Interaction between [(η<sup>6</sup>-<i>p</i>-cym)M(H<sub>2</sub>O)<sub>3</sub>]<sup>2+</sup> (M<sup>II</sup> = Ru, Os) or [(η<sup>5</sup>-Cp*)M(H<sub>2</sub>O)<sub>3</sub>]<sup>2+</sup> (M<sup>III</sup> = Rh, Ir) and Phosphonate Derivatives of Iminodiacetic Acid: A Solution Equilibrium and DFT Study

Interaction between [(η<sup>6</sup>-<i>p</i>-cym)M(H<sub>2</sub>O)<sub>3</sub>]<sup>2+</sup> (M<sup>II</sup> = Ru, Os) or [(η<sup>5</sup>-Cp*)M(H<sub>2</sub>O)<sub>3</sub>]<sup>2+</sup> (M<sup>III</sup> = Rh, Ir) and Phosphonate Derivatives of Iminodiacetic Acid: A Solution Equilibrium and DFT Study

The pH-dependent binding strengths and modes of the organometallic [(η<sup>6</sup>-<i>p</i>-cym)M(H<sub>2</sub>O)<sub>3</sub>]<sup>2+</sup> (M<sup>II</sup> = Ru, Os; <i>p</i>-cym = 1-methyl-4-isopropylbenzene) or [(η...

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Bibliographic Details
Main Authors: Linda Bíró, Botond Tóth, Norbert Lihi, Etelka Farkas, Péter Buglyó
Format: Article
Language:English
Published: MDPI AG 2023-02-01
Series:Molecules
Subjects:
IDA-based phosphonates
organoruthenium
organorhodium
solution equilibrium
complex
Online Access:https://www.mdpi.com/1420-3049/28/3/1477

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