Synthesis of kaolin-based alkali-activated cement: carbon footprint, cost and energy assessment

The main purpose of the work reported herein is to use kaolin to produce one-part alkali-activated cement. Thermal activation was performed on kaolin in the presence of alkalis (calcium oxide, sodium silicate, and sodium carbonate). Optimization experimental investigations were undertaken with selec...

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Main Authors: Ayman Ababneh, Faris Matalkah, Ruba Aqel
Format: Article
Language:English
Published: Elsevier 2020-07-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2238785420313867
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author Ayman Ababneh
Faris Matalkah
Ruba Aqel
author_facet Ayman Ababneh
Faris Matalkah
Ruba Aqel
author_sort Ayman Ababneh
collection DOAJ
description The main purpose of the work reported herein is to use kaolin to produce one-part alkali-activated cement. Thermal activation was performed on kaolin in the presence of alkalis (calcium oxide, sodium silicate, and sodium carbonate). Optimization experimental investigations were undertaken with selected alkalis to maximize the mechanical properties as well as minimize the cost of the resultant alkali-activated cement. Scanning electron microscopy/energy dispersive spectroscopy (SEM/EDS), thermogravimetric analysis (TGA), and X-ray diffraction (XRD) test techniques were used to get insight into the binder chemical phases and their microstructure. The results showed that the optimal formulation for the alkali-activated kaolin cement developed consists of 62.5 wt.% kaolin, 30 wt.% calcium oxide, 5 wt.% sodium carbonate and 2.5 wt.% sodium silicate. The 7-day compressive strength at heat and room-curing temperatures reached 19.83 and 16.47 MPa, respectively. The competitive merits of the kaolin-based cement assessed against Portland cement considering the raw materials and production processing contributions to carbon footprint, cost, and energy content. The carbon footprint of the alkali-activated kaolin cement was 70% less than that of Portland cement. The cost and energy content of the alkali-activated kaolin cement was 45% and 70%, respectively, less than those of Portland cement.
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spelling doaj.art-a9953ceacaea459ba4af04a93fe6bc832022-12-22T03:02:13ZengElsevierJournal of Materials Research and Technology2238-78542020-07-019483678378Synthesis of kaolin-based alkali-activated cement: carbon footprint, cost and energy assessmentAyman Ababneh0Faris Matalkah1Ruba Aqel2Department of Civil Engineering, Jordan University of Science and Technology, Irbid, Jordan; Corresponding author.Department of Civil Engineering, Yarmouk University, Irbid, JordanDepartment of Civil Engineering, Jordan University of Science and Technology, Irbid, JordanThe main purpose of the work reported herein is to use kaolin to produce one-part alkali-activated cement. Thermal activation was performed on kaolin in the presence of alkalis (calcium oxide, sodium silicate, and sodium carbonate). Optimization experimental investigations were undertaken with selected alkalis to maximize the mechanical properties as well as minimize the cost of the resultant alkali-activated cement. Scanning electron microscopy/energy dispersive spectroscopy (SEM/EDS), thermogravimetric analysis (TGA), and X-ray diffraction (XRD) test techniques were used to get insight into the binder chemical phases and their microstructure. The results showed that the optimal formulation for the alkali-activated kaolin cement developed consists of 62.5 wt.% kaolin, 30 wt.% calcium oxide, 5 wt.% sodium carbonate and 2.5 wt.% sodium silicate. The 7-day compressive strength at heat and room-curing temperatures reached 19.83 and 16.47 MPa, respectively. The competitive merits of the kaolin-based cement assessed against Portland cement considering the raw materials and production processing contributions to carbon footprint, cost, and energy content. The carbon footprint of the alkali-activated kaolin cement was 70% less than that of Portland cement. The cost and energy content of the alkali-activated kaolin cement was 45% and 70%, respectively, less than those of Portland cement.http://www.sciencedirect.com/science/article/pii/S2238785420313867SustainabilityGeopolymerKaolinAlkali activationThermal processingCement
spellingShingle Ayman Ababneh
Faris Matalkah
Ruba Aqel
Synthesis of kaolin-based alkali-activated cement: carbon footprint, cost and energy assessment
Journal of Materials Research and Technology
Sustainability
Geopolymer
Kaolin
Alkali activation
Thermal processing
Cement
title Synthesis of kaolin-based alkali-activated cement: carbon footprint, cost and energy assessment
title_full Synthesis of kaolin-based alkali-activated cement: carbon footprint, cost and energy assessment
title_fullStr Synthesis of kaolin-based alkali-activated cement: carbon footprint, cost and energy assessment
title_full_unstemmed Synthesis of kaolin-based alkali-activated cement: carbon footprint, cost and energy assessment
title_short Synthesis of kaolin-based alkali-activated cement: carbon footprint, cost and energy assessment
title_sort synthesis of kaolin based alkali activated cement carbon footprint cost and energy assessment
topic Sustainability
Geopolymer
Kaolin
Alkali activation
Thermal processing
Cement
url http://www.sciencedirect.com/science/article/pii/S2238785420313867
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AT farismatalkah synthesisofkaolinbasedalkaliactivatedcementcarbonfootprintcostandenergyassessment
AT rubaaqel synthesisofkaolinbasedalkaliactivatedcementcarbonfootprintcostandenergyassessment