Preparation and thermal properties of flame retardant phthalonitrile/epoxy blends
The blends were successfully prepared by the copolymerization of 2,2-bis [4-(3, 4-dicyanophenoxy) phenyl] propane (BAPh) and epoxy resins E-44 (EP) in the presence of 4,4′-diaminodiphenyl sulfone (DDS) as curing additive. With the loading of BAPh in blends increasing from 10% to 50%, the excellent f...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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De Gruyter
2012-03-01
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| Series: | Science and Engineering of Composite Materials |
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| Online Access: | https://doi.org/10.1515/secm-2011-0123 |
| _version_ | 1818689509567496192 |
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| author | Zhao Xin Lei Yajie Zhao Rui Liu Xiaobo |
| author_facet | Zhao Xin Lei Yajie Zhao Rui Liu Xiaobo |
| author_sort | Zhao Xin |
| collection | DOAJ |
| description | The blends were successfully prepared by the copolymerization of 2,2-bis [4-(3, 4-dicyanophenoxy) phenyl] propane (BAPh) and epoxy resins E-44 (EP) in the presence of 4,4′-diaminodiphenyl sulfone (DDS) as curing additive. With the loading of BAPh in blends increasing from 10% to 50%, the excellent flame retardancy properties of the copolymers with the weight ratio of 20:80 of BAPh/EP achieved over 30 according to the limiting oxygen index test (LOI) values and V-0 grade of UL-94 measurement compared with the pure EP. The temperatures at weight loss 5% (T5%) of the pure EP were improved 16.4°C in nitrogen and 64.6°C in air when the ratio was 20:80. In addition, the gelation time was shortened to 3 min when the prepolymerization temperature was 190°C. |
| first_indexed | 2024-12-17T12:11:14Z |
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| id | doaj.art-a97629d77e6c433484129d003a10661b |
| institution | Directory Open Access Journal |
| issn | 0792-1233 2191-0359 |
| language | English |
| last_indexed | 2024-12-17T12:11:14Z |
| publishDate | 2012-03-01 |
| publisher | De Gruyter |
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| series | Science and Engineering of Composite Materials |
| spelling | doaj.art-a97629d77e6c433484129d003a10661b2022-12-21T21:49:25ZengDe GruyterScience and Engineering of Composite Materials0792-12332191-03592012-03-01191899210.1515/secm-2011-0123Preparation and thermal properties of flame retardant phthalonitrile/epoxy blendsZhao Xin0Lei Yajie1Zhao Rui2Liu Xiaobo3Research Branch of Advanced Functional Materials, Institute of Microelectronic and Solid State Electronic, University of Electronic Science and Technology of China, Chengdu 610054, P.R. ChinaResearch Branch of Advanced Functional Materials, Institute of Microelectronic and Solid State Electronic, University of Electronic Science and Technology of China, Chengdu 610054, P.R. ChinaResearch Branch of Advanced Functional Materials, Institute of Microelectronic and Solid State Electronic, University of Electronic Science and Technology of China, Chengdu 610054, P.R. ChinaResearch Branch of Advanced Functional Materials, Institute of Microelectronic and Solid State Electronic, University of Electronic Science and Technology of China, Chengdu 610054, P.R. ChinaThe blends were successfully prepared by the copolymerization of 2,2-bis [4-(3, 4-dicyanophenoxy) phenyl] propane (BAPh) and epoxy resins E-44 (EP) in the presence of 4,4′-diaminodiphenyl sulfone (DDS) as curing additive. With the loading of BAPh in blends increasing from 10% to 50%, the excellent flame retardancy properties of the copolymers with the weight ratio of 20:80 of BAPh/EP achieved over 30 according to the limiting oxygen index test (LOI) values and V-0 grade of UL-94 measurement compared with the pure EP. The temperatures at weight loss 5% (T5%) of the pure EP were improved 16.4°C in nitrogen and 64.6°C in air when the ratio was 20:80. In addition, the gelation time was shortened to 3 min when the prepolymerization temperature was 190°C.https://doi.org/10.1515/secm-2011-0123blendsengineering propertiesflame retardancyphthalonitrile-epoxy |
| spellingShingle | Zhao Xin Lei Yajie Zhao Rui Liu Xiaobo Preparation and thermal properties of flame retardant phthalonitrile/epoxy blends Science and Engineering of Composite Materials blends engineering properties flame retardancy phthalonitrile-epoxy |
| title | Preparation and thermal properties of flame retardant phthalonitrile/epoxy blends |
| title_full | Preparation and thermal properties of flame retardant phthalonitrile/epoxy blends |
| title_fullStr | Preparation and thermal properties of flame retardant phthalonitrile/epoxy blends |
| title_full_unstemmed | Preparation and thermal properties of flame retardant phthalonitrile/epoxy blends |
| title_short | Preparation and thermal properties of flame retardant phthalonitrile/epoxy blends |
| title_sort | preparation and thermal properties of flame retardant phthalonitrile epoxy blends |
| topic | blends engineering properties flame retardancy phthalonitrile-epoxy |
| url | https://doi.org/10.1515/secm-2011-0123 |
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