Mitsui model with diagonal strains: A unified description of external pressure effect and thermal expansion of Rochelle salt NaKC<sub>4</sub>H<sub>4</sub>O<sub>6</sub>·4H<sub>2</sub>O

We elaborate a modification of the deformable two-sublattice Mitsui model of [Levitskii R.R. et al., Phys. Rev. B. 2003, Vol. 67, 174112] and [Levitskii R.R. et al., Condens. Matter Phys., 2005, Vol. 8, 881] that consistently takes into account diagonal components of the strain tensor, arising eithe...

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Bibliographic Details
Main Authors: I.R. Zachek, R.R. Levitskii, A.P. Moina
Format: Article
Language:English
Published: Institute for Condensed Matter Physics 2011-12-01
Series:Condensed Matter Physics
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Online Access:http://dx.doi.org/10.5488/CMP.14.43602
Description
Summary:We elaborate a modification of the deformable two-sublattice Mitsui model of [Levitskii R.R. et al., Phys. Rev. B. 2003, Vol. 67, 174112] and [Levitskii R.R. et al., Condens. Matter Phys., 2005, Vol. 8, 881] that consistently takes into account diagonal components of the strain tensor, arising either due to external pressures or due to thermal expansion. We calculate the related to those strains thermal, piezoelectric, and elastic characteristics of the system. Using the developed fitting procedure, a set of the model parameters is found for the case of Rochelle salt crystals, providing a satisfactory agreement with the available experimental data for the hydrostatic and uniaxial pressure dependences of the Curie temperatures, temperature dependences of spontaneous diagonal strains, linear thermal expansion coefficients, elastic constants c<sub>ij</sub><sup>E</sup> and c<sub>i4</sub><sup>E</sup>, piezoelectric coefficients d<sub>1i</sub> and g<sub>1i</sub> (i=1,2,3). The hydrostatic pressure variation of dielectric permittivity is described using a derived expression for the permittivity of a partially clamped crystal. The dipole moments and the asymmetry parameter of Rochelle salt are found to increase with hydrostatic pressure.
ISSN:1607-324X