1,8-Bis(dimethylamino)naphthyl-2-ketimines: Inside vs outside protonation

1,8-Bis(dimethylamino)naphthyl-2-ketimines: Inside vs outside protonation

The structure and protonation behaviour of four ortho-arylketimines of 1,8-bis(dimethylamonio)naphthalene with a different number of methoxy groups in an aromatic substituent were investigated in solution by NMR (acetone, DMSO, MeCN), in solid state by X-ray analysis and in the gas phase by DFT calc...

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Bibliographic Details
Main Authors: A. S. Antonov, A. F. Pozharskii, P. M. Tolstoy, A. Filarowski, O. V. Khoroshilova
Format: Article
Language:English
Published: Beilstein-Institut 2018-11-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
hydrogen bond
imine
NMR
proton sponge
superbase
Online Access:https://doi.org/10.3762/bjoc.14.273

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