Magnesium Coordination Chemistry: A Case Study of Magnesium Carboxylate Complexes with Hexamethylenetetramine
Three magnesium coordination compounds were obtained to explore the influence of carboxylate anions on the pattern of the formed hydrogen bonds. For their synthesis, various salts of magnesium carboxylic acid (formate, acetate, and propionate) were utilized. As an <i>N</i>-donor ligand,...
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MDPI AG
2022-10-01
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| Series: | Crystals |
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| Online Access: | https://www.mdpi.com/2073-4352/12/10/1434 |
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| author | Tomasz Sierański Agata Trzęsowska-Kruszyńska Marcin Świątkowski Marta Bogdan Paulina Sobczak |
| author_facet | Tomasz Sierański Agata Trzęsowska-Kruszyńska Marcin Świątkowski Marta Bogdan Paulina Sobczak |
| author_sort | Tomasz Sierański |
| collection | DOAJ |
| description | Three magnesium coordination compounds were obtained to explore the influence of carboxylate anions on the pattern of the formed hydrogen bonds. For their synthesis, various salts of magnesium carboxylic acid (formate, acetate, and propionate) were utilized. As an <i>N</i>-donor ligand, hexamethylenetetramine was employed. The supramolecular structures of the obtained compounds were determined and evaluated in Hirshfeld analysis. The length of the carbon chain of the used carboxylate anions has been proven to have a considerable impact on the self-organization of the supramolecular system by altering the three-dimensional net of the created hydrogen bonds. IR spectroscopy was used to characterize the obtained compounds, revealing significant differences between distinct systems. The thermal analysis of the investigated compounds also shows noticeable differences, demonstrating better stability of the systems containing formate anions. |
| first_indexed | 2024-03-09T20:25:32Z |
| format | Article |
| id | doaj.art-a9e8b67d9cec4b5f9b8351dc7225a6a8 |
| institution | Directory Open Access Journal |
| issn | 2073-4352 |
| language | English |
| last_indexed | 2024-03-09T20:25:32Z |
| publishDate | 2022-10-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Crystals |
| spelling | doaj.art-a9e8b67d9cec4b5f9b8351dc7225a6a82023-11-23T23:38:22ZengMDPI AGCrystals2073-43522022-10-011210143410.3390/cryst12101434Magnesium Coordination Chemistry: A Case Study of Magnesium Carboxylate Complexes with HexamethylenetetramineTomasz Sierański0Agata Trzęsowska-Kruszyńska1Marcin Świątkowski2Marta Bogdan3Paulina Sobczak4Institute of General and Ecological Chemistry, Lodz University of Technology, Zeromskiego 116, PL-90924 Lodz, PolandInstitute of General and Ecological Chemistry, Lodz University of Technology, Zeromskiego 116, PL-90924 Lodz, PolandInstitute of General and Ecological Chemistry, Lodz University of Technology, Zeromskiego 116, PL-90924 Lodz, PolandInstitute of General and Ecological Chemistry, Lodz University of Technology, Zeromskiego 116, PL-90924 Lodz, PolandInstitute of General and Ecological Chemistry, Lodz University of Technology, Zeromskiego 116, PL-90924 Lodz, PolandThree magnesium coordination compounds were obtained to explore the influence of carboxylate anions on the pattern of the formed hydrogen bonds. For their synthesis, various salts of magnesium carboxylic acid (formate, acetate, and propionate) were utilized. As an <i>N</i>-donor ligand, hexamethylenetetramine was employed. The supramolecular structures of the obtained compounds were determined and evaluated in Hirshfeld analysis. The length of the carbon chain of the used carboxylate anions has been proven to have a considerable impact on the self-organization of the supramolecular system by altering the three-dimensional net of the created hydrogen bonds. IR spectroscopy was used to characterize the obtained compounds, revealing significant differences between distinct systems. The thermal analysis of the investigated compounds also shows noticeable differences, demonstrating better stability of the systems containing formate anions.https://www.mdpi.com/2073-4352/12/10/1434magnesiumformateacetatepropionatehexamethylenetetraminecrystal structure |
| spellingShingle | Tomasz Sierański Agata Trzęsowska-Kruszyńska Marcin Świątkowski Marta Bogdan Paulina Sobczak Magnesium Coordination Chemistry: A Case Study of Magnesium Carboxylate Complexes with Hexamethylenetetramine Crystals magnesium formate acetate propionate hexamethylenetetramine crystal structure |
| title | Magnesium Coordination Chemistry: A Case Study of Magnesium Carboxylate Complexes with Hexamethylenetetramine |
| title_full | Magnesium Coordination Chemistry: A Case Study of Magnesium Carboxylate Complexes with Hexamethylenetetramine |
| title_fullStr | Magnesium Coordination Chemistry: A Case Study of Magnesium Carboxylate Complexes with Hexamethylenetetramine |
| title_full_unstemmed | Magnesium Coordination Chemistry: A Case Study of Magnesium Carboxylate Complexes with Hexamethylenetetramine |
| title_short | Magnesium Coordination Chemistry: A Case Study of Magnesium Carboxylate Complexes with Hexamethylenetetramine |
| title_sort | magnesium coordination chemistry a case study of magnesium carboxylate complexes with hexamethylenetetramine |
| topic | magnesium formate acetate propionate hexamethylenetetramine crystal structure |
| url | https://www.mdpi.com/2073-4352/12/10/1434 |
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