://jns.kashanu.ac.ir/article_87889_7161640b352f818e4fb989ae6875b7e9.pdfcoordination polymernano particlelead(ii) oxideglycine |
| spellingShingle | Zarnoosh Shokhchashm Azar Hakimifar Lida Hashemi Ali Morsali Michal Dusek Amir Reza Abbasi Mohammad Esmaeil Ebrahimzadeh Fateme Babaei Mojtaba Khanpour Matikolaei Synthesis and Crystal Structure of [Pb(gly)2]n; New lead(II) Coordination Polymer with Glycine Ligand Journal of Nanostructures coordination polymer nano particle lead(ii) oxide glycine |
| title | Synthesis and Crystal Structure of [Pb(gly)2]n; New lead(II) Coordination Polymer with Glycine Ligand |
| title_full | Synthesis and Crystal Structure of [Pb(gly)2]n; New lead(II) Coordination Polymer with Glycine Ligand |
| title_fullStr | Synthesis and Crystal Structure of [Pb(gly)2]n; New lead(II) Coordination Polymer with Glycine Ligand |
| title_full_unstemmed | Synthesis and Crystal Structure of [Pb(gly)2]n; New lead(II) Coordination Polymer with Glycine Ligand |
| title_short | Synthesis and Crystal Structure of [Pb(gly)2]n; New lead(II) Coordination Polymer with Glycine Ligand |
| title_sort | synthesis and crystal structure of pb gly 2 n new lead ii coordination polymer with glycine ligand |
| topic | coordination polymer nano particle lead(ii) oxide glycine |
| url | http://jns.kashanu.ac.ir/article_87889_7161640b352f818e4fb989ae6875b7e9.pdf |
| work_keys_str_mv | AT zarnooshshokhchashm synthesisandcrystalstructureofpbgly2nnewleadiicoordinationpolymerwithglycineligand AT azarhakimifar synthesisandcrystalstructureofpbgly2nnewleadiicoordinationpolymerwithglycineligand AT lidahashemi synthesisandcrystalstructureofpbgly2nnewleadiicoordinationpolymerwithglycineligand AT alimorsali synthesisandcrystalstructureofpbgly2nnewleadiicoordinationpolymerwithglycineligand AT michaldusek synthesisandcrystalstructureofpbgly2nnewleadiicoordinationpolymerwithglycineligand AT amirrezaabbasi synthesisandcrystalstructureofpbgly2nnewleadiicoordinationpolymerwithglycineligand AT mohammadesmaeilebrahimzadeh synthesisandcrystalstructureofpbgly2nnewleadiicoordinationpolymerwithglycineligand AT fatemebabaei synthesisandcrystalstructureofpbgly2nnewleadiicoordinationpolymerwithglycineligand AT mojtabakhanpourmatikolaei synthesisandcrystalstructureofpbgly2nnewleadiicoordinationpolymerwithglycineligand |