Stabilized Palladium Nanoparticles from Bis-(<i>N</i>-benzoylthiourea) Derived-Pd<sup>II</sup> Complexes as Efficient Catalysts for Sustainable Cross-Coupling Reactions in Water
Stable palladium (II) complexes, incorporating a double (<i>N</i>-benzoylthiourea) arrangement bonded to a complex heterocyclic scaffold, are used as precursors of catalytic species able to promote Suzuki–Miyaura, Mizoroki–Heck, Hiyama, Buchwald–Hartwig, Hirao and Sonogashira–Hagihara cr...
| Main Authors: | , , , , , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2024-03-01
|
| Series: | Molecules |
| Subjects: | |
| Online Access: | https://www.mdpi.com/1420-3049/29/5/1138 |
| _version_ | 1827319535352414208 |
|---|---|
| author | Samet Poyraz H. Ali Döndaş Samet Belveren Senanur Taş Raquel Hidalgo-León José Trujillo-Sierra Lesly V. Rodríguez-Flórez Mª de Gracia Retamosa Ana Sirvent Mohammad Gholinejad Sara Sobhani José M. Sansano |
| author_facet | Samet Poyraz H. Ali Döndaş Samet Belveren Senanur Taş Raquel Hidalgo-León José Trujillo-Sierra Lesly V. Rodríguez-Flórez Mª de Gracia Retamosa Ana Sirvent Mohammad Gholinejad Sara Sobhani José M. Sansano |
| author_sort | Samet Poyraz |
| collection | DOAJ |
| description | Stable palladium (II) complexes, incorporating a double (<i>N</i>-benzoylthiourea) arrangement bonded to a complex heterocyclic scaffold, are used as precursors of catalytic species able to promote Suzuki–Miyaura, Mizoroki–Heck, Hiyama, Buchwald–Hartwig, Hirao and Sonogashira–Hagihara cross-coupling transformations in water. These sustainable processes are chemoselective and very versatile. The nanoparticles responsible for these catalytic reactions were analyzed and studied. Their usefulness is demonstrated after several tests and analyses. The heterogeneous character of this species in water was also confirmed. |
| first_indexed | 2024-04-25T00:23:38Z |
| format | Article |
| id | doaj.art-a9d4789c3e4e42f88af83c8895e35fb0 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-04-25T00:23:38Z |
| publishDate | 2024-03-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-a9d4789c3e4e42f88af83c8895e35fb02024-03-12T16:51:14ZengMDPI AGMolecules1420-30492024-03-01295113810.3390/molecules29051138Stabilized Palladium Nanoparticles from Bis-(<i>N</i>-benzoylthiourea) Derived-Pd<sup>II</sup> Complexes as Efficient Catalysts for Sustainable Cross-Coupling Reactions in WaterSamet Poyraz0H. Ali Döndaş1Samet Belveren2Senanur Taş3Raquel Hidalgo-León4José Trujillo-Sierra5Lesly V. Rodríguez-Flórez6Mª de Gracia Retamosa7Ana Sirvent8Mohammad Gholinejad9Sara Sobhani10José M. Sansano11Department of Basic Pharmaceutical Sciences, Faculty of Pharmacy, Çukurova University, Balcalı, Adana 01330, TürkiyeDepartment of Basic Pharmaceutical Sciences, Faculty of Pharmacy, Çukurova University, Balcalı, Adana 01330, TürkiyeDepartment of Basic Pharmaceutical Sciences, Faculty of Pharmacy, Çukurova University, Balcalı, Adana 01330, TürkiyeDepartment of Biotechnology, Institute of Natural and Applied Sciences, Çukurova University, Balcalı, Adana 01330, TürkiyeDepartamento de Química Orgánica, Instituto de Síntesis Orgánica (ISO), Centro de Innovación en Química Avanzada (ORFEO-CINQA), University of Alicante, P.O. Box 99, 03690 Alicante, SpainDepartamento de Química Orgánica, Instituto de Síntesis Orgánica (ISO), Centro de Innovación en Química Avanzada (ORFEO-CINQA), University of Alicante, P.O. Box 99, 03690 Alicante, SpainDepartamento de Química Orgánica, Instituto de Síntesis Orgánica (ISO), Centro de Innovación en Química Avanzada (ORFEO-CINQA), University of Alicante, P.O. Box 99, 03690 Alicante, SpainDepartamento de Química Orgánica, Instituto de Síntesis Orgánica (ISO), Centro de Innovación en Química Avanzada (ORFEO-CINQA), University of Alicante, P.O. Box 99, 03690 Alicante, SpainDepartamento de Química Orgánica, Instituto de Síntesis Orgánica (ISO), Centro de Innovación en Química Avanzada (ORFEO-CINQA), University of Alicante, P.O. Box 99, 03690 Alicante, SpainDepartment of Chemistry, Institute for Advanced Studies in Basic Sciences (IASBS), P.O. Box 45195-1159, Zanjan 45137-66731, IranDepartment of Chemistry, College of Sciences, Shiraz University, Shiraz 71454, IranDepartamento de Química Orgánica, Instituto de Síntesis Orgánica (ISO), Centro de Innovación en Química Avanzada (ORFEO-CINQA), University of Alicante, P.O. Box 99, 03690 Alicante, SpainStable palladium (II) complexes, incorporating a double (<i>N</i>-benzoylthiourea) arrangement bonded to a complex heterocyclic scaffold, are used as precursors of catalytic species able to promote Suzuki–Miyaura, Mizoroki–Heck, Hiyama, Buchwald–Hartwig, Hirao and Sonogashira–Hagihara cross-coupling transformations in water. These sustainable processes are chemoselective and very versatile. The nanoparticles responsible for these catalytic reactions were analyzed and studied. Their usefulness is demonstrated after several tests and analyses. The heterogeneous character of this species in water was also confirmed.https://www.mdpi.com/1420-3049/29/5/1138nanoparticlespalladiumSuzukiHeckHiyamaBuchwald–Hartwig |
| spellingShingle | Samet Poyraz H. Ali Döndaş Samet Belveren Senanur Taş Raquel Hidalgo-León José Trujillo-Sierra Lesly V. Rodríguez-Flórez Mª de Gracia Retamosa Ana Sirvent Mohammad Gholinejad Sara Sobhani José M. Sansano Stabilized Palladium Nanoparticles from Bis-(<i>N</i>-benzoylthiourea) Derived-Pd<sup>II</sup> Complexes as Efficient Catalysts for Sustainable Cross-Coupling Reactions in Water Molecules nanoparticles palladium Suzuki Heck Hiyama Buchwald–Hartwig |
| title | Stabilized Palladium Nanoparticles from Bis-(<i>N</i>-benzoylthiourea) Derived-Pd<sup>II</sup> Complexes as Efficient Catalysts for Sustainable Cross-Coupling Reactions in Water |
| title_full | Stabilized Palladium Nanoparticles from Bis-(<i>N</i>-benzoylthiourea) Derived-Pd<sup>II</sup> Complexes as Efficient Catalysts for Sustainable Cross-Coupling Reactions in Water |
| title_fullStr | Stabilized Palladium Nanoparticles from Bis-(<i>N</i>-benzoylthiourea) Derived-Pd<sup>II</sup> Complexes as Efficient Catalysts for Sustainable Cross-Coupling Reactions in Water |
| title_full_unstemmed | Stabilized Palladium Nanoparticles from Bis-(<i>N</i>-benzoylthiourea) Derived-Pd<sup>II</sup> Complexes as Efficient Catalysts for Sustainable Cross-Coupling Reactions in Water |
| title_short | Stabilized Palladium Nanoparticles from Bis-(<i>N</i>-benzoylthiourea) Derived-Pd<sup>II</sup> Complexes as Efficient Catalysts for Sustainable Cross-Coupling Reactions in Water |
| title_sort | stabilized palladium nanoparticles from bis i n i benzoylthiourea derived pd sup ii sup complexes as efficient catalysts for sustainable cross coupling reactions in water |
| topic | nanoparticles palladium Suzuki Heck Hiyama Buchwald–Hartwig |
| url | https://www.mdpi.com/1420-3049/29/5/1138 |
| work_keys_str_mv | AT sametpoyraz stabilizedpalladiumnanoparticlesfrombisinibenzoylthioureaderivedpdsupiisupcomplexesasefficientcatalystsforsustainablecrosscouplingreactionsinwater AT halidondas stabilizedpalladiumnanoparticlesfrombisinibenzoylthioureaderivedpdsupiisupcomplexesasefficientcatalystsforsustainablecrosscouplingreactionsinwater AT sametbelveren stabilizedpalladiumnanoparticlesfrombisinibenzoylthioureaderivedpdsupiisupcomplexesasefficientcatalystsforsustainablecrosscouplingreactionsinwater AT senanurtas stabilizedpalladiumnanoparticlesfrombisinibenzoylthioureaderivedpdsupiisupcomplexesasefficientcatalystsforsustainablecrosscouplingreactionsinwater AT raquelhidalgoleon stabilizedpalladiumnanoparticlesfrombisinibenzoylthioureaderivedpdsupiisupcomplexesasefficientcatalystsforsustainablecrosscouplingreactionsinwater AT josetrujillosierra stabilizedpalladiumnanoparticlesfrombisinibenzoylthioureaderivedpdsupiisupcomplexesasefficientcatalystsforsustainablecrosscouplingreactionsinwater AT leslyvrodriguezflorez stabilizedpalladiumnanoparticlesfrombisinibenzoylthioureaderivedpdsupiisupcomplexesasefficientcatalystsforsustainablecrosscouplingreactionsinwater AT madegraciaretamosa stabilizedpalladiumnanoparticlesfrombisinibenzoylthioureaderivedpdsupiisupcomplexesasefficientcatalystsforsustainablecrosscouplingreactionsinwater AT anasirvent stabilizedpalladiumnanoparticlesfrombisinibenzoylthioureaderivedpdsupiisupcomplexesasefficientcatalystsforsustainablecrosscouplingreactionsinwater AT mohammadgholinejad stabilizedpalladiumnanoparticlesfrombisinibenzoylthioureaderivedpdsupiisupcomplexesasefficientcatalystsforsustainablecrosscouplingreactionsinwater AT sarasobhani stabilizedpalladiumnanoparticlesfrombisinibenzoylthioureaderivedpdsupiisupcomplexesasefficientcatalystsforsustainablecrosscouplingreactionsinwater AT josemsansano stabilizedpalladiumnanoparticlesfrombisinibenzoylthioureaderivedpdsupiisupcomplexesasefficientcatalystsforsustainablecrosscouplingreactionsinwater |