Aqueous-phase reforming of hydroxyacetone solution to bio-based H2 over supported Pt catalysts
Aqueous-phase reforming (APR) is an attractive process to produce bio-based hydrogen from waste biomass streams, during which the catalyst stability is often challenged due to the harsh reaction conditions. In this work, three Pt-based catalysts supported on C, AlO(OH), and ZrO2 were investigated fo...
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| Format: | Article |
| Language: | English |
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KeAi Communications Co., Ltd.
2024-04-01
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| Series: | Green Energy & Environment |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2468025722001339 |
| _version_ | 1797291786447618048 |
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| author | A.K.K. Vikla K. Koichumanova Songbo He K. Seshan |
| author_facet | A.K.K. Vikla K. Koichumanova Songbo He K. Seshan |
| author_sort | A.K.K. Vikla |
| collection | DOAJ |
| description | Aqueous-phase reforming (APR) is an attractive process to produce bio-based hydrogen from waste biomass streams, during which the catalyst stability is often challenged due to the harsh reaction conditions. In this work, three Pt-based catalysts supported on C, AlO(OH), and ZrO2 were investigated for the APR of hydroxyacetone solution in a fixed bed reactor at 225 °C and 35 bar. Among them, the Pt/C catalyst showed the highest turnover frequency for H2 production (TOF of 8.9 molH2 molPt−1 min−1) and the longest catalyst stability. Over the AlO(OH) and ZrO2 supported Pt catalysts, the side reactions consuming H2, formation of coke, and Pt sintering result in a low H2 production and the fast catalyst deactivation. The proposed reaction pathways suggest that a promising APR catalyst should reform all oxygenates in the aqueous phase, minimize the hydrogenation of the oxygenates, maximize the WGS reaction, and inhibit the condensation and coking reactions for maximizing the hydrogen yield and a stable catalytic performance. |
| first_indexed | 2024-03-07T19:41:49Z |
| format | Article |
| id | doaj.art-a9f0e2b1c8cb4760b50738a4e96e489b |
| institution | Directory Open Access Journal |
| issn | 2468-0257 |
| language | English |
| last_indexed | 2024-03-07T19:41:49Z |
| publishDate | 2024-04-01 |
| publisher | KeAi Communications Co., Ltd. |
| record_format | Article |
| series | Green Energy & Environment |
| spelling | doaj.art-a9f0e2b1c8cb4760b50738a4e96e489b2024-02-29T05:20:07ZengKeAi Communications Co., Ltd.Green Energy & Environment2468-02572024-04-0194777788Aqueous-phase reforming of hydroxyacetone solution to bio-based H2 over supported Pt catalystsA.K.K. Vikla0K. Koichumanova1Songbo He2K. Seshan3Faculty of Science and Technology, University of Twente, 7500 AE Enschede, The NetherlandsFaculty of Science and Technology, University of Twente, 7500 AE Enschede, The NetherlandsJoint International Research Laboratory of Circular Carbon, Nanjing Tech University, Nanjing, 211816, China; Faculty of Science and Technology, University of Twente, 7500 AE Enschede, The Netherlands; CoRe Pro, 9723 BL Groningen, The Netherlands; Corresponding author.Faculty of Science and Technology, University of Twente, 7500 AE Enschede, The NetherlandsAqueous-phase reforming (APR) is an attractive process to produce bio-based hydrogen from waste biomass streams, during which the catalyst stability is often challenged due to the harsh reaction conditions. In this work, three Pt-based catalysts supported on C, AlO(OH), and ZrO2 were investigated for the APR of hydroxyacetone solution in a fixed bed reactor at 225 °C and 35 bar. Among them, the Pt/C catalyst showed the highest turnover frequency for H2 production (TOF of 8.9 molH2 molPt−1 min−1) and the longest catalyst stability. Over the AlO(OH) and ZrO2 supported Pt catalysts, the side reactions consuming H2, formation of coke, and Pt sintering result in a low H2 production and the fast catalyst deactivation. The proposed reaction pathways suggest that a promising APR catalyst should reform all oxygenates in the aqueous phase, minimize the hydrogenation of the oxygenates, maximize the WGS reaction, and inhibit the condensation and coking reactions for maximizing the hydrogen yield and a stable catalytic performance.http://www.sciencedirect.com/science/article/pii/S2468025722001339APRHydroxyacetoneTOFBio-based H2Support effect |
| spellingShingle | A.K.K. Vikla K. Koichumanova Songbo He K. Seshan Aqueous-phase reforming of hydroxyacetone solution to bio-based H2 over supported Pt catalysts Green Energy & Environment APR Hydroxyacetone TOF Bio-based H2 Support effect |
| title | Aqueous-phase reforming of hydroxyacetone solution to bio-based H2 over supported Pt catalysts |
| title_full | Aqueous-phase reforming of hydroxyacetone solution to bio-based H2 over supported Pt catalysts |
| title_fullStr | Aqueous-phase reforming of hydroxyacetone solution to bio-based H2 over supported Pt catalysts |
| title_full_unstemmed | Aqueous-phase reforming of hydroxyacetone solution to bio-based H2 over supported Pt catalysts |
| title_short | Aqueous-phase reforming of hydroxyacetone solution to bio-based H2 over supported Pt catalysts |
| title_sort | aqueous phase reforming of hydroxyacetone solution to bio based h2 over supported pt catalysts |
| topic | APR Hydroxyacetone TOF Bio-based H2 Support effect |
| url | http://www.sciencedirect.com/science/article/pii/S2468025722001339 |
| work_keys_str_mv | AT akkvikla aqueousphasereformingofhydroxyacetonesolutiontobiobasedh2oversupportedptcatalysts AT kkoichumanova aqueousphasereformingofhydroxyacetonesolutiontobiobasedh2oversupportedptcatalysts AT songbohe aqueousphasereformingofhydroxyacetonesolutiontobiobasedh2oversupportedptcatalysts AT kseshan aqueousphasereformingofhydroxyacetonesolutiontobiobasedh2oversupportedptcatalysts |