(E)-2-[4-(Dimethylamino)styryl]-1-methylquinolinium 4-methylbenzenesulfonate monohydrateThis paper is dedicated to the late Her Royal Highness Princess Galyani Vadhana Krom Luang Naradhiwas Rajanagarindra for her patronage of Science in Thailand.
In the title compound, C20H21N2+·C7H7O3S−·H2O, the cation is essentially planar, as indicated by the dihedral angle of 2.79 (13)° between the quinolinium and the dimethylaminophenyl rings, and exists in the E configuration. The π-conjugated pla...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-01-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808040671 |
| _version_ | 1818971460449861632 |
|---|---|
| author | Thawanrat Kobkeatthawin Thitipone Suwunwong Hoong-Kun Fun Suchada Chantrapromma |
| author_facet | Thawanrat Kobkeatthawin Thitipone Suwunwong Hoong-Kun Fun Suchada Chantrapromma |
| author_sort | Thawanrat Kobkeatthawin |
| collection | DOAJ |
| description | In the title compound, C20H21N2+·C7H7O3S−·H2O, the cation is essentially planar, as indicated by the dihedral angle of 2.79 (13)° between the quinolinium and the dimethylaminophenyl rings, and exists in the E configuration. The π-conjugated planes of the cation and the anion are inclined to each other at a dihedral angle of 66.95 (12)°. The cation is linked to the anion through C—H...O hydrogen bonds and the anion is further linked with the water molecule by O—H...O hydrogen bonds, forming a three-molecule unit. These units are arranged in a face-to-face manner into a ribbon-like structure along the b axis. The ribbons are stacked along the c axis. The crystal structure is further stabilized by C—H...π interactions involving the dimethylaminophenyl and methylphenyl rings. A π–π interaction with a centroid–centroid distance of 3.6074 (19) Å is also observed. |
| first_indexed | 2024-12-20T14:52:44Z |
| format | Article |
| id | doaj.art-a9ac3e55071c468bac9b31712bbdd974 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T14:52:44Z |
| publishDate | 2009-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-a9ac3e55071c468bac9b31712bbdd9742022-12-21T19:36:57ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-01-01651o76o7710.1107/S1600536808040671(E)-2-[4-(Dimethylamino)styryl]-1-methylquinolinium 4-methylbenzenesulfonate monohydrateThis paper is dedicated to the late Her Royal Highness Princess Galyani Vadhana Krom Luang Naradhiwas Rajanagarindra for her patronage of Science in Thailand.Thawanrat KobkeatthawinThitipone SuwunwongHoong-Kun FunSuchada ChantraprommaIn the title compound, C20H21N2+·C7H7O3S−·H2O, the cation is essentially planar, as indicated by the dihedral angle of 2.79 (13)° between the quinolinium and the dimethylaminophenyl rings, and exists in the E configuration. The π-conjugated planes of the cation and the anion are inclined to each other at a dihedral angle of 66.95 (12)°. The cation is linked to the anion through C—H...O hydrogen bonds and the anion is further linked with the water molecule by O—H...O hydrogen bonds, forming a three-molecule unit. These units are arranged in a face-to-face manner into a ribbon-like structure along the b axis. The ribbons are stacked along the c axis. The crystal structure is further stabilized by C—H...π interactions involving the dimethylaminophenyl and methylphenyl rings. A π–π interaction with a centroid–centroid distance of 3.6074 (19) Å is also observed.http://scripts.iucr.org/cgi-bin/paper?S1600536808040671 |
| spellingShingle | Thawanrat Kobkeatthawin Thitipone Suwunwong Hoong-Kun Fun Suchada Chantrapromma (E)-2-[4-(Dimethylamino)styryl]-1-methylquinolinium 4-methylbenzenesulfonate monohydrateThis paper is dedicated to the late Her Royal Highness Princess Galyani Vadhana Krom Luang Naradhiwas Rajanagarindra for her patronage of Science in Thailand. Acta Crystallographica Section E |
| title | (E)-2-[4-(Dimethylamino)styryl]-1-methylquinolinium 4-methylbenzenesulfonate monohydrateThis paper is dedicated to the late Her Royal Highness Princess Galyani Vadhana Krom Luang Naradhiwas Rajanagarindra for her patronage of Science in Thailand. |
| title_full | (E)-2-[4-(Dimethylamino)styryl]-1-methylquinolinium 4-methylbenzenesulfonate monohydrateThis paper is dedicated to the late Her Royal Highness Princess Galyani Vadhana Krom Luang Naradhiwas Rajanagarindra for her patronage of Science in Thailand. |
| title_fullStr | (E)-2-[4-(Dimethylamino)styryl]-1-methylquinolinium 4-methylbenzenesulfonate monohydrateThis paper is dedicated to the late Her Royal Highness Princess Galyani Vadhana Krom Luang Naradhiwas Rajanagarindra for her patronage of Science in Thailand. |
| title_full_unstemmed | (E)-2-[4-(Dimethylamino)styryl]-1-methylquinolinium 4-methylbenzenesulfonate monohydrateThis paper is dedicated to the late Her Royal Highness Princess Galyani Vadhana Krom Luang Naradhiwas Rajanagarindra for her patronage of Science in Thailand. |
| title_short | (E)-2-[4-(Dimethylamino)styryl]-1-methylquinolinium 4-methylbenzenesulfonate monohydrateThis paper is dedicated to the late Her Royal Highness Princess Galyani Vadhana Krom Luang Naradhiwas Rajanagarindra for her patronage of Science in Thailand. |
| title_sort | e 2 4 dimethylamino styryl 1 methylquinolinium 4 methylbenzenesulfonate monohydratethis paper is dedicated to the late her royal highness princess galyani vadhana krom luang naradhiwas rajanagarindra for her patronage of science in thailand |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808040671 |
| work_keys_str_mv | AT thawanratkobkeatthawin e24dimethylaminostyryl1methylquinolinium4methylbenzenesulfonatemonohydratethispaperisdedicatedtothelateherroyalhighnessprincessgalyanivadhanakromluangnaradhiwasrajanagarindraforherpatronageofscienceinthailand AT thitiponesuwunwong e24dimethylaminostyryl1methylquinolinium4methylbenzenesulfonatemonohydratethispaperisdedicatedtothelateherroyalhighnessprincessgalyanivadhanakromluangnaradhiwasrajanagarindraforherpatronageofscienceinthailand AT hoongkunfun e24dimethylaminostyryl1methylquinolinium4methylbenzenesulfonatemonohydratethispaperisdedicatedtothelateherroyalhighnessprincessgalyanivadhanakromluangnaradhiwasrajanagarindraforherpatronageofscienceinthailand AT suchadachantrapromma e24dimethylaminostyryl1methylquinolinium4methylbenzenesulfonatemonohydratethispaperisdedicatedtothelateherroyalhighnessprincessgalyanivadhanakromluangnaradhiwasrajanagarindraforherpatronageofscienceinthailand |